全文获取类型
收费全文 | 15040篇 |
免费 | 1581篇 |
国内免费 | 1167篇 |
专业分类
化学 | 9547篇 |
晶体学 | 88篇 |
力学 | 56篇 |
综合类 | 54篇 |
数学 | 4890篇 |
物理学 | 1351篇 |
无线电 | 1802篇 |
出版年
2024年 | 34篇 |
2023年 | 316篇 |
2022年 | 212篇 |
2021年 | 250篇 |
2020年 | 473篇 |
2019年 | 471篇 |
2018年 | 463篇 |
2017年 | 347篇 |
2016年 | 543篇 |
2015年 | 659篇 |
2014年 | 895篇 |
2013年 | 1298篇 |
2012年 | 852篇 |
2011年 | 1012篇 |
2010年 | 887篇 |
2009年 | 1023篇 |
2008年 | 1048篇 |
2007年 | 1017篇 |
2006年 | 853篇 |
2005年 | 625篇 |
2004年 | 560篇 |
2003年 | 565篇 |
2002年 | 468篇 |
2001年 | 325篇 |
2000年 | 301篇 |
1999年 | 285篇 |
1998年 | 252篇 |
1997年 | 175篇 |
1996年 | 183篇 |
1995年 | 215篇 |
1994年 | 174篇 |
1993年 | 136篇 |
1992年 | 131篇 |
1991年 | 71篇 |
1990年 | 65篇 |
1989年 | 57篇 |
1988年 | 57篇 |
1987年 | 31篇 |
1986年 | 32篇 |
1985年 | 57篇 |
1984年 | 46篇 |
1982年 | 53篇 |
1981年 | 40篇 |
1980年 | 31篇 |
1979年 | 36篇 |
1978年 | 34篇 |
1977年 | 25篇 |
1976年 | 29篇 |
1975年 | 19篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
Hiroshi Ito Masaki Okazaki Dolores C. Miller 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1478-1505
Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with 1H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004 相似文献
62.
In this paper we define and study an extension of the g-Drazin for elements of a Banach algebra and for bounded linear operators based on an isolated spectral set rather than on
an isolated spectral point. We investigate salient properties of the new inverse and its continuity, and illustrate its usefulness
with an application to differential equations. Generalized Mbekhta subspaces are introduced and the corresponding extended
Mbekhta decomposition gives a characterization of circularly isolated spectral sets. 相似文献
63.
Shuguang Wang 《Geometriae Dedicata》1995,57(2):207-215
We classify, in terms of simple algebraic equations, the fixed point sets of the moduli space of stable bundles over genus 2 curves with anti-holomorphic involutions.Research supported by SRF of University of Missouri. 相似文献
64.
We demonstrate that the 3-power torsion points of the Jacobians of the principal modular curves X(3n) are fixed by the kernel of the canonical outer Galois representation of the pro-3 fundamental group of the projective line
minus three points. The proof proceeds by demonstrating the curves in question satisfy a two-part criterion given by Anderson
and Ihara. Two proofs of the second part of the criterion are provided; the first relies on a theorem of Shimura, while the
second uses the moduli interpretation.
Received: 30 September 2005 相似文献
65.
66.
Jan J. Dijkstra 《Topology and its Applications》2006,153(15):2948-2951
In 1988 A. Gutek proved that there exist one-point connectifications of hereditarily disconnected spaces that do not have the fixed point property. We improve on this result by constructing a one-point connectification of a totally disconnected space without the fixed point property. 相似文献
67.
Piotr Niemiec 《Topology and its Applications》2006,153(18):3373-3382
Equicontinuous semigroups of transformations of a compact Hausdorff space and their sets of all invariant (Borel, regular and probabilistic) measures are studied. Conditions equivalent to the existence of at least one invariant measure are given. The (algebraic and topological) structure of the set of invariant measures is researched. 相似文献
68.
主要讨论了不含k-C-圈的n阶r-一致超图,对不同的k,分别得出了它的极大边数的一个下界,并且得出在有些情况下它的下界是最大的.另外,我们得到了Krn含k-C-圈的一个充分必要条件. 相似文献
69.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献
70.
本文对二种新合成的2,3-二羟基萘二钼和四钼多酸有机衍生物[n-Bu)4N]2[Mo2O5(OC10H6O)2](Ⅰ)和[n-Bu)4N]2[Mo4O10(OC10H6O)2(OCH3)2](Ⅱ)进行了红外光谱与核磁共振波谱研究,发现[Mo2O5]^2 中钼氧多桥键的红外振动频率较[Mo4O10(OCH3)2]^2 中钼氧多桥键的红外振动频率红移,而在配合物Ⅱ中2,3-二羟基中芳环的^1H化学位移较配合物Ⅰ中向低场移动。同时还发现含二钼配位中心[Mo2O5]^2 的[Mo2O5(OC10H6O)2]^2-与含四钼配位中心[Mo4O10(OCH3)2]^2 的[Mo4O10(OC10H6O)2(OCH3)2]^2-生成条件的差异仅仅只在反应体系的pH值的微小变化,说明钼多酸有机衍生物阴离子是对体系酸碱度极为敏感的物质。 相似文献