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141.
Cyanoacetamides 3 were prepared via reacting ethyl cyanoacetate with benzylamine. Yields and reaction times needed for reaction completion at room temperature, by microwaves (μω) heating and under ultrasound (US) irradiations are compared. The formed cyanoacetamides were coupled with aromatic diazonium salts and the formed arylhydrazones were used as precursors to title triazoles and pyrazoles via reacting the former with hydroxylamine and chloroacetonitrile. Yields of products formed via conventional heating are compared with those of μω and US irradiation. 相似文献
142.
Lucas Pizzuti Luciana A. Piovesan Alex F.C. Flores Frank H. Quina Claudio M.P. Pereira 《Ultrasonics sonochemistry》2009,16(6):728-731
An efficient and green synthesis of thiocarbamoyl-3,5-diaryl-4,5-dihydro-1H-pyrazoles via the condensation of chalcones with thiosemicarbazide in ethanol and KOH under ultrasound irradiation is reported. The products were isolated in good yields after short reaction times. 相似文献
143.
Zirconium-based metal-organic framework materials (Zr−MOFs) have more practical usage over most conventional benchmark porous materials and even many other MOFs due to the excellent structural stability, rich coordination forms, and various active sites. However, their mass-production and application are restricted by the high-cost raw materials, complex synthesis procedures, harsh reaction conditions, and unexpected environmental impact. Based on the principles of “Green Chemistry”, considerable efforts have been done for breaking through the limitations, and significant progress has been made in the sustainable synthesis of Zr−MOFs over the past decade. In this review, the advancements of green raw materials and green synthesis methods in the synthesis of Zr−MOFs are reviewed, along with the corresponding drawbacks. The challenges and prospects are discussed and outlooked, expecting to provide guidance for the acceleration of the industrialization and commercialization of Zr−MOFs. 相似文献
144.
《Wave Motion》2015
The linearised water-wave radiation problem for the oscillating 2D submerged source in an inviscid shear flow with a free surface is investigated analytically. There is a nonzero surface velocity. The depth is infinite and the vorticity is uniform. The amplitudes radiated from the source are calculated analytically. Due to Doppler effects, there may be up to four different emitted waves, and there is resonance with zero group velocity and infinite amplitude. 相似文献
145.
At present, the major drawback for mobile phones is the issue of power consumption. As one of the alternatives to decrease the power consumption of standard, power-hungry location-based services usually require the knowledge of how individual phone features consume power. A typical phone feature is that the applications related to multimedia streaming utilize more power while receiving, processing, and displaying the multimedia contents, thus contributing to the increased power consumption. There is a growing concern that current battery modules have limited capability in fulfilling the long-term energy need for the progress on the mobile phone because of increasing power consumption during multimedia streaming processes. Considering this, in this paper, we provide an offline meaning sleep-mode method to compute the minimum power consumption comparing with the power-on solution to save power by implementing energy rate adaptation (RA) mechanism based on mobile excess energy level purpose to save battery power use. Our simulation results show that our RA method preserves efficient power while achieving better throughput compared with the mechanism without rate adaptation (WRA). 相似文献
146.
147.
We study the equidistribution on spheres of the n-step transition probabilities of random walks on graphs. We give sufficient conditions for this property being satisfied and for the weaker property of asymptotical equidistribution. We analyze the asymptotical behaviour of the Green function of the simple random walk on 2 and we provide a class of random walks on Cayley graphs of groups, whose transition probabilities are not even asymptotically equidistributed. 相似文献
148.
In this paper we show that the Cahn–Hilliard stochastic PDE has a function valued solution in dimension 4 and 5 when the perturbation is driven by a space-correlated Gaussian noise. We study the regularity of the trajectories of the solution and the absolute continuity of its law at some given time and position. This is done by showing a priori estimates which heavily depend on the specific equation, and by proving general results on stochastic and deterministic integrals involving general operators on smooth domains of d which are parabolic in the sense of Petrovskii, and do not necessarily define a semi-group of operators. These last estimates might be used in a more general framework. 相似文献
149.
Abstract
We give a linear symmetric differential operator L defined by
in the 2π-periodic function space, and study the inverse-definiteness property of L. We obtain a complete result about the inverse-definiteness property of L with real constants a and b when b
2-4a > 0 and a - bk
2 + k
4 ≠ 0 for any k ∈? {1, 2, 3, . . . }.
Supported by GNAFACNR and the Natural Science Foundation of China and Jiangsu Provincial Education Commission 相似文献
150.
The electron-phonon interaction in the periodic Anderson model (PAM) is considered. The PAM incorporates the effect of onsite
Coulomb interaction (U) between f-electrons. The influence of Coulomb correlation U on the phonon response of the system is studied by evaluating the phonon spectral function for various parameters of the
model. The numerical evaluation of the spectral function is carried out in the long wavelength limit at finite temperatures
keeping only linear terms in U. The observed behaviour is found to agree well with the general features obtained experimentally for some heavy fermion (HF)
systems. 相似文献