基于经验数据的温室内的温湿度过程控制系统

针对温室内的温湿度过程控制中参数人工设定的困难和参数自设定的必要性,提出了一种新颖的基于经验数据的适用于温室内的温湿度过程控制系统.该系统硬件采用新型的数字式温湿度一体化传感器LTM8901.温湿度过程控制系统采用具有大容量Flash存储器的C8051F023微控制器,它可在1年时间内以小时为单位设定经验温湿度值,用于控制并记录实测值,实现在1年时间内完全自动控制,无须操作人员干预.具有数据可靠、安装简单、使用和维修方便的特点.     

基于SU-8胶转子的非接触压电微马达

研制了一种非接触压电微马达，通过阻抗分析仪对定子进行扫频测试，确定其共振频率，并且详细介绍了SU-8胶转子制作的工艺流程。利用转速仪比较不同形状和尺寸的转子在调频和调压下的转速，从而确立压电微马达的最优转子。转子半径为6mm，叶片宽度为6mm的三叶片转子转速最高为3569r／min。转子的启动电压和最高电压分别为8V和24V。     

基于TMS320F28335的FIR-IFFT数字滤波方法

针对现有数字滤波方法存在大量傅里叶变换以及卷积运算,在工业控制领域处理50 Hz信号时,易造成处理器消耗大量运算时间,导致在低端处理器上无法实现常规数字滤波算法的问题,介绍了一种修改后的数字滤波算法,综合短时采样序列与最优窗函数在TMS320F28335上可快速实现该算法。经过窗函数截取后的信号进行FFT分析,去除谐波频率后IFFT还原波形,与通用的IIR或FIR滤波器相比,大幅缩短了程序运行时间,同时减少通用滤波器的大量卷积运算,提高程序执行效率。     

冲击法测量磁感应强度实验的数字化解决方案

介绍了冲击法测量磁感应强度实验的基本原理,利用当今成熟的V／F变换技术和单片机技术,实现了对电压积分的测量,解决了冲击法测量磁感应强度实验的数字化问题．     

End effects for pre-stressed and pre-polarized piezoelectric solids in anti-plane shear

This paper is concerned with investigation of the influence of pre-stress and pre-polarization on the decay of Saint-Venant end effects in piezoelectric solids. This issue is examined within the framework of incremental anti-plane shear states for prestressed and prepolarized solids. Attention is confined to a specific class of materials, namely those of hexagonal 6mm or 4mm symmetry. It is shown that the mechanical and electrical fields uncouple in this case, and the governing system of coupled second-order linear partial differential equations uncouple to a single homogeneous second-order equation with constant coefficients for the displacement and a Poisson equation for the electric potential. The exact decay rate for mechanical and electrical end effects is determined and the influence of pre-stress and pre-polarization is assessed. Motivation for this work arises from the current rapid developments in smart materials technology.     

Catalyst-free synthesis of 3-(alkylamino)-2-arylimidazo[1,2-a]pyridine-8-carboxylic acids via a three-component condensation

The synthesis of a number of 3-(alkylamino)-2-arylimidazo[1,2-a]pyridine-8-carboxylic acids via a facile route involving the reaction between 2-amino-3-pyridinecarboxylic acid, benzaldehyde derivatives, and isonitriles is reported. The structures of the synthesized compounds are proved by X-ray crystallography.     

Rhodium(I)‐Catalyzed Regiospecific Dimerization of Aromatic Acids: Two Direct CH Bond Activations in Water

2,2′‐Diaryl acids are key building blocks for some of the most important and high‐performance polymers such as polyesters and polyamides (imides), as well as structural motifs of MOFs (metal–organic frameworks) and biological compounds. In this study, a direct, regiospecific and practical dimerization of simple aromatic acids to generate 2,2′‐diaryl acids has been discovered, which proceeds through two rhodium‐catalyzed C? H activations in water. This reaction can be easily scaled up to gram level by using only 0.4–0.6 mol % of the rhodium catalyst. As a proof‐of‐concept, the natural product ellagic acid was synthesized in two steps by this method.     

Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

Zeolite imidazole frameworks 8(ZIF-8) and modified ones after pyrolysis are highly promising toward oxygen reduction reaction(ORR). Especially, the compositional modification of ZIF-8 is crucial to the enhancement of ORR performance, yet limited to the substitution of skeletal Zn(II) with other cations or simple physical adsorption of cations. Herein, we report the decoration of ZIF-8 with ORR active hemin(FeP) and Co(III) protoporphyrin(CoP) via the coordination between the peripheral carboxylic group of FeP and CoP with skeletal Zn(II). This allows well control over the quantity of loaded FeP and CoP, critical to the synthesis of advanced electrocatalysts. Subsequent pyrolysis of FeP and CoP co-decorated ZIF-8 leads to highly active ORR electrocatalysts with a half-wave potential(E_1/2) of 0. 913 V(vs. RHE) in 0.1 mol/L KOH aq. and an E_1/2 of 0.803 V(vs. RHE) in 0.1 mol/L HClO₄ aq. Moreover, our electrocatalyst shows much more improved and comparable durability in alkaline and acidic media, respectively, during 3000 cycles of cyclic voltammetry(CV) scanning relative to commercial Pt/C.     

运动粒子全息测试仪

本文论述了用序列脉冲激光在4F光学系统中测量各种情况下的喷雾粒子大小、分布及运动速度的同轴全息和离轴全息方法。并讨论了仪器的结构原理,特点。文章共分了四个部分: 1)用4F光学系统测量微粒子的基本原理。 2)光学系统结构的特点。 3)红宝石脉冲激光光源。 4)仪器的组成及性能指标。     

A novel method for the synthesis of 5,6-dihydro-4H-oxocin-4-ones: 6-endo-dig versus 8-endo-dig cyclizations

The condensation of substituted α-keto alkynes with p-nitrobenzaldehyde in the presence of lithium diisopropylamide (LDA) affords highly substituted 5,6-dihydro-4H-oxocin-4-ones in good yields. Surprisingly, no six-membered carbocycles were formed in this 8-endo-dig cyclization to the oxocinone system.