基于MSP430的车载防醉驾安全系统设计

针对目前交警使用手持式酒精测试仪,导致检查范围极为狭窄的缺陷,设计了车载防醉驾系统。利用32位的低功耗单片机MSP430F149为主控芯片,通过检测模块对对酒精浓度实时分析并送LCD12864显示,对酒精浓度超标则控制汽车点火并报警电路。仿真及实验电路的软硬件联合调试证明该设计能全面达到防止醉酒驾驶的目的,具有一定的实用性和推广价值。     

Evidence for a second,local contact condition for a planar electric double layer containing size and valency asymmetric ions

A generalised form of a local contact condition for the charge profile in a primitive model planar double layer [Bhuiyan, Outhwaite, and Henderson, Mol. Phys. 107, 343 (2009)] at low electrode charge is examined for completely asymmetric, binary electrolytes. The cation and anion sizes are taken to be different from each other with the valencies being 2⁺:1^? or 1⁺:2^?, while the electrode surface charge density is varied from being negative through zero to being positive. Monte Carlo simulation data obtained for such double layer systems at varying ionic radius ratios and electrolyte concentrations suggest the generalised contact relation to be valid at low charge on the electrode.     

The quadrupole–quadrupole polarizability of a non-magnetic molecule

The quadrupole–quadrupole polarizability of a molecule introduced by Buckingham is not a unique molecular property, in the sense that it depends on an arbitrary choice of the origin of the molecular coordinates. To obtain a physically acceptable form of this property for a non-magnetic molecule, a linear combination is taken of molecular polarizabilities of the relevant multipole order (electric octopole-magnetic quadrupole). By requiring this combination to possess the desired space–time and symmetry properties, as well as origin independence, an acceptable quadrupole–quadrupole polarizability is obtained. Expressions are presented for the components of this polarizability for molecules of certain symmetries.     

CASPT2 and CCSD(T) calculations of dipole moments and polarizabilities of acetone in excited states

The acetone molecule is investigated in its ground state and valence ^1,3n-π*, ^1,3π-π*, and ^1,3σ-π* excited states and Rydberg ^1,3n-3s, ^1,3π-3?, ^1,3n-3p_y and ^1,3π-3p_y states using the CASSCF, CASPT2, and CCSD(T) methods. Equilibrium geometries of excited states are obtained and their changes with respect to the ground state are discussed. For most excited states the C_2v symmetry of the ground state is lowered to the C_s symmetry. A series of valence vertical and adiabatic excitation energies is presented along with excitation energies for Rydberg states. The main body of the paper contains Finite-Field Perturbation Theory (FFPT) calculations of electric properties of the vertically as well as geometry relaxed excited states. Dipole moments of valence excited states decrease significantly upon excitation, being about one half of the ground state dipole moment. Polarizabilities usually change upon excitation much less (increase by about 30%) but hyperpolarizabilities are enhanced up to one or two orders of magnitude. The orientation of the dipole moment is reversed in some vertically excited Rydberg states. Properties of the ground and excited states are discussed considering alterations of the electronic structure and shifts in the geometry.     

An internally heated composite gasket for diamond-anvil cells using the pressure-chamber wall as the heating element

The implementation of a heating element to a composite gasket for high-temperature applications in the diamond-anvil cell was developed based on a double-gasket assemblage. The heating element is a thin platinum wall that covers the central borehole of the metal–ceramic–metal composite gasket and interconnects the two metal component parts of the gasket. Applying electric powers up to 35 W to the two gasket metal components result in ring-like heating around the sample inside the pressure chamber with temperatures exceeding ～2000 K in individual cases. The ring-like distribution of the maximum temperature located at the pressure-chamber wall facilitates a homogeneous temperature distribution at the sample position. As a consequence of the concentration of the heating power to the pressure chamber region, gradients of surface temperatures, both at the gasket and the diamond anvil, appear to be more pronounced compared with those known for classical external electrical heating. Apart from the tests of the mechanical stability on high-pressure operation in the diamond anvil cell at room temperature, the influence of the anvils in contact with the gasket on the characteristic power–temperature curves, temperature gradients and thermal equilibration resulting from changes in electrical power settings have been evaluated within the scope of a series of experimental investigations.     

