Simple Silole‐Containing Polyfluorene for White Electroluminescence with Simultaneous Blue,Green, and Red Emission

Novel conjugated silole‐containing polyfluorenes, with green‐ and red‐emissive siloles on the backbone of the blue‐emissive polyfluorene are synthesized for white light electroluminescence (EL) from a single polymer with simultaneous red, green, and blue (RGB) emission. The CIE coordinates (0.33, 0.36) of the white light EL spectra are very close to that for pure white light (0.33, 0.33). The EL spectra are also quite stable at different applied voltages or brightness. The relative intensities for the three RGB peaks, at 450, 505, and 574 nm, were 0.94, 1, and 0.97, respectively, which demonstrates a balanced simultaneous RGB emission. A maximum luminous efficiency of 2.03 cd · A⁻¹ for a brightness of 344 cd · m⁻², and a luminous efficiency of 1.86 cd · A⁻¹ for a more practical brightness of 2 703 cd · m⁻², were achieved.

     

基于正交试验法的显微镜上照明设计

根据LED光源特性和目标面光强的分布要求,采用正交试验法,对显微镜的LED照明系统进行优化设计。利用TracePro软件对所设计的系统进行光线追迹仿真,结果表明,在Φ50mm的范围内照度均匀性达到83.7%,能量利用率达到52.8%。该结构简单,成本低,易于实现。     

基于相关分析的LED路灯光强分布测试步距角优化研究

优化LED路灯光强分布测试系统的测试步距角可以较大程度地提高LED路灯测试的效率。选择不同的测试步距角对LED路灯的光强分布进行测试,将1°测试步距角所测得的路灯光强分布视为真值,采用相关分析的方法研究在较大步距角下所测得的路灯光强分布与真值之间的近似程度。研究结果显示,当相关系数要求在98%左右时,可以选择15°测试步距角对LED路灯的光强分布进行测试,相对于真值测试,在此步距下LED路灯的测试时间减少了98%以上,极大地提高了测试效率。     

Perylene polyphenylmethylsiloxanes for optoelectronic applications

The incorporation of fluorescent organic dyes in an encapsulating matrix represents a route to generate stable and processable materials for optoelectronic devices. Here, we present a method to embed perylene dyes into a high refractive index (HRI) polysiloxane matrix applying an allyl functionalized perylene dye and hydrosilylation chemistry. In a first approach, the dye molecules were covalently integrated into the backbone of linear polyphenylmethylsiloxane chains. The fluorescent and liquid polymers were synthesized with molecular weights from 5660 up to 8400 g mol^?1. In a second approach, the dye itself was used as a cross‐linking agent between linear polyphenylmethylsiloxane chains. These preformed fluorescent batch polymers are liquids with dye concentrations between 0.025 and 8 wt %. The applied synthetic methods incorporated the dye covalently into the polymer structure and avoided the crystallization of the dye molecules and thus the formation of excimers, which would reduce the optical emission. The resulting products can be easily incorporated into curable commercially available HRI polyphenylmethylsiloxane resins. The formed materials are ideal LED encapsulants with a solid and flexible consistency, a uniform dispersion of the dyes, and adjustable mechanical properties, realized by changing the amount of perylene polymers. Further properties of the obtained materials are thermal stabilities up to 478 °C, quantum yields larger than 0.97, and high photostabilities. Thus, the covalent integration of dyes into polyphenylsiloxane structures represents a possible route for the stabilization of the organic dyes against the extreme irradiance and thermal conditions in LED applications. © 2019 The Authors. Journal of Polymer Science Part B: Polymer Physics published by Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 1062–1073     

镁合金用水溶性脱模剂 MK-300、MK-400的研制及其性能评价

研制开发了镁合金压铸用水溶性脱模剂MK-300、MK-400,可在高倍稀释的条件下使用,实验及实用结果显示MK-300、MK-400的脱模性、润滑性、高温附着性、模具保温性、模具残留物、铸件喷涂适应性、废液处理等均取得了满意的效果。     

