Platinum‐Catalyzed Cascade Rearrangement Reaction of 1,5‐Diynyl Esters: Unusual Regioselective 1,5‐Hydride Migration

A highly regioselective sequential 1,3‐acyloxy migration/pentannulation/1,5‐hydride migration reaction is disclosed which provides an efficient access to (E)‐2‐vinyl‐3‐oxo‐1‐methyleneindenes under neutral and mild reaction conditions. The migrated hydrogen atom was derived from an unactivated alkyl group, and the long‐range 1,5‐H shift was confirmed through related deuterium experiments.     

基于Agent的动态负载均衡技术及仿真实现

实现负载均衡需要解决三个关键问题，即负载状况的定义、负载探测以及均衡策略。文章分析了现有负载均衡技术存在的问题．这些问题包括负载探测的间接性，负载均衡的单向性、静态性和主观性等；提出一种基于Multi—Agent的动态负载探测技术和均衡策略，给出了相应的结构模型和算法，并进行了仿真试验，结果表明该技术优于其它负载均衡技术。     

逆合成孔径成像激光雷达成像算法

逆合成孔径成像激光雷达是一种能实现运动目标超高分辨实时成像的雷达,它在发射激光信号的基础上,运用逆合成孔径原理对目标进行成像。但激光信号具有极高载频、超大带宽和极短波长的特性,传统的距离-多普勒算法不再适用。在对回波信号特征进行分析的基础上,利用重排维格纳分布和Hough变换对光外差探测后的信号进行时频分析以估计目标的运动速度,构造有效的补偿因子,完成了对回波信号的精确运动补偿,并进一步采用Keystone变换完成对目标散射点的越距离单元徙动校正,实现了对目标的高分辨二维成像。仿真实验验证了成像算法的有效性,并通过与微波波段逆合成孔径雷达的比较,证明了逆合成孔径成像激光雷达可实现对运动目标更快速、更高分辨的成像。     

Enzymatic inhibitory activity of Ficus deltoidea leaf extract on matrix metalloproteinase-2, 8 and 9

Dysregulation of matrix metalloproteinases (MMPs) activity is known in many pathological conditions with which most of the conditions are related to elevate MMPs activities. Ficus deltoidea (FD) is a plant known for its therapeutic properties. In order to evaluate the therapeutic potential of FD leaf extract, we study the enzymatic inhibition properties of FD leaf extract and its major bioactive compounds (vitexin and isovitexin) on a panel of MMPs (MMP-2, MMP-8 and MMP-9) using experimental and computational approaches. FD leaf extract and its major bioactive compounds showed pronounced inhibition activity towards the MMPs tested. Computational docking analysis revealed that vitexin and isovitexin bind to the active site of the three tested MMPs. We also evaluated the cytotoxicity and cell migration inhibition activity of FD leaf extract in the endothelial EA.hy 926 cell line. Conclusively, this study provided additional information on the potential of FD leaf extract for therapeutical application.     

光传送网向光分组交换网演进的策略探讨

光分组交换(OPS)是分组交换技术向光层的渗透和延伸,OPS网是未来光网络中承栽话音和数据等多种业务的理想平台.受IP业务的拉动以及目前不断发展的光交换技术的推动,OPS网络必将有着非常广阔的应用前景.文章描述了OPS传送网的分层结构以及网络组成结构,给出了近期、中期和远期3个发展阶段OPS传送网的分层参考模型,基于该参考模型,探讨了现有光传送网在3个发展阶段向OPS传送网演进的策略.     

从ext2到ext3文件系统转换的实现

日志文件系统ext3具有ext2所不具备的特点和优势,顺利完成从ext2到ext3的转换,是实现ext3文件系统优势之必须。     

相移迁移法在激光超声合成孔径聚焦技术中的应用

通过分析脉冲源激光辐照于工件表面激发的多模式、宽带超声体波信号并结合合成孔径聚焦技术(SAFT),实现了对工件内部微小缺陷的检测、定位和成像。首先基于有限元仿真模拟了激光激发超声波在含缺陷样品中的传播过程,编写了基于相移迁移法(PSM)的SAFT成像算法,然后在实验中使用激光在含缺陷样品表面激发超声波,使用激光测振仪探测超声波,并基于已有算法和探测结果对样品内缺陷进行了检测和定位,以验证算法的正确性。有限元仿真以及实验结果均表明,将激光超声技术与频域SAFT-PSM结合,能够有效地对微小缺陷进行检测和定位,且其图像重构速度快于时域SAFT,可为激光超声无损检测提供更快速的实时技术方案。     

校园计算网格作业自适应调度的研究和实现

由于网格资源具有分布、异构、动态、自治等特性。使得网格作业调度成为网格计算中具有挑战性的任务之一。针对校园高性能计算资源负载不均衡、管理模式不统一的问题，提出了校园计算网格自适应调度系统的解决方案。详细研究了网格作业的白适应调度技术，设计了含有负载均衡能力的资源动态信息收集模型，并给出自适应调度算法。实现了校园范围内高性能计算资源的负载均衡和统一的资源管理。     

Synthesis and anticancer property of one Fe(II) compound based on 5-(3-pyridyl)tetrazole-2-acetic acid

Abstract

Tetrazole-carboxylate ligands are universally considered as multi-functional candidates for the construction of coordination architectures. A 1-D [Fe(pytza)₂(H₂O)₂]_n·2nH₂O (pytza = 5-(3-pyridyl)tetrazole-acetato) has been prepared. In vitro study on Hela cells show that Hpytza is naturally nontoxic while [Fe(pytza)₂(H₂O)₂]_n·2nH₂O shows high toxicity with a half-maximal inhibitory concentration (IC₅₀) of 6.3?×?10^?5 M. In addition, the compound can effectively inhibit the migration of Hela cells.