Time resolved spectroscopic NMR imaging using hyperpolarized Xe

We have visualized the melting and dissolution processes of xenon (Xe) ice into different solvents using the methods of nuclear magnetic resonance (NMR) spectroscopy, imaging, and time resolved spectroscopic imaging by means of hyperpolarized ¹²⁹Xe. Starting from the initial condition of a hyperpolarized solid Xe layer frozen on top of an ethanol (ethanol/water) ice block we measured the Xe phase transitions as a function of time and temperature. In the pure ethanol sample, pieces of Xe ice first fall through the viscous ethanol to the bottom of the sample tube and then form a thin layer of liquid Xe/ethanol. The xenon atoms are trapped in this liquid layer up to room temperature and keep their magnetization over a time period of 11 min. In the ethanol/water mixture (80 vol%/20%), most of the polarized Xe liquid first stays on top of the ethanol/water ice block and then starts to penetrate into the pores and cracks of the ethanol/water ice block. In the final stage, nearly all the Xe polarization is in the gas phase above the liquid and trapped inside the pores. NMR spectra of homogeneous samples of pure ethanol containing thermally polarized Xe and the spectroscopic images of the melting process show that very high concentrations of hyperpolarized Xe (about half of the density of liquid Xe) can be stored or delivered in pure ethanol.     

Influence of the network chain orientation on the fracture toughness of a mesogenic epoxy resin modified with CTBN

A biphenol‐type epoxy resin, which had a mesogenic group in the backbone moiety, was modified with carboxy‐terminated butadiene acrylonitrile copolymer (CTBN) as a reactive elastomer, and its fracture toughness was measured. With the addition of CTBN, the fracture toughness of the biphenol‐type epoxy resin significantly increased and became significantly higher than that of a bisphenol A‐type epoxy resin modified with CTBN. The network chain orientation in the cured biphenol‐type epoxy resin system was clearly observed during the fracture process with polarized microscopy Fourier transform infrared measurements, although such a phenomenon was not observed in the bisphenol A‐type epoxy resin system. The high toughness of the cured biphenol‐type system was clearly due to the consumption of the mechanical energy by a large deformation of the matrix resin due to the orientation of the network chains during the fracture process. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1198–1209, 2003     

激光水下偏振特性用于目标图像探测

利用激光水下偏振特性获得偏振差分图像(PDI),并运用PDI技术,从理论和实验上对水下目标探测进行了研究.介绍了PDI基本概念和实验系统原理,然后比较分析了不同条件下普通图像与PDI在辨别目标距离及其纹理上的差别和PDI中背景偏振光的影响,得出利用目标和背景偏振光的差异区分二者,从而提高探测距离的结论,并取得了较好的效果.在此基础上提出了通过处理有关PDI偏振参量来进一步辨别目标与背景的设想.     

Structure–electrical property study of anisotropic polyaniline films

The relationships of the structure and electrical properties of anisotropic HCl‐doped polyaniline (PANI) films cast from N,N′‐dimethylpropylene urea (DMPU) solutions and stretched to different draw ratios were studied. The anisotropic structure of the stretched PANI films was examined by X‐ray diffraction, near‐infrared wave‐guide coupling, and polarized infrared measurements. The PANI emeraldine base (EB) films cast from DMPU solutions had a single‐phase noncrystalline structure, and stretching of the films did not cause crystallization to occur. The transition moment angles of two weakly absorbing infrared bands were determined, and the Hermans' orientation functions for the PANI EB films were calculated. The PANI films were then doped with HCl, and the electrical properties were determined by impedance spectroscopy. With a specially designed test fixture, the in‐plane and through‐plane impedance was obtained. The conductivity along the stretch direction increased with orientation. The in‐plane conductivity was significantly higher than the through‐plane conductivity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 823–841, 2003     

成像光谱技术发展的科学背景和现状

本文分析与阐述了成像光谱技术发展的科学背景与现状。     

热成像技术在厚膜混合集成电路热设计中的应用

本文简述了红外热成像技术用于厚膜混合集成电路热设计中的理论与实验方法，并讨论了结果。     

流延热释电厚膜陶瓷制备单元红外探测器

本文报道采用流延法制备的热释电厚膜陶瓷材料直接装配的单元红外探测器，该方法大大简化了目前探测器的制备工艺，极大地提高了材料的利用率，器件的性能也达到了目前探测器的水平。     

快速启动微型J—T制冷器

在一些特殊应用中，要求把红外探测器必须在几秒钟或更短的时间内冷却到工作状态。微型Ｊ－Ｔ式制冷是常用致冷方式。本文介绍了快速启动冷却红外探测器的Ｊ－Ｔ制冷器的设计及达到快速冷却的方法以及测试结果。     

第二讲合成孔径声纳成像及其研究进展

文章在介绍了图像声纳的特点、合成孔径声纳（synthetic aperture sonar,SAS）产生背景和发展过程的基础上,对合成孔径声纳的原理、技术难点、成像算法等问题进行了讨论.着重分析了合成孔径声纳成像过程中高分辨率的获取方法、水声信道对成像的影响、多子阵技术及其成像算法、稳定的声纳运动平台和运动监测问题、运动补偿与自聚焦方法等.文章还给出了国内外合成孔径声纳研究的最新进展情况,进而展望了合成孔径声纳的应用前景.