基于网格技术的企业应用系统集成研究

针对当前企业的大量异构应用系统不能互联互通、资源不能共享、数据不能联动的现状。利用基于OGSA体系结构的最新网格开发工具GT4构建一个数据网格平台来集成现有应用系统。并详细描述实现的技术路线,给出整个系统的体系结构的描述。对其中的数据一致性维护、服务选择和系统异构性的消除等关键技术提供了解决方法。     

Three new dibromopyrrole alkaloids from the South China Sea sponge Agelas nemoechinata

Three new dibromopyrrole alkaloids, 9-N-methylcylindradine A (1), 1-N-methylugibohlin (2), nemoechine H (3), together with one known dibromopyrrole alkaloid N-methyldibromoisophakellin (4) were isolated from the South China Sea sponge Agelas nemoechinata. Their structures were elucidated by comprehensive spectroscopic methods including HRESIMS and NMR, and the absolute configuration of compound 1 was further confirmed by comparison of optical rotation. Compound 3 exhibited moderate cytotoxic activity against K562 and L-02 with IC₅₀ values of 6.1 μM and 12.3 μM, respectively.     

Efficient activation of peroxymonosulfate by hollow cobalt hydroxide for degradation of ibuprofen and theoretical study

Hollow microsphere structure cobalt hydroxide (h-Co(OH)₂) was synthesized via an optimized solvothermal-hydrothermal process and applied to activate peroxymonosulfate (PMS) for degradation of a typical pharmaceutically active compound, ibuprofen (IBP). The material characterizations confirmed the presence of the microscale hollow spheres with thin nanosheets shell in h-Co(OH)₂, and the crystalline phase was assigned to α-Co(OH)₂. h-Co(OH)₂ could efficiently activate PMS for radicals production, and 98.6% of IBP was degraded at 10 min. The activation of PMS by h-Co(OH)₂ was a pH-independent process, and pH 7 was the optimum condition for the activation-degradation system. Scavenger quenching test indicated that the sulfate radical (SO₄^{? ?}) was the primary reactive oxygen species for IBP degradation, which contributed to 75.7%. Fukui index (f ^?) based on density functional theory (DFT) calculation predicted the active sites of IBP molecule for SO₄^{? ?} attack, and then IBP degradation pathway was proposed by means of intermediates identification and theoretical calculation. The developed hollow Co(OH)₂ used to efficiently activate PMS is promising and innovative alternative for organic contaminants removal from water and wastewater.     

Nd(OTf)3-catalyzed intramolecular-intermolecular cascade cyclization reaction: An access to phenanthro[9,10-b]furan derivatives

An intramolecular-intermolecular cascade cyclization reaction via multi metal-carbene intermediates has been developed. This reaction uses catalytic amount of Nd(OTf)₃, which actives both alkyne and aldehyde moieties. This protocol provides a novel strategy for the synthesis of phenanthro[9,10-b]furans.     

多方量子密钥管理协议设计与安全性分析

针对多个用户之间多功能、多任务的保密通信需求,利用d级Bell态和猫态的纠缠交换,设计了一种能在一次执行过程中同时实现密钥生成、密钥分发和密钥备份功能的新型量子密钥管理(Quantum Key Management,QKM)协议,并将协议从面向两个管理者和两个用户的特定方案推广到含有L个管理者和N个用户的一般情形。最后,详细论证了该协议的安全性能。     

太赫兹通信关键技术与发展愿景

6G研究已启动,太赫兹通信技术以其支持超大带宽资源和超高通信速率等技术特点成为未来6G愿景实现的关键候选技术。从太赫兹通信技术特点出发,讨论了太赫兹通信未来可能的应用场景,系统分析了太赫兹通信的关键技术方向、产业发展现状与面临挑战,最后提出了未来太赫兹通信技术的目标愿景与发展建议。     

激光重熔对Ni/WC涂层组织结构的改善机制研究

为了进一步探讨激光重熔等离子喷涂金属陶瓷涂层的组织与性能。本文通过等离子喷涂设备在45钢表面上制备了Ni/WC金属陶瓷涂层,再进行激光重熔处理,然后利用SEM、XRD、Photoshop软件及显微硬度测试仪等分析测试手段研究了该涂层在激光重熔前后的组织性能变化。结果表明:激光重熔前涂层为典型的层状结构,基体与涂层的结合面为机械结合,涂层内有大量未熔WC颗粒,且XRD检测其高温作用使得喷涂颗粒发生分解,分解出的C元素与其他元素发生反应生成新的化合物,丰富了涂层的硬质相;激光重熔后涂层中颗粒细化,分布均匀且能消除涂层中大部分孔隙和WC团聚。WC再次发生分解,生成新的硬质相,与周围的Ni形成“软基相+硬质点”的组合分布,基体与涂层的结合方式由机械结合转变为冶金结合。孔隙率由7.02%降到了3.08%,显微硬度也相应提高,且涂层显微硬度比基体高了255HV。     

Simultaneous Prediction for Multiple Key Performance Indicators in Semiconductor Wafer Fabrication

The prediction and key factors identification for lot Cycle time (CT) and Equipment utilization (EU) which remain the Key performance indicators (KPI)are vital for multi-objective optimization in semiconductor manufacturing industry.This paper proposes a prediction methodology which predicts CT and EU simultaneously and identifies their key factors.Bayesian neural network (BNN) is used to establish the simultaneous prediction model for Multiple key performance indicators (MKPI),and Bayes theorem is key solution in model complexity controlling.The closed-loop structure is built to keep the stability of MKPI prediction model and the weight analysis method is the basis of identifying the key factors for CT and EU.Compared with Artificial neural network (ANN)and Selective naive Bayesian classifier (SNBC),the simulation results of the prediction method of BNN are proved to be more feasible and effective.The prediction accuracy of BNN has been obviously improved than ANN and SNBC.