Determination of the rheological behavior of epoxy–amine thermosets by dynamic mechanical analysis: Isothermal methods versus nonisothermal methods

The reticulation process of an epoxy resin using an amine as a cure agent was studied at different temperatures and concentrations of the cure agent with dynamic mechanical thermal analysis. The study was performed under both isothermal and nonisothermal conditions, and a temperature–time–transformation diagram was obtained. The measurements from the two modes gave similar results, although the nonisothermal mode required fewer experiments. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1965–1977, 2003     

T(x) phase diagram of the Cu2Se-Al2Se3 system

Twenty alloys of various compositions in the Cu₂Se-Al₂Se₃ system were prepared and investigated. The T(x) phase diagram of the Cu₂Se-Al₂Se₃ system was obtained from x-ray diffraction, differential thermal analysis, and microstructure investigation for the first time. The homogeneity region of the CuAlSe₂ semiconducting compound was established. Previous articles by this author were presented with the spelling of his name as B.V. Korzun.     

四个麦芽品质性状的杂种优势和相关分析

本文对四个主要麦芽品质性状—a一淀粉酶活力、麦芽汁粘度、麦芽汁色度和搪化力进行了杂种优势和相关分析.(1)相对优势结果表明，在84个组合次中，呈正向优势的46个，占54.76男，负向优势34个，占40.48男，无显性4个，占4.75男;(2)四个品质性状的中亲优势平均值分别为一6.117、一9.965 40.452和一。.545s a-淀粉酶活力和糖化力的超高亲优势分别为一14.578和一8.201,麦芽汁粘度和色度的超低亲优势分别为5.442和70.455.四个性状杂种优势的变异系数均很大.(3)麦芽汁色度的F，对MP的回归系数(B)和相关系数(r)均达显著水平，分别为。..43和0.50，麦芽汁粘度的相关系数达显著水平，为一。.45,其余均未达显著水平，(4)除麦芽汁色度性状外，另三个性状的中亲优势、超亲优势和特殊配合力的相关均达显著或极显著水平.(5)四个麦芽品质性状间的相关结果表明，仅有a-淀粉酶活力和麦芽汁粘度间呈极显著负相关(r=一0.56').最后，文章根据实验结果，就啤酒大麦麦芽品质改良的遗传育种及其杂种优势应用进行了初步讨论.     

Monitoring Power Dissipation for Fault Detection

In this paper, we suggest that the dynamic power dissipation of acircuit can be used for fault detection. Even those faults which do notaffect static power dissipation can be detected by monitoring dynamic powerdissipation. We discuss how stuck-at, stuck-open, and redundant faults maybe detected by monitoring dynamic power dissipation. In many cases, theFourier spectra of the supply currents in the good and faulty circuits willalso be very different. Further, specific tests can be applied so as toimprove fault coverage. Power monitoring is verified using simulation, andalso experimentally, for example circuits.     

HL—1装置SiC涂层辐照实验的表面分析

本文应用表面分析技术研究HL-1装置中SiC涂层的等离子体辐照性能。结果表明,SiC材料应用于孔栏和壁涂层有利于减少杂质和提高等离子体品质。     

无源软开关电路拓扑的研究

提出一个研究无源软开关电路的新技术方法;其特征是对基本的单管隔离型PWM DC/DC变换器进行类比分析,由此直接导出可行的缓冲能量再生复位电路.该新方法能使DC/DC PWM硬开关变换器转变为软开关变换器.以新型Boost无源软开关变换器为例,进行了电路理论分析与中功率样机的实验测试;结果表明此新变换器具有较宽的软开关工作范围、较低的电应力、较小的缓冲元件量值等特点.由此认为,这种研究方法推导简单、物理意义清晰,还能深入地研究无源软开关的新电路拓扑.     

A density functional theory computational study of the role of ligand on the stability of CuI and CuII species associated with ATRP and SET‐LRP

Atom transfer radical polymerization (ATRP) and single electron‐transfer living radical polymerization (SET‐LRP) both utilize copper complexes of various oxidation states with N‐ligands to perform their respective activation and deactivation steps. Herein, we utilize DFT (B3YLP) methods to determine the preferred ligand‐binding geometries for Cu/N‐ligand complexes related to ATRP and SET‐LRP. We find that those ligands capable of achieving tetrahedral complexes with Cu^I and trigonal bipyramidal with axial halide complexes with [Cu^IIX]⁺ have higher energies of stabilization. We were able to correlate calculated preferential stabilization of [Cu^IIX]⁺ with those ligands that perform best in SET‐LRP. A crude calculation of energy of disproportionation revealed that the same preferential binding of [Cu^IIX]⁺ results in increased propensity for disproportionation. Finally, by examining the relative energies of the basic steps of ATRP and SET‐LRP, we were able to rationalize the transition from the ATRP mechanism to the SET‐LRP mechanism as we transition from typical nonpolar ATRP solvents to polar SET‐LRP solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4950–4964, 2007     

An integer goal programming model for hazardous waste treatment and disposal

The improper handling and disposal of hazardous wastes cause threats to human health and the environment. One reason for the improper handling and disposal of these wastes is that not much consideration is usually given to the logistical aspects of hazardous waste systems. In this paper an integer goal programming model is developed that takes into consideration the multiple goals and needs of many groups involved in managing and planning hazardous waste systems. The model can easily be implemented and can be used to address many of the issues related to facility location, recycling, treatment, and disposal of hazardous wastes.     

热电厂锅炉运行技术指标的微机管理

本文从锅炉运行技术指标台帐微机管理的实际出发，提出了热量计算中主蒸汽流量修正系数Ｃ和给水焓值Ｚ两项参数回归的计算公式，提高了热量计算数值精度。     

超短脉冲光电导开关的全波分析

本文采用时域有限差分法直接求解包含传导电流的三维麦克斯韦方程组,对超短脉冲光电导开关进行全波分析,分析中考虑了静电场影响,采用了比较精确的光电导数学模型。本文还讨论了开关输出信号的模式组成和激光脉冲能量、脉宽对开关性能的影响,并给出了光电导开关响应在不同时刻的三维图形。