不同沙粒底面下气泡脉动特性实验研究

通过高速摄影系统对电火花气泡与不同沙粒底面间的相互作用进行了实验研究,并改变气泡与沙粒底面之间的距离.实验结果表明:气泡在与沙粒底面的相互作用中会产生两种明显不同的现象,即形成与近刚性壁面类似的气泡射流以及“蘑菇状”气泡,“蘑菇状”气泡撕裂形成两个气泡,随后产生两个反方向的沿轴线方向的射流.沙粒底面边界具有刚性与弹性两种特征.另外,随着气泡与沙粒底面之间的距离d的增大,气泡脉动周期先增大然后减小,存在气泡脉动周期峰值.对于不同的沙粒底面边界,出现气泡脉动周期峰值的距离d随着沙底粒径的增大而越小.     

基于最小电压法的超声换能器谐振频率自动跟踪*

首先分析了最大电流法跟踪超声换能器谐振频率的原理及应用范围。研究了基于由串联电感和并联电容匹配电路下,不同频率时换能器两端电压电流的变化规律。研究表明在串联电感和并联电容匹配电路下发生谐振时,换能器两端的电压最小而电流并非最大。由此形成了采用最小电压法跟踪谐振频率的自动跟踪策略,并给出了该方法的具体实施步骤。论文研究结果为换能器谐振频率的自动跟踪方法提供了新的选择。     

分段线性电路切换系统的复杂行为及非光滑分岔机理

分析了分段线性电路系统在周期切换下的复杂动力学行为及其产生的机理. 基于平衡点分析, 给出了两子系统Fold分岔和Hopf分岔条件. 考虑了在不同稳定态时两子系统周期切换的分岔特性, 产生了不同的周期振荡, 并揭示了其产生的机理. 在不同的周期振荡中, 切换点的数量随参数变化产生倍化, 导致切换系统由倍周期分岔进入混沌. 关键词： 分段线性电路 切换系统 非光滑分岔     

空间电荷效应对热场致发射中诺廷汉效应的影响

热场致发射阴极所产生的强流电子束具有很强的空间电荷效应,为研究该效应对热场致发射过程中诺廷汉（Nottingham）效应的影响机理,在理论分析的基础上,用数值方法研究了不同逸出功和多个外加电场条件下考虑空间电荷效应对诺廷汉效应结果的影响,并与不考虑空间电荷效应时的情形进行了对比. 结果表明：空间电荷效应的强弱会显著影响到阴极表面的稳态电场,进而对诺廷汉效应产生不可忽略的影响;当逸出功在3.0–4.52 eV、外加电场在3×10⁹–9×10⁹ V/m范围内时,考虑空间电荷效应的影响后,热场致发射电子所带走的平均能量较不考虑空间电荷效应时增加0–2.5 eV,且温度越高或外加电场越大时,该增加值越大;考虑空间电荷效应对诺廷汉效应的影响后,热场致发射电子从阴极带走的平均能量随外加电场的增加呈非线性下降规律;当阴极表面温度较高时,诺廷汉效应中的冷却效应随二极管间隙距离的变大而增强. 关键词： 热场致发射 诺廷汉效应 空间电荷效应 阴极表面电场     

分数阶Chua's系统错位同步无感模块化电路实现及应用

基于分数阶混沌系统稳定性理论, 设计高效的非线性控制器, 实现初始值不同的两个分数阶Chua's系统错位投影同步. 根据分数阶复频域近似方法, 提出分数阶系统的等效电路, 实现分数阶Chua's系统错位投影同步的无感模块化电路. 最后,利用改进的混沌掩盖通信原理, 将以上同步方案应用于混沌保密通信中, 在发送端使用分数阶混沌序列对有用信号加密传送, 从接收端可以无失真地恢复出有用信号. 数值仿真与电路仿真证实了提出方案的可行性. 关键词： 分数阶Chua's系统 错位投影同步 无感模块化电路 保密通信