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11.
12.
In green chemistry, biocatalysis using microwaves is a very attractive tool for various regioselective syntheses. L-Ascorbyl fatty acid esters were synthesized by an immobilized lipase from Bulkholderia multivorans using microwaves, with a dynamically enhanced rate of reaction and appreciable yield of around 80%. Microwave radiation had no effect on enzymic inactivation, however, synergism between microwaves and biocatalyst was observed. 相似文献
13.
This study investigated the effects of high-power ultrasound (HPU, 0–45 °C, 242–968 W/cm2, 2–16 min) on the rheological properties of strawberry pulp. Following the HPU treatment, the strawberry pulp exhibited an increase in apparent viscosity, storage modulus (G′), and loss modulus (G″). The water-soluble pectin (WSP), pectin methylesterase (PME) activity, and free calcium ions (Ca2+) of the strawberry pulp after HPU treatment were investigated to determine a possible reason for this phenomenon. HPU caused a significant decrease in the degree of esterification (DE), molecular weight (Mw), and particle size of strawberry WSP, but no significant changes were evident in the galacturonic acid (GalA) content and the zeta (ζ)-potential (P > 0.05), resulting in decrease in the apparent viscosity. Moreover, the largest reduction of PME activity was 22.6% after HPU treatment at 605 W/cm2 and 45 °C for 16 min, indicating that the PME was resistant to the HPU treatments. The free Ca2+ content in the strawberry pulp was significantly decreased after exposure to HPU (P < 0.05). The maximal reduction of 52.01% in the free Ca2+ was achieved at 605 W/cm2 and 45 °C for 16 min. The overall results indicated that the high residual activity (RA) of PME after HPU might induce the low esterification of WSP, while HPU promoted the interaction of free Ca2+ and low-methylated pectin, to form the network structure of Ca2+-low-methylated pectin, resulting in an increase in viscosity in the complex strawberry system. 相似文献
14.
We investigated the effect of ultrasound (US) and high hydrostatic pressure (HHP) on the size of reformed casein micelles (RMCs) obtained by titrating calcium and phosphorous solution into sodium caseinate solutions. Both US and HHP reduced the size of the RMCs. A decrease in size from ~200 nm to ~170 nm when US (20 kHz, 0.46 W/mL) was applied for 30 min; and down to ~85 nm when HHP was applied 500 MPa for 15 min. Electron microscopic analysis showed that the RMCs before and after US are similar to milk native casein micelles, and that HHP extensively disintegrated the RMCs. Small angle X-ray scattering and SDS-PAGE showed that the internal structure of the RMCs as well as the casein molecules are not affected by the US and HHP treatments. 相似文献
15.
The activity of [Pd(C6H4CH2 NH2‐κ2‐C‐N)PPh3MOBPPY]OTf complex, A (MOBPPY = 4‐methoxybenzoylmethylenetriphenyl‐ phosphoraneylide), was investigated in the Heck–Mizoroki C? C cross‐coupling reaction under conventional heating and microwave irradiation conditions. The complex is an active and efficient catalyst for the Heck reaction of aryl halides. The yields were excellent using a catalytic amount of [Pd(C6H4CH2 NH2‐κ2‐C‐N)PPh3MOBPPY]OTf complex in N‐methyl‐2‐pyrrolidinone (NMP) at 130 °C and 600 W. In comparison to conventional heating conditions, the reactions under microwave irradiation gave higher yields in shorter reaction times. Copyright © 2010 European Peptide Society and John Wiley & Sons, Ltd. 相似文献
16.
George A. Baker Jr. 《General Relativity and Gravitation》2002,34(6):767-791
Recent experimental results from supernovae Ia observations have been interpreted to show that the rate of expansion of the universe is increasing. Other recent experimental results find strong indications that the universe is flat. In this paper, I investigate some solutions of Einstein's field equations which go smoothly between Schwarzschild's relativistic gravitational solution near a mass concentration to the Friedmann-Lemaître expanding universe solution. In particular, the static, curved-space extension of the Lemaître-Schwarzschild solution in vacuum is given. Uniqueness conditions are discussed. One of these metrics preserves the cosmological equation. We find that when the rate of expansion of the universe is increasing, space is broken up into domains of attraction. Outside a domain of attraction, the expansion of the universe is strong enough to accelerate a test particle away from the domain boundary. I give a domain-size–mass relationship. This relationship may very well be important to our understanding of the large scale structure of the universe. 相似文献
17.
