全文获取类型
收费全文 | 59313篇 |
免费 | 7345篇 |
国内免费 | 4979篇 |
专业分类
化学 | 14229篇 |
晶体学 | 998篇 |
力学 | 10466篇 |
综合类 | 616篇 |
数学 | 19121篇 |
物理学 | 15617篇 |
无线电 | 10590篇 |
出版年
2024年 | 165篇 |
2023年 | 746篇 |
2022年 | 1231篇 |
2021年 | 1435篇 |
2020年 | 1824篇 |
2019年 | 1540篇 |
2018年 | 1551篇 |
2017年 | 2129篇 |
2016年 | 2358篇 |
2015年 | 2030篇 |
2014年 | 3303篇 |
2013年 | 4633篇 |
2012年 | 3803篇 |
2011年 | 4075篇 |
2010年 | 3365篇 |
2009年 | 3845篇 |
2008年 | 3779篇 |
2007年 | 3703篇 |
2006年 | 3310篇 |
2005年 | 3079篇 |
2004年 | 2594篇 |
2003年 | 2281篇 |
2002年 | 2033篇 |
2001年 | 1647篇 |
2000年 | 1538篇 |
1999年 | 1405篇 |
1998年 | 1252篇 |
1997年 | 1063篇 |
1996年 | 1029篇 |
1995年 | 779篇 |
1994年 | 692篇 |
1993年 | 553篇 |
1992年 | 568篇 |
1991年 | 418篇 |
1990年 | 325篇 |
1989年 | 273篇 |
1988年 | 210篇 |
1987年 | 146篇 |
1986年 | 102篇 |
1985年 | 156篇 |
1984年 | 154篇 |
1983年 | 72篇 |
1982年 | 96篇 |
1981年 | 76篇 |
1980年 | 46篇 |
1979年 | 57篇 |
1978年 | 41篇 |
1977年 | 45篇 |
1976年 | 20篇 |
1974年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
91.
A.A. FilaretovM.G. Zhizhin L.N. KomissarovaV.P. Danilov V.V. ChernyshevB.I. Lazoryak 《Journal of solid state chemistry》2002,166(2):362-368
A new ammonium indium phosphate (NH4)In(OH)PO4 was prepared by hydrothermal reaction in the In2O3-NH4H2PO4-NH3/OH system (T=200°C, autogenous pressure, 7 days). The formula (NH4)In(OH)PO4 was determined on the basis of chemical and thermal analysis (TG/DSC), X-ray powder diffraction and IR-spectroscopy. (NH4)In(OH)PO4 crystallizes in the tetragonal system with space group P43212 (No. 96); a=9.4232(1) Å, c=11.1766(1) Å, V=992.45(2) Å3; Z=8. The crystal structure was refined by the Rietveld method (Rw=6.35%, Rp=5.10%). The second-harmonic generation study confirmed that structure of (NH4)In(OH)PO4 does not have a center of symmetry. The cis-InO4(OH)2 octahedra form helical chains, parallel to the c-axis. The In-O-In bonds are nearly equidistant. The chains are interconnected by phosphate tetrahedra and create tunnels containing the NH4+ ions along the c-axis. (NH4)In(OH)PO4 is isostructural with RbIn(OH)PO4. 相似文献
92.
Mu Jie YANG Kuan LIU 《中国化学快报》2006,17(10):1381-1384
Since the early works of A. J. Heeger, A G. MacDiarmid and Hideki Shirakawa on semiconducting polymers, π-conjugated oligomers and polymers have been actively investigated for a variety of optoelectronic applications, such as field effect transitors (FET… 相似文献
93.
94.
Absorbance values between 300 and 800 nm of aqueous solutions of poly(N-isopropyl acrylamide-co-itaconic acid-9.80), poly(N-isopropyl acrylamide-co-itaconic acid-52.05) and poly(N-isopropyl acrylamide)s containing Tegomer H-Si 2111 end groups and/or blocks were measured using a Shimadzu 160-A UV-visible spectrometer. Turbidities obtained from these absorbance values were used to interpret the macromolecular phase transition from a hydrophilic to a hydrophobic structure of the polymers. The effects of comonomer type and content, concentration of the solutions, pH and temperature on the coil-globule transition were discussed in terms of turbidity form factor, β related to size and shapes of particles and calculated by using the simplified form of Debye equation.The results presented in this work show that the presence of Tegomer H-Si 2111 (Si containing end groups and/or blocks) or high amount of itaconic acid (IA) in the chains prevent a collapse transition from hydrated extended coils to hydrophobic globules, which aggregate and form a separate phase (β<2). Furthermore, it was observed that in the case of concentrated solutions intermolecular hydrophobic interactions between isopropyl groups overcame the repulsive forces resulting from the ionized carboxylic acid groups of IA or surface active nature of Si containing hydrophobic groups (β>2). This stage of the transition corresponds to macroscopic phase separation after an intramolecular process. 相似文献
95.
纳米级NiTiO3粉体的合成 总被引:3,自引:0,他引:3
以H2TiO3,H2O2及NiCl2为主要原料,用化学共沉淀法制备了纳米级NiTiO3。确定了反应物H2TiO3,H2O2,NH3的最佳摩尔比为1:8:2,用不同的退火温度和退火时间对样品处理得到相应粒径的纳米级粉体。 相似文献
96.
97.
严继民 《中国科学B辑(英文版)》1990,(7)
An ab initio calculation of the hydrogen bond complex (HF)_2 is given with the 6-311 G~(**) basis set, according to which the potential surface around the balance point of the distancès and the orientations between two HF molecules is obtained. The atomic charges in the system are calculated with the PD/LSF method (potential-derived/least-square-fitting method) and then an analysis of the hydrogen bond interaction between two HF molecules is given with the (exp-6-1) potential function, by means of which it is shown that the main interaction between them is not an electro-static but a charge transfer one. The potential curve between two HF molecules is like a Morse function. 相似文献
98.
根据在自由基引发剂存在下,8,9-苯并-2-亚甲基-1,4,6-三氧螺(4,4)壬烷(Ⅰ)可能存在的竞争反应,推导了动力学方程式。用红外光谱法测定了单体的消失速率和苯酞的生成速率。实验结果与推导动力学方程式相符。进一步证明了单体(Ⅰ)的增长反应由加成聚合和开环—异构化—加成这两个反应组成。这两个反应对总速率的相对贡献与单体浓度有关。得到了共聚物的结构。 相似文献
99.
Numerical results for the ground state of the HN
2
+
and HCO+ molecular ions at their near equilibrium geometry, obtained by the complex molecular orbitals (CMO) method in the extended basis set, are reported. The CMO wavefunction of the HN
2
+
ion is compared with the CI wavefunction obtained in the same basis set. This reveals the nature of approximations inherent in the CMO method. A peculiar feature of the occupation numbers of the CMO natural orbitals is also explained.Alexander von Humboldt Fellow. On leave from the Institute Rudjer Bokovi, Zagreb, Croatia, Yugoslavia. 相似文献
100.
This paper presents in detail a robust, efficient and accurate methodology for the computation of equilibrium composition in gaseous mixtures. The methodology is founded on the concept of the chemical basis, which is defined and formalized using a powerful matricial approach. The method is specially designed to be general, thus providing basic thermodynamic data in several areas, such as combustion, plasma chemistry and, more generally speaking, computational fluid dynamics. The performance of the method is given in terms of CPU usage and the computed results are compared with those in the published literature. The method is shown to yield results of very high quality in terms of accuracy and smoothness. 相似文献