单壁碳纳米管的轴向能带工程

单壁碳纳米管具有优异的电子学特性,是制备新一代高性能集成电路的重要材料.碳纳米管芯片之路存在诸多挑战,包括直径和手性的控制生长方法、金属性和半导体性单壁碳纳米管的分离方法、器件加工与集成方法等.这些课题从本质上讲大多属于化学问题,因此碳纳米管芯片研究为化学家们提供了新的机遇与挑战.过去10年来,我们围绕单壁碳纳米管的轴向能带工程这一研究思路,开展了一系列碳纳米管芯片的基础探索工作,发展了若干有效的单壁碳纳米管局域能带的调控方法,包括温度阶跃生长法、脉冲供料生长法、基底调控法以及形变调控法等.本文系统地阐述了这些局域能带调控方法,为使读者对该领域的研究进展有一个较为全面的了解,文中对其他课题组开展的代表性工作也给予了综述性介绍.     

Switching in Metal–Organic Frameworks

In recent years, metal–organic frameworks (MOFs) have become an area of intense research interest because of their adjustable pores and nearly limitless structural diversity deriving from the design of different organic linkers and metal structural building units (SBUs). Among the recent great challenges for scientists include switchable MOFs and their corresponding applications. Switchable MOFs are a type of smart material that undergo distinct, reversible, chemical changes in their structure upon exposure to external stimuli, yielding interesting technological applicability. Although the process of switching shares similarities with flexibility, very limited studies have been devoted specifically to switching, while a fairly large amount of research and a number of Reviews have covered flexibility in MOFs. This Review focuses on the properties and general design of switchable MOFs. The switching activity has been delineated based on the cause of the switching: light, spin crossover (SCO), redox, temperature, and wettability.     

金刚石膜在真空电子器件输出窗中的应用

综述了金刚石膜的性能和制备方法，着重介绍丁国内外常用的封接工艺，讨论了该材料在mm波器件中的应用前景。     

Miniaturized molecularly imprinted polymer extraction method for the gas chromatographic analysis of flavonoids

In this study, the use of monolithic molecularly imprinted polymers in a micropipette tip format allowing the simple and fast extraction of flavonoids from standard solutions and a black tea sample is demonstrated. The imprinted polymer employed quercetin, methacrylic acid or 4‐vinylpyridine, and ethylene glycol dimethacrylate as template, functional monomer, and cross‐linker, respectively. Surface morphologies of the quercetin‐imprinted polymers and the corresponding nonimprinted polymers were characterized by SEM. Extraction of flavonoid standards was performed to evaluate the selectivity and recovery with these imprinted and nonimprinted polymers. Flavonoid compositions in aliquots eluted from the tips were identified using fast GC with flame ionization detection. Maximum specific capacities of 0.2, 5.7, and 16.0 mg/g for catechin, morin, and quercetin, respectively, were obtained with the imprinted polymer prepared with methacrylic acid, with the corresponding recoveries of 99.8, 98.8, and 95.4%, respectively. Efficient extraction by the quercetin‐imprinted polymer of epicatechin, catechin, and quercetin from an apple‐flavored black tea sample was achieved, with GC–MS employed for compound identification for both the tea and extracted samples.     

Molecular Machines Working on Surfaces and at Interfaces

In the past ten years a great variety of artificial molecular machines have been constructed, and very interesting concepts for controlling molecular‐level movements by external inputs have been developed. Most of the studies, however, have been performed in solution, where the investigated systems contain a huge number of molecules which behave independently from one another because they cannot be addressed individually. Before such systems can find applications in many fields of technology, they must be interfaced with the macroscopic world by ordering them in some way so that they can behave coherently and can be addressed in space. The problem of obtaining ordered arrays of molecular machines can be addressed by a variety of techniques, which include deposition on surfaces, incorporation into polymers, organization at interfaces, and immobilization in membranes or porous materials. In the last few years, the development of scanning‐probe techniques has also enabled direct observation and manipulation of single molecular‐machine molecules on surfaces. Techniques of this kind have opened novel routes to the study of molecular machines, and have also contributed to better understanding the differences between movement at the macroscopic and molecular levels. This paper reviews some recent achievements in the field of molecular machines working on surfaces and at interfaces, as single molecules or ordered arrays. Hybrid natural–artificial machines are also discussed, and the working mechanism of some natural machines is illustrated for the purpose of comparison.     

Transparent and flexible field emission display device based on single‐walled carbon nanotubes

A fully transparent and flexible field emission device (FED) has been demonstrated. Single‐walled carbon nanotubes (SWCNTs) coated on arylite substrate were used as electron emitters for the FED and a novel metavanadate phosphor coated on the SWCNTs/arylite film was used as transparent and flexible screen. The SWCNTs/arylite based emitters and the SWCNTs/arylite/metal‐vanadate‐based phosphor showed a transmittance value of 92.6% and 54%, respectively. The assembled device also showed satisfactory transparency and flexibility as well as producing significant current. Metavanadate phosphor is considered to be an excellent candidate due to its superior luminescence properties and easy fabrication onto transparent and flexible conductive substrate at room temperature while retaining reasonable transparency of the substrate. Thus, its transparency and flexibility will open the door to next‐generation FEDs. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Development of a novel 6LoWPAN-based multipurpose sensor monitoring and notification system

In the area of wireless communication technologies, 6LoWPAN leverages the extensive capabilities of IPv6, even within the constraints imposed by resource-limited devices, particularly within wireless sensor networks (WSNs). The integration of 6LoWPAN into modern solutions for implementing the IPv6-based Internet of Things (IoT) is becoming increasingly important. In this paper, a sensor monitoring and notification system specifically designed for deployment over 6LoWPAN has been proposed. Multipurpose capability, scalability, and ease of deployability are the main features of the proposed system. Its architecture reflects the highest degree of flexibility and allows for a variety of use cases encountered in practical scenarios. In addition, a web interface has been developed as part of the comprehensive system architecture. This interface enables efficient management of the entire system and facilitates connection for new users and seamless integration of additional sensors. By encapsulating complex functions in a user-friendly interface, the system promotes accessibility, convenience, and an enhanced user experience. The proposed system overcomes the limitations of current approaches, thereby creating new opportunities. The flexibility of the proposed system allows it to be applied to various use cases.     

PLD在数字信号处理系统中的应用

论述了目前数字电路系统中广泛使用的可编程逻辑器件PLD的特点及发展趋势．以LATTICE公司的可编程逻辑器件ispLSl1032为例,介绍了其在数字信号处理电路中的应用情况,分析了设计流程,提出了开发使用中需要注意的问题．