玻璃衬底上制备GaN薄膜的研究进展

近年来,GaN基发光二极管(LED)的发展异常迅速,以玻璃为衬底的LED具有成本低、可大面积化生产等优点而引起了国内外许多科研机构的广泛研究兴趣.但由于普通玻璃较低的软化温度(500～ 600℃)以及与GaN之间存在较大的晶格失配问题,一直阻碍其发展.重点综述了玻璃衬底上生长GaN薄膜的方法以及改善外延层晶体质量的技术.分别介绍了两种在普通玻璃上生长GaN的方法,即低温生长和局部加热生长,同时详述了采用缓冲层和横向外延过生长(ELO)技术对外延GaN晶体质量的影响.对局部加热、ELO等技术在玻璃衬底LED方面的应用进行了分析和预测,认为以玻璃为衬底的LED终会取得快速地发展.     

基于ATmega128单片机的点阵广告屏设计

为了实现AVR单片机对LED点阵显示系统的控制,采用ATmega128作为下位机MCU,通过接收上位机发送的显示内容和显示模式的串行信号,实现16×32高亮点阵屏的一行多个文字或符号的显示。系统实际运行稳定,显示效果良好,便于多块点阵屏的扩展,作为高职学生的大学生实践创新有较高的实践意义。     

基于双同步斩波模式的LED声控灯驱动电源设计

提出了基于双同步斩波模式的微功耗LED声控灯驱动电源设计方法。该驱动电源用一个单片机控制两个开关管分别为主电源和待机电源提供工作电流。主电源采用全波斩波工作模式为LED灯组提供工作电流;待机电源采用半波斩波工作模式,从而大幅降低了待机功耗。该驱动电源结构简单,可在50~60 Hz频率的180~250 V的宽电压范围内工作,具有恒流驱动功能和微功耗特性,且稳定可靠和较高的性价比。     

Failure analysis on reflector blackening between lead frame electrodes in LEDs under WHTOL test

Blackening induced lumen decay in a QFN LED after WHTOL reliability test was reported and analyzed in this paper. A new LED blackening failure mechanism was proposed based on solid experimental results. We concluded that the failure process underwent delamination between lead frame and reflector polymer composites followed by chemical penetration, composite corrosion, silver migration, and finally caused blackening failure. Delamination and corrosive de-flash agent were the key factors for the failure mode. Besides, we also estimated the influence of the failure to the optical performance through simulation. Apart from other reported factors, this study highlighted that both composite corrosion and Ag migration could generate serious illumination decrease as well. The outcome of this study is valuable for LED manufacture and quality control in the future.     

提升LED驱动芯片视觉刷新率的逻辑电路设计

为了提升LED显示屏的画面质量,设计了能提高LED显示屏视觉刷新率的逻辑电路。该电路将一个显示周期分为32段,每一段包含有128个灰度时钟周期,占空比由12位灰度数据控制。逻辑电路产生的PWM和传统的PWM相比能提高视觉刷新率,最高能将视觉刷新率提高至32倍;能弥补S-PWM( Scrambled-PWM)在灰度数据低时视觉刷新率低的不足。在Cadence软件下进行设计仿真,并在开发板上进行了验证设计的可行性。     

双通道PWM的冷暖白光LED混色模型研究

LED光色度的动态调节是实现智能照明的基础, 采用冷暖白光LED和双通道脉冲宽度调制(PWM)法,基于1931CIE标准建立混合光源模型,推导出混合光源色坐标、相关色温 、最大亮度、显色指数与双通道调制脉冲 占空比比值的关系式。采用暖白光(色温3282 K)和冷白光(色温12930K)两种白光LED进行 混色实验, 通过微控制器输出PWM信号控制LED驱动电源,改变冷色光和暖色光的比重,得到的混合 光源色坐 标、最大亮度、相关色温及显色指数值与理论计算值吻合很好,证明了理论模型的正确性。 理论和实验结 果还表明,混合光源在双通道调制脉冲占空比比值为1的附近可得到低色温、高显色性和大 光通量的混合白光。     

