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该文对微机械气流式水平姿态传感器敏感机理进行了三维的有限元分析.利用ANSYS-FLOTRAN CFD软件,通过建模、划分网格、加载和求解等途径,计算了微机械气流式水平姿态传感器敏感元件密闭腔体中气流速度在不同倾斜状态下的分布.阐明微机械气流式水平姿态传感器的敏感机理,为气流式水平姿态传感器的优化设计开辟了更精确的研究途径.     

一种基于防毒面具的通话系统

防毒面具的隔绝特性使得用户之间的通话较为困难,为解决其在烟雾、火灾、战场等复杂使用环境下的通信问题,基于点到多点和．董到点两项功能,构建一种基于防毒面具的无线通话系统。系统采用语音编码和跳频等技术方法,开发出防毒面具内置的小型多功能无线通话终端。经软硬件测试表明,系统通信安全可靠,保密性强,体积小,成本低。     

基于CAN总线煤矿瓦斯智能节点的研究与设计

煤矿瓦斯气体监测的系统是保证煤矿生产安全的必备设备。分析国内外煤矿瓦斯气体监测系统特．羔．提出基于CAN总线煤矿瓦斯气体监测的网络系统。着重介绍以P80C592单片机作为CAN总线煤矿瓦斯智能节点．研究设计CAN总线通信接口电路、MAX306数据采集电路以及相应的软件设计等。通过研究设计表明智能节点具有简单明了、体积小、性能高、成本低廉、抗干扰能力强等特点,能够满足煤矿瓦斯气体监测的网络系统要求。     

煤矿矿井数学模型的研究

通过各监测点处瓦斯浓度,风速等观测值来判定其高低瓦斯矿井,详细阐述了煤矿瓦斯绝对、相对浓度的计算方法;通过瓦斯煤尘的检测数据,对矿井发生爆炸的概率进行建模预测,估算出了该矿井的不安全程度。在数据处理过程中主要借助Excel、Matlab等辅助工具来实现。此外还根据《煤矿安全规程》对主要工作面风量进行了规划,得出了最优通风模型;具有较强参考价值。     

微球状ZnO纳米粉体的制备与气敏性能研究

以Zn(CH3COO)2·2H2O为原料,无表面活性剂存在时,利用水热法合成了微球状ZnO纳米粉体。采用XRD,SEM和TEM等测试手段,对其物相、结构进行了表征。结果表明:此粉体为六方晶系的ZnO,结晶良好,直径小于4μm。利用该粉体制成气敏元件,并用静态配气法测试了元件的气敏性能。研究发现:元件在180℃工作温度下,对体积分数为50×10–6的丙酮和乙醇气体的灵敏度分别达到5.9和8.6。     

Al掺杂ZnO厚膜的sol-gel法制备及其气敏性能研究

以硝酸锌、硝酸铝和氢氧化钠为原料,采用sol-gel法制备铝掺杂的纳米氧化锌厚膜(样品),并利用XRD和SEM对其微观结构进行了表征。研究了铝掺杂量和退火温度对ZnO厚膜的气敏性能的影响。结果表明:700℃退火、掺w(Al)为2.9%的样品对体积分数为4.0×10–1的丙酮有很好的选择性,最大灵敏度达到7 779左右,最佳工作温度约为162℃,响应、恢复时间均为1 s,最后讨论了铝掺杂纳米氧化锌的气敏机理。     

ZnS掺杂WO_3纳米粉体的制备及H_2S气敏性能

采用共沉淀法制备了w(ZnS)为0~0.2%的ZnS-WO3纳米粉体,利用X射线衍射仪分析了粉体的微观结构,探讨了ZnS掺杂量、工作温度对由所制粉体制成的气敏元件的气敏性能的影响。研究发现:适量的ZnS掺杂抑制了WO3晶粒的生长,提高了粉体对H2S的灵敏度。其中,掺杂ZnS的质量分数为1.0%的烧结型气敏元件,在160℃时对体积分数为0.001%的H2S的灵敏度达到87,响应时间7s,恢复时间12s。     

Evaluation of comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry for the diagnosis of inherited metabolic disorders using an automated data processing strategy

Organic acidurias are a large group of inherited metabolic disorders (IMDs), commonly diagnosed by GC-MS analysis of organic acids in urine after acidic extraction and trimethylsilylation. In this study, a GC×GC-ToF-MS method has been optimized for the analysis of pathological metabolites in urine. An automated data processing strategy based on the use of mass spectra and GC retention times for the target search and quantification of pathological metabolites has been developed. Using this procedure, each unknown sample is automatically examined for the presence of markers of several diseases at the same time. The method has been applied for the analysis of 6 challenging proficiency testing samples from patients with IMDs (thymidine phosphorylase deficiency, mevalonic aciduria, hawkinsinuria, aromatic l-amino acid decarboxylase deficiency, propionic acidemia and medium-chain acyl-CoA dehydrogenase deficiency). Using the GC×GC-ToF-MS method, we were able to determine complete sets of markers for all the IMDs. The quality of the mass spectral matches for the pathological markers was higher than 800 (out of 1000).     

Supercritical fluid chromatography hyphenated with twin comprehensive two-dimensional gas chromatography for ultimate analysis of middle distillates

This paper reports the conditions of online hyphenation of supercritical fluid chromatography (SFC) with twin comprehensive two-dimensional gas chromatography (twin-GC × GC) for detailed characterization of middle distillates; this is essential for a better understanding of reactions involved in refining processes. In this configuration, saturated and unsaturated compounds that have been fractionated by SFC are transferred on two different GC × GC columns sets (twin-GC × GC) placed in the same GC oven. Cryogenic focusing is used for transfer of fractions into the first dimension columns before simultaneous GC × GC analysis of both saturated and unsaturated fractions. The benefits of SFC–twin-GC × GC are demonstrated for the extended alkane, iso-alkane, alkene, naphthenes and aromatics analysis (so-called PIONA analysis) of diesel samples which can be achieved in one single injection. For that purpose, saturated and unsaturated compounds have been separated by SFC using a silver loaded silica column prior to GC × GC analysis. Alkenes and naphthenes are quantitatively recovered in the unsaturated and saturated fractions, respectively, allowing their identification in various diesel samples. Thus, resolution between each class of compounds is significantly improved compared to a single GC × GC run, and for the first time, an extended PIONA analysis of diesel samples is presented.     

Convex hull: A new method to determine the separation space used and to optimize operating conditions for comprehensive two-dimensional gas chromatography

It is important to develop methods of optimizing the selection of column sets and operating conditions for comprehensive two-dimensional gas chromatography. A new method for the calculation of the percentage of separation space used was developed using Delaunay's triangulation algorithms (convex hull). This approach was compared with an existing method and showed better precision and accuracy. It was successfully applied to the selection of the most convenient column set and the geometrical parameters of second column for the analysis of 49 target compounds in wastewater.