Towards Dynamic Control of Wettability by Using Functionalized Altitudinal Molecular Motors on Solid Surfaces

We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were introduced to the rotor part of the motors. Molecular motors were attached to quartz surfaces by using interfacial 1,3‐dipolar cycloadditions. To test the effect of the functional groups on the rotary motion, photochemical and thermal isomerization studies of the motors were performed both in solution and when attached to the surface. We found that the substituents have no significant effect on the thermal and photochemical processes, and the functionalized motors preserved their rotary function both in solution and on a quartz surface. Preliminary results on the influence of the functional groups on surface wettability are also described.     

On chip novel video streaming system for bi-network multicasting protocols

In the past three decades, tremendous Ethernet-related research has been done, which has led to today's ubiquitous Ethernet technology. On the other hand, with the emergence of new network needs, a new protocol, the IEEE 1394 standard serial bus (or Firewire) was introduced. Firewire is suitable for high-quality audio/video applications which do not perform well in the best-effort-based Ethernet technology. However, since Firewire is a serial bus, it has harsh cable length limitations as compared to Ethernet capabilities.In this paper, we present a novel on-chip system that receives Firewire video and transmits it in multicast mode using Ethernet protocol. A major advantage of this novel system is to utilize the existing Ethernet infrastructure to extend the range of Firewire video streaming to reach remote nodes and make it even accessible to nodes with a single Ethernet interface. This will have tremendous impact on Firewire applications such as deploying Firewire cameras in big-scale security-sensitive buildings or industrial facilities with image-based remote quality control.This novel chip utilizes the concept of Ethernet multicasting transmission mode for video streaming. The proposed chip design converts the IEEE 1394 isochronous traffic to the Ethernet multicast frame format via two off-chip asynchronous write and read buffers.The goal of this research is to design an On Chip Novel Video Streaming System that avoids performance bottlenecks in the software protocol conversion of these two important network protocols. The author decided to study these two networks because of their broad use and cable power provisioning capabilities. The novel system design is implemented using a customized field programmable gate array (FPGA), which enables the integration of various system components on one chip. The designed prototype is studied using both network monitoring tools and analytical techniques, to verify its function and compare it with the existing approaches.Performance measures show that the On Chip Novel Video Streaming System consumes less than 21 mW of power for 100 Mbps and 82 mW of power for 1 Gbps, and utilizes 57% of a Xilinx Spartan 2-100E-6FT256 FPGA resources. Hence, it is possible to incorporate further extensions. Experimental results show that 88% of the network utilization can be achieved, due to the use of the customized, FPGA-based design of bi-network traffic conversion.     

A theoretical study of the performance of sub-micron MOSFET devices in the presence of edge potential

In the present communication we have presented a detailed theoretical analysis of the performance of the sub-micron device in the presence of the discontinuity at the Si–SiO₂ interface. It is assumed that due to interface discontinuity a potential develops at the edges (Source/Drain) in addition to the built-in-potential. This potential, called Edge Potential, measures directly the extent of the interface roughness. The effect of this potential is more critical in the case of short channel device where drain and source are in close proximity. Our analysis shows that the discontinuity is dominant at the edges but not in the channel. Drive current as well as saturation transconductance decreases in the presence of edge potential. These results suggest that the performance of the device degrades due to the interface roughness. Effect of interface roughness near the edges can be reduced at high gate voltage but it will result more interface roughness scattering.     

Beam focusing through a tapered subwavelength aperture surrounded by dielectric surface gratings

A novel plasmonic nanolens formed by a tapered subwavelength metal slit surrounded by surface dielectric gratings is proposed and demonstrated numerically. By patterning surface corrugations on the output surface, the beam can be focused, by regulating the aperture, the focal length can be controlled effectively. Numerical simulations using Finite-Difference Time-Domain (FDTD) method coupled with anisotropic perfectly matched layer (APML) boundary conditions verify that the proposed metallic lens can focus the radiation on the scale of a wavelength below the substrate and the method is effective for the design of nano-optical devices such as optical microprobes.     

High-performance 850 nm vertical-cavity surface-emitting laser in Gigabit Ethernet network

High-performance oxide vertical-cavity surface-emitting (VCSEL) laser is fabricated, and its usefulness is demonstrated as a suitable transmitting light source at 850 nm operating wavelength for Gigabit Ethernet application. Utilization of barrier reduction layers reveals low-threshold current requirement for operation at high modulation bandwidth. The electrical and optical characteristics, measured from the fabricated VCSEL, are simulated for Gigabit Ethernet transmission. Data rates of 1.25 Gbps with a bit error rate of 10⁻¹¹ are achieved by the use of a specific multimode network simulator.     

High performance oscillator with 2-mW output power at 300 GHz

Material structures and device structures of a 100-GHz InP based transferred-electron device are designed in this paper. In order to successfully fabricate the Gunn devices operating at 100 GHz, the InP substrate was entirely removed by mechanical thinning and wet etching. The Gunn device was connected to a tripler link and a high RF(radio frequency)output with power of 2 mW working at 300 GHz was obtained, which is high enough for applications in current military electronic systems.     

Electrically induced flows in the vicinity of a dielectric stripe on a conducting plane

We report a theoretical and experimental study of the hydrodynamic flow induced by an a.c. electric field in the vicinity of a dielectric stripe deposited on a conducting plate. In the theoretical part, we model the stripe as a small change of the surface capacitance of the plate, and a perturbative approach is used to perform the calculations. This approach predicts an outwards rectified electro-osmotic slip along the surface that generates two steady counter-rotating rolls, the size of which decreases with the frequency. In the experimental section, we use tracers to determine the structure of the flow and investigate its dependence on the frequency and the amplitude of the applied voltage. The structure and amplitude of the observed flow compares satisfactorily with the theoretical analysis. This could guide the design of surface-controlled flows and help to understand the collective behavior of colloids near electrodes. Received 20 June 2002 RID="a" ID="a"e-mail: nadal@crpp.u-bordeaux.fr     

High Molecular Weights,Polydispersities, and Annealing Temperatures in the Optimization of Bulk‐Heterojunction Photovoltaic Cells Based on Poly(3‐hexylthiophene) or Poly(3‐butylthiophene)

A series of poly(3‐hexylthiophene)s (P3HTs) and poly(3‐butylthiophene)s (P3BTs) with predetermined molecular weights and varying polydispersities are prepared using a simplified Grignard metathesis chain‐growth polymerization. Techniques were elaborated to prepare extremely high molecular weight P3HT (number‐average molecular weight of around 280 000 g mol^–1) with a low polydispersity (< 1.1) without resorting to fractionation. Optimization of the annealing of a series of solar cells based on blends of poly(3‐alkylthiophene)s (P3ATs) and [6,6]‐phenyl C₆₁ butyric acid methyl ester indicates that the polydispersities, molecular weights, and degrees of conjugation of the P3ATs all have an important impact not only on cell characteristics but also on the most effective annealing temperature required. The results indicate that each cell requires annealing treatments specific to the type of polymer and its molecular weight distribution.     

敏感元件在有线电视器件中的应用

阐述敏感元件的基本概念及其在有线电视网络器件中的几种典型应用,首先介绍敏感材料的基本类型和今后的发展趋势,然后详细介绍目前比较典型的几种敏感元件在开关稳压电源、Cable Modem、双向放大器、彩电消磁、程控交换机、光工作站中的应用。