基于嵌入式的工业控制人机界面系统研究

针对工业控制系统网络化和良好人机交互性的需求,构建和开发了基于ARM9微处理器的通用工业控制人机界面系统。硬件部分主要讨论了以S3C2440微处理器为核心的硬件电路设计,外围电路模块包括SDRAM及Flash存储器电路、以太网电路、RS-232/RS-422电路、触摸屏及LCD接口等电路,在分析了硬件系统信号完整性的前提下,完成了6层PCB的设计工作。软件部分主要研究了U-Boot移植和内核裁剪技术,编写了相关的硬件设备驱动程序,设计了基于QT/Embedded的人机界面和相关应用程序。论文研究最终实现了工业控制系统的人机交互和控制需求。     

A green-emitting α-substituted β-diketonate Tb3+ phosphor for ultraviolet LED-based solid-state lighting

The α-substituted β-diketonate [Ln(3Cl-acac)₃(H₂O)₂] [Ln = Tb, Gd] complexes (with 3Cl-acac^– being 3-chloro-2,4-pentanedionate) were characterized by elemental analysis, infrared, ultraviolet (UV)-visible and photoluminescence spectroscopies. For comparison purposes regarding photoluminescence, the well-known [Tb(acac)₃(H₂O)₂] complex was also synthesized. By considering the phosphorescence spectra of [Gd(3Cl-acac)₃(H₂O)₂], the effect of chloride replacement of hydrogen on the triplet state energy of the 3Cl-acac ligand was revealed. To support the interpretation and rationalization of the experimental results, Time-dependent DFT calculations were performed on Tb(3Cl-acac)₃(H₂O)₂. Additionally, the possibility of Tb(3Cl-acac)₃(H₂O)₂ to be used as potential green-emitting phosphor material for solid-sate light emitting diodes was evaluated. A prototype was successfully fabricated coating a near-UV LED (370 nm) with the Tb(3Cl-acac)₃(H₂O)₂ complex.     

Laguncularia racemosa Phenolics Profiling by Three-Phase Solvent System Step-Gradient Using High-Performance Countercurrent Chromatography with Off-Line Electrospray Mass-Spectrometry Detection

The detailed metabolite profiling of Laguncularia racemosa was accomplished by high-performance countercurrent chromatography (HPCCC) using the three-phase system n-hexane–tert-butyl methyl ether–acetonitrile–water 2:3:3:2 (v/v/v/v) in step-gradient elution mode. The gradient elution was adjusted to the chemical complexity of the L. racemosa ethyl acetate partition and strongly improved the polarity range of chromatography. The three-phase solvent system was chosen for the gradient to avoid equilibrium problems when changing mobile phase compositions encountered between the gradient steps. The tentative recognition of metabolites including the identification of novel ones was possible due to the off-line injection of fractions to electrospray ionization mass spectrometry (ESI-MS/MS) in the sequence of recovery. The off-line hyphenation profiling experiment of HPCCC and ESI-MS projected the preparative elution by selected single ion traces in the negative ionization mode. Co-elution effects were monitored and MS/MS fragmentation data of more than 100 substances were used for structural characterization and identification. The metabolite profile in the L. racemosa extract comprised flavonoids, hydrolysable tannins, condensed tannins and low molecular weight polyphenols.     

Built-in piezoelectric field improved photocatalytic performance of nanoflower-like Bi2WO6 using low-power white LEDs

Photocatalysis technology has been proved to be a potential strategy for removal of organic dyes, however high-power light sources are generally necessary to initiate photocatalytic reaction. In this work, we employed an excellent photocatalyst of Bi₂WO₆ with visible light harvest and meanwhile an intrinsic ferroelectricity, which realized the efficient degradation of organic dye via the synergetic photopiezocatalysis. Through coupling the illumination by a low-power (9 W) LED and the ultrasonic vibration (120 W) by an ultrasonic cleaner, the nanoflower-like Bi₂WO₆ composed of ultrathin nanosheets showed a much more enhanced photopiezocatalysis performance for purification of organic dye than the individual photocatalysis and piezocatalysis. Furthermore, the high mineralization efficiency and the good durability of the Bi₂WO₆ catalyst were demonstrated. The possible mechanism of photopiezocatalysis was finally proposed, where the ultrasound-induced piezoelectric field in Bi₂WO₆ drove photo-generated electrons and holes to diffuse along opposite directions, consequently promoting the separation efficiency of charge carriers. This work indicates that the synergetic photopiezocatalysis by coupling irradiation and ultrasonic vibration is a promising strategy to purify organic pollutants in wastewater.