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水解胶原蛋白热氧化及CaSO4形成机理探讨;水解胶原蛋白; L-抗坏血酸; H2O2; 热氧化; CaSO4 相似文献
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ZHANG Jin-lei TAN Xue-cai ZHAO Dan-dan TAN Sheng-wei HUANG Zeng-wei MI Yan HUANG Zai-yin 《高等学校化学研究》2010,26(4):541-545
<正>A novel third-generation hydrogen peroxide(H_2O_2) biosensor(Hb/CdS/MWNTs/GCE) was fabricated through hemoglobin(Hb) adsorbed onto the mercaptoacetic acid modified CdS QDs/carboxyl multiwall carbon nanotubes'(MWNTs) films.Cyclic voltammogram of Hb/CdS/MWNTs/GCE showed a pair of well-defined and quasi-reversible redox peaks with a formal potential(E~0) of-0.230 V(vs.Ag/AgCl) in 0.1 mol/L pH=8.0 phosphate buffer solution(PBS),which was the characteristic of the Hb heme Fe(Ⅲ)/Fe(Ⅱ) redox couple.The biosensor shows an excellent electrocatalytic activity to the reduction of H_2O_2.The response time of the designed biosensor to H_2O_2 at a potential of -0.30 V was less than 2 s and linear relationships were obtained in the concentration ranges of 2.0×10~(-6)—2.7×10~(-3) mol/L and 2.7×10~(-3)—7.7×10~(-3) mol/L with a detection limit of 3.0×10~(-7)mol/L(S/N=3).The apparent Michaelis-Menten constant K_m was estimated to be 1.324 mmol/L that illustrated the excellent biological activity of the fixed Hb. 相似文献
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1,2,3-三氮唑化合物是一类具有重要生理活性的含氮杂环化合物, 其在医药、农药、材料科学等领域都具有广泛的应用. 不断开发基于三氮唑骨架的新型结构, 寻找新型高效的合成三氮唑衍生物的方法具有重要的意义和应用价值. 过渡金属催化的C—H键活化策略具有操作简便、效率高、三废少等优点, 是现代有机合成中高效构筑C—C键和C—X键的强大工具. 近年来, 过渡金属催化的三氮唑导向的C—H官能团化反应受到科学工作者的广泛关注, 该方法以不同结构的1,2,3-三氮唑作为导向基团, 在不同反应条件下通过直接活化C—H键来构建新的C—C键和C—X键, 高效合成复杂的三氮唑衍生物. 综述了近年来1,2,3-三氮唑导向下过渡金属催化的C—H键官能团化反应研究进展, 按照成键类型(碳-碳键、碳-杂键以及环化反应)对这些反应进行了梳理和总结, 并对今后该领域的发展进行了展望. 相似文献
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磁共振成像(MRI)是一种强大的非侵入式生物医学诊断技术. 临床上, MRI需要借助造影剂来提高成像质量, 从而提高诊断的准确性. 由于具有优越的信号放大能力和生物相容性, 自组装多肽探针可负载特定的MRI分子, 通过酶促自组装过程实现肿瘤靶向和特异性富集, 增强肿瘤病灶区MRI信号, 从而进一步提高MRI的准确性和灵敏度. 本综述总结了近年来多肽自组装探针在不同MRI模式( 1H MRI, 19F MRI和双自旋核MRI)下的最新进展, 并展望了这类新型探针在MRI领域的应用前景. 相似文献
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Establishing a reliable method to predict the global mean temperature (Te) is of great importance because CO2 reduction activities require political and global cooperation and significant financial resources. The current climate models all seem to predict that the earth's temperature will continue to increase, mainly based on the assumption that CO2 emissions cannot be lowered significantly in the foreseeable future. Given the earth's multifactor climate system, attributing atmospheric CO2 as the only cause for the observed temperature anomaly is most likely an oversimplification; the presence of water (H2O) in the atmosphere should at least be considered. As such, Te is determined by atmospheric water content controlled by solar activity, along with anthropogenic CO2 activities. It is possible that the anthropogenic CO2 activities can be reduced in the future. Based on temperature measurements and thermodynamic data, a new model for predicting Te has been developed. Using this model, past, current, and future CO2 and H2O data can be analyzed and the associated Te calculated. This new, esoteric approach is more accurate than various other models, but has not been reported in the open literature. According to this model, by 2050, Te may increase to 15.5 ℃ under "business-as-usual" emissions. By applying a reasonable green technology activity scenario, Te may be reduced to approximately 14.2 ℃. To achieve CO2 reductions, the scenario described herein predicts a CO2 reduction potential of 513 gigatons in 30 years. This proposed scenario includes various CO2 reduction activities, carbon capturing technology, mineralization, and bio-char production; the most important CO2 reductions by 2050 are expected to be achieved mainly in the electricity, agriculture, and transportation sectors. Other more aggressive and plausible drawdown scenarios have been analyzed as well, yielding CO2 reduction potentials of 1051 and 1747 gigatons, respectively, in 30 years, but they may reduce global food production. It is emphasized that the causes and predictions of the global warming trend should be regarded as open scientific questions because several details concerning the physical processes associated with global warming remain uncertain. For example, the role of solar activities coupled with Milankovitch cycles are not yet fully understood. In addition, other factors, such as ocean CO2 uptake and volcanic activity, may not be negligible. 相似文献
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