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991.
This article presents a measuring method for determination of convective heat transfer in rotating environments. The method is used to obtain temperature and Nusselt number distributions on optically accessible objects inside real operating environments, without the need for implementation of complex surface heat flux measurements. Temperature maps of the observed surfaces are acquired non-intrusively by infrared (IR) thermography, whereas heat flux data is computed numerically by computational fluid dynamics (CFD) tools. The method was employed on a rotating hollow blade, heated internally by secondary air flow. Experimental and numerical results for the observed blade side are compared in terms of surface temperature 2D distributions. Temperature distributions are further statistically evaluated and show good agreement, which is the basic precondition for combining experimental and numerical data by the method. Results are presented in terms of combined experimental-numerical Nusselt number shown as two-dimensional distribution on the blade pressure side. 相似文献
992.
Abstract Measurements of electron paramagnetic resonance, infrared and electrical properties were carried out for the K2SO4—Na2SO4 mixed system before and after γ-irradiation. EPR measurements revealed the presence of a quartet of lines characterized by an isotropic g-value of 2.0034. These lines are mainly attributed to the formation of a SO? 3 center which results from the interaction of γ-rays with the sulfate ion. A decrease in the absorption intensity of the Infrared radiation was observed after γ-irradiation due to radiation damage in the sulfate group. The electrical conductivity, σ, was measured for the K2SO4—Na2SO4 system before and after γ-irradiation in the temperature range from 30 up to 430°C. A considerable decrease in the conductivity value accompanied by an increase in the activation energy was observed after γ-irradiation. The energy of formation of Frenkel defects was estimated to be 2.94eV. The current-voltage characteristics were measured at different temperatures in order to estimate the type of conduction in the samples. Isothermal annealing kinetics was investigated at different temperatures before and after γ-irradiation. The electrical conductivity decreases with increasing time of annealing and the annealing process is dominated by a unique rate process. 相似文献
993.
994.
B. A. Shainyan N. N. Chipanina L. P. Oznobikhina Yu. S. Danilevich 《Journal of Physical Organic Chemistry》2013,26(8):653-658
The first N‐allenyl derivative of trifluoromethanesulfonamide, N‐benzyl‐N‐(allenyl)trifluoromethanesulfonamide ( 1 ), was studied experimentally by the FT‐IR spectroscopy and theoretically at the DFT and MP2 levels of theory. The intramolecular interaction of the nitrogen atom with the triflyl and the allenyl group was studied in comparison with the analogously substituted vinyl derivatives. Compound 1 in heptane solution at 295–183 K exists as an equilibrium mixture of conformational isomers. Protonation at different basic sites in a series of reference molecules is studied theoretically. The central C2 atom of the allenyl group in 1 has the highest proton affinity, which is 16 kcal/mol higher than in the N‐vinyl analogues. The relative ability of the allenyl and vinyl groups to conjugation with an electron‐rich and electron‐deficient nitrogen atom lone electron pair is discussed. From the NBO analysis, the conjugation of the nitrogen lone electron pair with the allenyl group is much stronger than with the vinyl group. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
995.
The ferrite system Ni x Mg1-x Fe2O4 with 0≤x≤1 was prepared using the usual ceramic technique. The prepared samples were studied by X-ray diffraction and IR spectroscopy. X-ray diffraction analysis proved that all the samples were single-phase with the cubic spinel structure. The lattice constant, radius of the tetrahedral ion, unshared octahedral edge, tetrahedral bond and tetrahedral edge decrease while the bulk and theoretical densities, radius of octahedral ion, octahedral bond and shared octahedral edge increase as nickel ion substitution increases. The positions and intensities of the four bands of IR absorption spectra characterizing ferrites are composition dependent. 相似文献
996.
The IR spectra have been recorded in the solid state for the parent molecule, 6-(N-pyrrolyl)purine (1) and its N-9-and N-7-substituted derivatives: 9-and 7-(2-hydroxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (2 and 3), 9-and 7-(2-acetoxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (4 and 5), 9-and 7-(2,3-dihydroxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (6 and 7) as well as 9-and 7-(2,3-diacetoxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (8 and 9). Analysis of the characteristic bands has proved to be useful in differentiating between N-9 and N-7 regioisomers. 相似文献
997.
Nand K. Narain 《光谱学快报》2013,46(12):865-875
A rare flavone, Genkwanin, was isolated by column and preparative thin layer chromatography of a chloroform extract of the leaves of Vernonia fasciculata Michx. Spectral studies (NMR, IR, UV and MS) and a comparison with data for closely related compounds has been made. 相似文献
998.
999.
M. V. Bel’kov G. A. Ksendzova G. I. Polozov I. V. Skornyakov V. L. Sorokin G. B. Tolstorozhev O. I. Shadyro 《Journal of Applied Spectroscopy》2008,75(1):69-74
FTIR methods were used to study intramolecular and intermolecular interactions in solutions and the solid state of the biologically
active aminophenols 2-anilino-4,6-di-tert-butylphenol, N-(3,5-di-tert-butyl-2-methoxyphenyl)aniline, and 2,4-di-tert-butyl-10H-1-phenothiazinol.
An analysis of the IR spectra has shown that intramolecular interactions between the OH and NH groups occur in solutions of
2-anilino-4,6-di-tertbutylphenol in CCl4 to form O-H⋯N hydrogen bonds. The NH groups in solutions of N-(3,5-di-tert-butyl-2-methoxyphenyl)aniline in CCl4 are present in the non-associated state because of the absence of hydroxyl groups in the molecular structure. The OH and
NH groups in solutions of 2,4-di-tert-butyl-10H-1-phenothiazinol in CCl4 do not interact within the molecule due to a decrease in the conformational mobility of the molecular fragments due to the
presence of the rigid CAr-S-CAr molecular bond in this compound. Intermolecular interactions involving the NH groups occur in the solid state of these compounds.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 1, pp. 68–73, January–February, 2008. 相似文献
1000.
U. Okwieka M. M. Szostak T. Misiaszek I. Turowska‐Tyrk I. Natkaniec A. Pavlukoj 《Journal of Raman spectroscopy : JRS》2008,39(7):849-862
Polarized FT‐IR, Raman, neutron scattering (IINS), and UV‐Vis‐NIR spectra of 2‐methyl‐4‐nitroaniline (MNA) crystal plates, powder, and solutions were measured in the 10–50 000 cm−1 range. The FT‐IR spectrum of deuterated MNA (DMNA) in KBr pellet, the Raman spectrum of the DMNA powder as well as the EPR spectrum of the MNA powder were also recorded. Complete assignments of bands to normal vibrations have been proposed. Density functional theory (DFT) calculations of wavenumbers and potential energy distribution (PED) have been performed to strengthen the assignments. The analysis of vibrational and electronic spectra has revealed vibronic couplings in MNA molecules in solutions and in crystals. In the polarized FT‐IR spectra of the crystal five unusually large bands are observed in MIR and NIR regions. Their origin is discussed in terms of N H···O, C H···O, C H···H N hydrogen bonds, intermolecular charge transfers, electrostatic interactions, and ion radicals formation in the crystal. The role of a methyl group introduction to 4‐nitroaniline is analyzed. The crystal structure of MNA at the room temperature was re‐investigated. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献