Unusual conformation of molecular cylindrical brushes strongly adsorbed on a flat solid surface

Conformational properties of comb-like polymers strongly adsorbed on a flat solid surface were investigated using computer simulation and scanning force microscopy. The computer simulation showed that the macromolecules with asymmetric distribution of the side chains relatively to the backbone are effectively in a collapsed state even under conditions of a good solvent. They formed peculiar helical superstructures which could be observed by scanning force microscopy of cylindrical brushes of polymethylmethacrylate on mica. Received 13 September 1999     

A Novel Grounded Inductor Realization Using a Minimum Number of Active and Passive Components

In this study, we present a new topology for realizing a grounded inductor employing only a single current conveyor, called a negative‐type modified inverting second‐generation current conveyor (MICCII‐), and a minimum number of passive components, two resistors, and one capacitor. The non‐ideality effects of the MICCII‐on a simulated inductor are investigated. To demonstrate the performance of the presented inductance simulator, we use it to construct a third order Butterworth high‐pass filter and a parallel resonant circuit. Simulation results are given to confirm the theoretical analysis.     

1V电源的CMOS开关电容滤波器

本文设计实现了一种低压的开关电容滤波器,该电路采用上华0.8微米标准CMOS工艺实现.本电路是基于一种新的时钟倍增电路实现的一个双二阶带通滤波器,测试结果表明该带通滤波器可以在1V电源电压下正常工作,测试结果与仿真一致.     

用多色菲涅耳全息滤波器作彩色图像特征识别

本文在用多色匹配滤波器(MSF)作彩色图像相关检测和用菲涅耳全息滤波器(FHF)作无透镜强度相关的基础上,提出一种把两者结合起来的技术,即用多色菲涅耳全息滤波器实现彩色图像的相关检测.     

Whole-wafer fabrication process for three-terminal double stacked tunnel junctions

A new fabrication process for three-terminal superconducting devices consisting of two Josephson junctions in a stacked configuration is reported. The process is based on the deposition of the whole Nb/Al_xO_y/Nb-Al/Al_xO_y/Nb multilayer on a Si crystalline wafer without any vacuum breaking. Lift-off techniques, anodization processes and a SiO film deposition have been adopted for patterning and insulating the two tunnel stacked junctions. Devices have been characterized in terms of current-voltage (I-V) curves and Josephson critical current vs. the externally applied magnetic field. They show high quality factors (V _m values up to 65 mV at 4.2 K), and good current uniformity. Received 5 June 2001     

Kinetic model of gas phase polymerization of 1,3-butadiene catalyzed by supported rare earth coordination system

Gas phase polymerization of 1,3-butadiene (Bd) catalyzed by supported rare earth coordination system is studied and a new kinetic model is proposed. Four elementary reactions or processes: the process of exposure and activation of potential active catalytic center, propagation, deactivation and chain transfer reaction to alkyl aluminum, are considered in this model. Some important parameters, such as monomer-consuming rate, are well expressed as the functions of macroscopic polymerization conditions such as pressure, temperature, and duration. The model can simulate the whole polymerization procedure satisfactorily.     

Whither tube theory: From believing to measuring

This short contribution examines the difficulties that have not yet been fully overcome in the many developments made from the simplest (and original) tube model for entangled polymers.     

Molecular modeling, theoretical calculations and property evaluation of three muscarinic agonists. X-ray structures of LU 25-109 and WAL 2014

LU 25-109 (II) and WAL 2014 (talsaclidine, III) are two M1 muscarinic agonists chemically related to the natural substance arecoline (I). All these compounds have beneficial effects on memory and cognition in animals and humans, and they have been proposed in the treatment of Alzheimer's disease, but only III will likely find a place in therapy. In this work we have investigated the solid state structures of II and III, and the X-ray structures of the two molecules and of the parent compound I have been used to input a series of computational chemistry efforts.

In particular, the X-ray geometries have been manipulated to model 20 molecular structures (1–20) which have been submitted to ab initio, semiempirical quantum mechanics and molecular mechanics calculations. The conformational space accessible to the 20 structures has been assessed by means of potential energy maps. The reactivities of 1–20 have been estimated by examining at the graphics terminal the composition and the extension of the frontier orbitals (HOMOs and LUMOs) and of the molecular electrostatic potential. The information obtained has been interpreted to explain the different degrees of activity shown by I–III. Our data indicate that III has better in vivo activity for its intermediate size, less polar surface, conformational rigidity and orientation of reactive domains.