SrSi2O2N2∶Eu2+荧光粉的制备及性能研究

以SrCO3,Si3N4,Eu2O3为原料,在N2气氛下,采用自还原高温固相法制备了SrSi2O2N2:Eu2+荧光粉。研究了该荧光粉的物相结构、发光性能和晶体形貌,同时对比在不同气氛下合成的荧光粉。结果表明,在N2气氛与N2/H2气氛下分别合成的SrSi2O2N2:Eu2+荧光粉物相结构和光谱特性基本一致。显示出合成了主晶相SrSi2O2N2,但还含有少量未知的中间项。Eu2+浓度的变化不影响激发状态,而发射光谱的波长在Eu2+浓度为1mol%-20mol%之间,从530 nm的绿光红移至550 nm的黄绿光区域。同时,激发光谱覆盖的范围宽,均能有效的被UV或蓝光激发,这意味着该类荧光粉在白光LED方面有可能得到广泛的应用。     

一种新型黄色荧光类水滑石材料的制备及表征

用适量的Zn(Ⅱ)取代镁铝水滑石中的Mg(Ⅱ),同时将一定量的2-对联苯基-8-羟基喹啉分散到类水滑石层间的亲油性阴离子中,使其与层板表面上的Zn(Ⅱ)配位,用一步法合成、组装得到一类新型黄色荧光类水滑石复合物(Zn-(HQ-4-biPh)-HTlc)。采用荧光光谱、红外光谱、X射线衍射、扫描电子显微镜和热分析等对其进行了表征。研究结果表明,Zn-(HQ-4-biPh)-HTlc在蓝光(481 nm)激发下可发出黄色荧光(554 nm),与其相应的含锌配合物(Zn[2-(p-biph)-8-Q-O]2)相比,不仅可节省配体用量,而且具有更高的发光强度和更好的热稳定性,有望在白光LED等光电领域得到应用。     

LED光诱导化学发光法检测饮料中的核黄素

以化学发光法为基础,建立了以发光二极管(LED)诱导化学发光体系(LED-CL)检测饮料中核黄素含量的分析方法。样品溶液与鲁米诺溶液混合后由蠕动泵带出,经LED灯照射后产生化学发光,产生的化学发光信号由光电检测器检测。核黄素浓度检测线性范围为0.39~79.56μg/L(R≥0.999 7),加标回收率为99.3%~103%,可用于饮料中核黄素的检测。     

Built-in piezoelectric field improved photocatalytic performance of nanoflower-like Bi2WO6 using low-power white LEDs

Photocatalysis technology has been proved to be a potential strategy for removal of organic dyes, however high-power light sources are generally necessary to initiate photocatalytic reaction. In this work, we employed an excellent photocatalyst of Bi₂WO₆ with visible light harvest and meanwhile an intrinsic ferroelectricity, which realized the efficient degradation of organic dye via the synergetic photopiezocatalysis. Through coupling the illumination by a low-power (9 W) LED and the ultrasonic vibration (120 W) by an ultrasonic cleaner, the nanoflower-like Bi₂WO₆ composed of ultrathin nanosheets showed a much more enhanced photopiezocatalysis performance for purification of organic dye than the individual photocatalysis and piezocatalysis. Furthermore, the high mineralization efficiency and the good durability of the Bi₂WO₆ catalyst were demonstrated. The possible mechanism of photopiezocatalysis was finally proposed, where the ultrasound-induced piezoelectric field in Bi₂WO₆ drove photo-generated electrons and holes to diffuse along opposite directions, consequently promoting the separation efficiency of charge carriers. This work indicates that the synergetic photopiezocatalysis by coupling irradiation and ultrasonic vibration is a promising strategy to purify organic pollutants in wastewater.     

Geometry dependence of the elongation behavior of a polypropylene melt through a micro die

A series of rheological experiments was performed for a polypropylene (PP) melt to explore its elongation behavior through a capillary die. Using an advanced twin-bore capillary rheometer with dies measuring 1.0, 0.5, and 0.25 mm in diameter, the experiments were performed at 210, 220, and 230 °C. The results indicated that the temperature of the PP melt had a significant effect on its extensional viscosity. The different decreases in the extensional viscosity values in the tested dies revealed the geometry dependence of the extensional viscosity. In the case of PP in the 0.25 mm die at 210 °C, the extensional viscosity values under different extensional strain rates were much higher than those in the other dies. Only in the 1.0 mm die did the relationship between the extensional viscosity of PP and its temperature obey the Arrhenius equation due to the larger die size which related to a slight size effect on its elongation behavior. The calculated deviations of the extensional viscosity in the tested dies demonstrated that the increasing pressure applied to the PP melt in the micro channel was related to the geometry dependence of the elongation behavior of the PP melt. The change in the extensional viscosity eventually relied on the interaction of the die geometry, the temperature, and the extensional stress of the PP melt.