Wenxiang Wang Lingna Yue Guoqing Zhao Yubin Gong 《International Journal of Infrared and Millimeter Waves》2005,26(2):147-161
The microwave modes discrimination and analysis for high power waveguide systems is an important topic. In this paper we review different methods and discuss their advantages and disadvantages. Both the limitations and applicability of various techniques are commented as well. 相似文献
18.
Analytical theory of high-power microwave propagation in waveguide filled with plasma is presented in this paper. The ponderomotive force effect of high power microwave is taken into consideration and preliminary numerical calculations are carried out, the propagation characteristics of the high-power microwave and the influence of microwave power on the distribution of plasma density are calculated and discussed. 相似文献
19.
T. M. Mishonov M. V. Stoev Y. G. Maneva 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):533-536
Absorption of Alfvén waves is considered to be the main mechanism of
heating in the solar corona. It is concluded that the sharp increase
of the plasma temperature by two orders of magnitude is related to a
self-induced opacity with respect to Alfvén waves. The maximal
frequency for propagation of Alfvén waves is determined by the
strongly temperature dependent kinematic viscosity. In such a way
the temperature jump is due to absorption of high frequency Alfvén
waves in a narrow layer above the solar surface. It is calculated
the power per unit area dissipated in this layer due to damping of
Alfvén waves that blows up the plasma and gives birth to the
solar wind. A model short wave-length (WKB) evaluation takes into
account the 1/f2 frequency dependence of the transversal magnetic
field and velocity spectral densities. Such spectral densities agree
with old magnetometric data taken by Voyager 1 and recent
theoretical calculations in the framework of Langevin-Burgers MHD.
The presented theory predicts existence of intensive high frequency
MHD Alfvén waves in the cold layer beneath the corona. It is
briefly discussed how this statement can be checked experimentally.
It is demonstrated that the magnitude of the Alfvén waves
generating random noise and the solar wind velocity can be expressed
only in terms of satellite experimental data. It is advocated that
investigation of properties of the solar surface as a random driver by
optical methods is an important task for future solar physics. 相似文献
20.
With the reduction of crude oil throughout the world, enhance oil recovery technology has become a major oil research topics, which can greatly increase the recovery ratio of the crude oil before the dawning of renewable energy era. Near-well ultrasonic processing technology, as one new method, has attracted more attention for Enhanced Oil Recovery due to its low cost, good applicability and no environmental pollution in recent rears. There are two important relevant aspects about Near-well ultrasonic processing technology: (a) how to enhance the oil flow through the rocks into the pumping pool and (b) how to reduce the oil viscosity so that it can be easier to pump. Therefore, how to design a high-power ultrasonic equipment with excellent performance is crucial for Near-well ultrasonic processing technology. In this paper, recent new high-power ultrasonic transducers for Near-well ultrasonic processing technology are summarized. Each field application of them are also given. The purpose of this paper is to provide reference for the further development of Near-well ultrasonic processing technology.With the reduction of crude oil throughout the world, enhance oil recovery technology has become a major oil research topics, which can greatly increase the recovery ratio of the crude oil before the dawning of renewable energy era. Near-well ultrasonic processing technology, as one new method, has attracted more attention for Enhanced Oil Recovery due to its low cost, good applicability and no environmental pollution in recent rears. There are two important relevant aspects about Near-well ultrasonic processing technology: (a) how to enhance the oil flow through the rocks into the pumping pool and (b) how to reduce the oil viscosity so that it can be easier to pump. Therefore, how to design a high-power ultrasonic equipment with excellent performance is crucial for Near-well ultrasonic processing technology. In this paper, recent new high-power ultrasonic transducers for Near-well ultrasonic processing technology are summarized. Each field application of them are also given. The purpose of this paper is to provide reference for the further development of Near-well ultrasonic processing technology 相似文献