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111.
112.
Asymptotic normality of the solutions of the initial-value problems for multidimensional Burgers' equation with weakly dependent possible non-Gaussian initial condition is proved. 相似文献
113.
Multiparticle production data on proton-nucleus collisions have been analyzed taking the number of ‘created’ charged particles
instead of the observed number of shower particles as the variable. The mean normalized multiplicity,R
A
, has been found to be independent of energy in the energy range (7–8000) GeV and its mass number dependence has been obtained.
The modified analysis introduces some more regularities in the experimental results onp-nucleus collisions like the invariance with respect to energy of the relationshipR
A
= α + βN
h
and the KNO-like scaling of the multiplicity distributions of the created charged particles. The functional form of the scaling
function has been calculated. 相似文献
114.
Ooms KJ Feindel KW Willans MJ Wasylishen RE Hanna JV Pike KJ Smith ME 《Solid state nuclear magnetic resonance》2005,28(2-4):125-134
Results from a solid-state 139La NMR spectroscopic investigation of the anhydrous lanthanum(III) halides (LaX3; X=F, Cl, Br, I) at applied magnetic fields of 7.0, 9.4, 11.7, 14.1, and 17.6 T are presented and highlight the advantages of working at high applied magnetic field strengths. The 139La quadrupolar coupling constants are found to range from 15.55 to 24.0 MHz for LaCl3 and LaI3, respectively. The lanthanum isotropic chemical shifts exhibit an inverse halogen dependence with values ranging from −135 ppm for LaF3 to 700 ppm for LaI3, which represents nearly half of the total lanthanum chemical shift range. The spans of the magnetic shielding tensors also vary widely, from 35 to 650 ppm for the solid LaF3 through LaI3. DFT calculations of the 139La electric field gradient and magnetic shielding tensors have been performed and provide a qualitative interpretation of the trends observed experimentally. 相似文献
115.
P.?K.?Ghosh S.?Das K.?K.?ChattopadhyayEmail author 《Journal of nanoparticle research》2005,7(2-3):219-225
Nanocrystallites of cadmium oxide (CdO) thin films were deposited by sol–gel dip coating technique on glass and Si substrates. XRD and TEM diffraction patterns confirmed the nanocrystalline cubic CdO phase formation. TEM micrograph of the film revealed the manifestation of nano CdO phase with average particle size lying in the range 1.6–9.3 nm. UV–Vis spectrophotometric measurement showed high transparency (nearly 75% in the wavelength range 500–800 nm) of the film with a direct allowed bandgap lying in the range 2.86–3.69 eV. Particle size has also been calculated from the shift of bandgap with that of bulk value for the films for which the particles sizes are comparable to Bohr exitonic radius. The particle size increases with the increase in annealing temperature and also the intensity of XRD peaks increases which implies that better crystallinity takes place at higher temperature.This revised version was published online in August 2005 with a corrected issue number. 相似文献
116.
T.?A.?Prokof’evEmail author B.?A.?Polezhaev A.?V.?Kovalenko 《Journal of Applied Spectroscopy》2005,72(6):865-871
The mechanisms of photoluminescence excitation of Mn2+ ions in ZnS crystals have been investigated on the basis of complex analysis of the temperature dependences of the photoluminescence
and photoluminescence-excitation spectra of ZnS:Mn crystals. The activation energy of a manganese luminescence center was
estimated at Ea = 0.17 ± 0.05 eV. It is shown that Ea represents an energy band with a width ΔEa = 0.1 eV, within which a manganese luminescence center can experience radiationless recombination.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 788–793, November–December, 2005. 相似文献
117.
We describe the construction and operation of a variable temperature (VT) system for a high field fast magic angle spinning (MAS) probe. The probe is used in NMR investigations of biological macromolecules, where stable setting and continuous measurement of the temperature over periods of several days are required in order to prevent sample overheating and degradation. The VT system described is used at and below room temperature. A vortex tube is used to provide cooling in the temperature range of -20 to 20 degrees C, while a liquid nitrogen-cooled heat exchanger is used below -20 degrees C. Using this arrangement, the lowest temperature that is practically achievable is -140 degrees C. Measurement of the air temperature near the spinning rotor is accomplished using a fiber optic thermometer that utilizes the temperature dependence of the absorption edge of GaAs. The absorption edge of GaAs also has a magnetic field dependence that we have measured and corrected for. This dependence was calibrated at several field strengths using the well-known temperature dependence of the (1)H chemical shift difference of the protons in methanol. 相似文献
118.
Mojia Huang 《Journal of the mechanics and physics of solids》2004,52(8):1827-1853
Herein we obtain a formula for the effective elastic stiffness tensor Ceff of an orthorhombic aggregate of cubic crystallites by the perturbation method. The effective elastic stiffness tensor of the polycrystal gives the relationship between volume average stress and volume average strain. Under Voigt's model, Reuss’ model and Man's theory, the elastic constitutive relation accounts for the effect of the orientation distribution function (ODF) up to terms linear in the texture coefficients. However, the formula derived in this paper delineates the effect of crystallographic texture on elastic response and shows quadratic texture dependence. The formula is very simple. We also consider the influence of grain shape to elastic constitutive relations of polycrystals. Some examples are given to compare computational results of the formula with those given by Voigt's model, Reuss's model, the finite element method, and the self-consistent method. In Section 3, we also present an expression of the perturbation displacement field, in which Green's function for an orthorhombic aggregate of cubic crystallites is included. 相似文献
119.
Intermolecular photoinduced electron transfer (PET) in a gas phase was studied using carbazole vapor fluorescence quenching by halomethanes (CHCl3, CH2Br2, CCl4, CHBr3). The fluorescence quenching rate constants k
q changing from 2.3·105 sec–1·torr–1 in mixtures with CHCl3 to 4.6·106 sec–1·torr–1 in mixtures with CHBr3 at a constant temperature of 403 K were estimated. The dependence of the carbazole fluorescence decay rates in the presence of halomethanes on the free energy change G during transfer of the electron from carbazole to halomethanes is considered. It is suggested to take into account the influence of the vibrational energy of the carbazole molecule E
vib and its temperature changes in estimation of the G values. The differences between PET in the gas and liquid phases were analyzed. It is found that for mixtures with CCl4 and CHBr3 the negative temperature dependence of k
q is observed, when the decay rates and efficiencies of the intermolecular PET decreased with temperature increase in the range 403–573 K, i.e. these mixtures the electron transfer is not a barrier-restricted process. 相似文献
120.
David Eisenbud Craig Huneke Bernd Ulrich 《Proceedings of the American Mathematical Society》2003,131(3):701-708
In this paper we show that the Rees algebra can be made into a functor on modules over a ring in a way that extends its classical definition for ideals. The Rees algebra of a module may be computed in terms of a ``maximal' map from to a free module as the image of the map induced by on symmetric algebras. We show that the analytic spread and reductions of can be determined from any embedding of into a free module, and in characteristic 0--but not in positive characteristic!--the Rees algebra itself can be computed from any such embedding.