生长条件对KDP晶体中散射颗粒的影响

利用透射电子显微技术对不同条件下生长的KDP晶体中包裹物进行了观察并测量了其相应尺寸。结果表明，晶体中的生长缺陷、pH值、生长速度和杂质与KDP晶体散射颗粒的形态存在密切关系。     

羰基铁类随机混合吸波材料等效电磁参数的计算

本文为计及多重散射偶极子间的相互作用，引入参量εｈ和μｈ，导得一组公式。它不仅能计算铁氧体类也能计算羰基铁类的随机混合吸波材料的等效电磁参数，均与实验结果吻合良好。     

Intravascular and Intracellular Hepatic Relaxivities of Superparamagnetic Particles: An Isolated and Perfused Organ Pharmacokinetics Study

The relative contributions of intravascular and intracellular compartments to the proton transverse relaxation of the isolated and excised rat liver were determined during the phagocytosis of superparamagnetic particles. The evolution of the proton transverse magnetization of the organ perfused with increasing doses of starch-coated magnetic microspheres was followed up using a Carr–Purcell–Meiboom–Gill sequence with various echo times. From the multiexponential fit of the echo train, the amplitudes and the relaxation ratesR₂of the liver tissue were obtained. The results clearly indicate that shortly after contrast medium administration, an internalization takes place which can be followed by the rapid and biphasic evolution of the transverse relaxation rate of the water protons. A very fast decaying component looking like an initial loss of the magnetization is observed together with an increase of the relaxation rate of the remaining water tissue. This regime is strongly dependent on both the echo time and the iron concentration, a behavior characteristic of the agglomeration of magnetic particles. The examination of the liver tissues by electron microscopy shows that this clustering arises in cytoplasmic vacuoles.     

A Micellar Route to Ordered Arrays of Magnetic Nanoparticles: From Size‐Selected Pure Cobalt Dots to Cobalt–Cobalt Oxide Core–Shell Systems

Starting with Co‐salt‐loaded inverse micelles, which form if the diblock copolymer polystyrene‐block‐poly(2‐vinylpyridine) is dissolved in a selective solvent like toluene and CoCl₂ is added to the solution, monomicellar arrays of such micelles exhibiting a significant hexagonal order can be prepared on top of various substrates with tailored intermicellar distances and structure heights. In order to remove the polymer matrix and to finally obtain arrays of pure Co nanoparticles, the micelles are first exposed to an oxygen plasma, followed by a treatment in a hydrogen plasma. Applying in‐situ X‐ray photoelectron spectroscopy, it is demonstrated that: 1) The oxygen plasma completely removes the polymer, though conserving the original order of the micellar array. Furthermore, the resulting nanoparticles are entirely oxidized with a chemical shift of the Co 2p_3/2 line pointing to the formation of Co₃O₄. 2) By the subsequent hydrogen plasma treatment the nanoparticles are fully reduced to metallic Co. 3) By exposing the pure Co nanoparticles for 100 s to various oxygen partial pressures pequation/tex2gif-inf-5.gif, a stepwise oxidation is observed with a still metallic Co core surrounded by an oxide shell. The data allow the extraction of the thickness of the oxide shell as a function of the total exposure to oxygen (pequation/tex2gif-inf-7.gif × time), thus giving the opportunity to control the ferromagnetic–antiferromagnetic composition of an exchange‐biased magnetic system.     

无机纳米粒子作为生物探针在生物分析中的研究进展

介绍了无机纳米粒子在生物分析领域的研究进展分别从生物分子与纳米粒子的耦联方式、检测生物分子的纳米金探针、核酸或蛋白质修饰的其它纳米探针以及生物纳米技术的应用前景4个方面对该领域的发展进行了概述。     

Fock Theories and Quantum Logics

The notion of Fock theory is introduced in the framework of quantum logics, which are here orthomodular atomic lattices satisfying the covering property. It is shown that there are some fundamental facts concerning particles, which may be successfully discussed in this general context. One of these facts is to establish the theoretical conditions for considering particles as sharply defined entities. The other refers to the theoretical circumstances, which almost impose to consider that some particles have a structure, meaning they are composed from other particles. This last problem is strongly related with the conservative time evolutions.     

A transport model for the evolution of urban systems

When comparing an urban system to an elasto-plastic lattice, an analogy to the solid state of matter can be exploited using the concepts of the band theory similarly. Thereafter, the population dynamics – in a region of certain stability in the state space and within appropriate energy bands – can be described in terms of Cellular Automata, with two mobile agents or pseudo particles: the inhabitant (representative of an average individual) and the recurson (representative of its multidimensional resources). As in the solid state, transition rules take the form of two coupled transport equations, comprising the terms equivalent to the generation-recombination and circulation processes. The first process can be compared to a predator–prey growth model, typical of Ecology; whereas the circulation process – composed of a drift component and a diffusion component – should be compared to the concentration-sprawl demographic balance seen in urban occupation and dynamics. Thus, it needs to be defined and determined an urban potential function, an equivalent population charge, mobility and diffusion parameters, as well as net growth factors. This analogy, discussed within the context of a case study for Great Mendoza, plausibly explains the varied growth rates of the political departments, as well as the principal urban trends for spatial occupation.     

Magnetic silica colloids for catalysis

Monodisperse magnetizable colloidal silica particles in a stable dispersion have been functionalized with a homogeneous catalyst: a PCP–pincer Pd-complex. In a proof-of-principle experiment we demonstrate the catalytic activity of the colloids in a C–C bond formation reaction. Advantages of the magnetic silica carriers are the large surface-to-volume ratio and the easy recovery by magnetic separation. After magnetic separation, the catalyst-loaded particles are readily redispersed for further use.     

X-ray fluorescence intensity distribution in circular specimens

Summary The relative X-ray fluorescence (XRF) intensities for annular source and various annular specimen are measured with a Ge-Li detection system and calculated by the Monte Carlo numerical techniques (MCNT).Kα X-ray intensities of annular specimens with different radii prepared from a pure-molybdenum foil are measured and it is seen that the measured values are in good agreement with the values calculated by MCNT. The variation of the fluorescence intensity due to the collimator radius is also studied. The differences between the MCNT and experimental results are discussed in terms of the possible sources of errors.     

BNL/AGS10.7A GeV金核诱发作用中核碎裂与粒子产生

研究了在美国BNL/AGS上能量10.7AGeV的¹⁹⁷Au离子诱发核作用,报告了EMU–01国际合作实验关于射弹核碎裂和产生粒子密度等最新实验结果.