Macroscopic non-equilibrium thermodynamics in dynamic calorimetry

What is really measured in dynamic calorimetric experiments is still an open question. This paper is devoted to this question, which can be usefully envisaged by means of macroscopic non-equilibrium thermodynamics. From the pioneer work of De Donder on chemical reactions and with other authors along the 20th century, the question is tackled under an historical point of view. A special attention is paid about the notions of frequency dependent complex heat capacity and entropy production due to irreversible processes occurring during an experiment. This phenomenological approach based on thermodynamics, not widely spread in the literature of calorimetry, could open significant perspectives on the study of macro-systems undergoing physico-chemical transformations probed by dynamic calorimetry.     

Time jitter analysis of 1-bit sigma-delta synthesizer

This letter presents a general analysis of time jitter in sigma-delta synthesizer. One of the practical applications of 1-bit sigma-delta systems is a generation of high-resolution local oscillator (LO) signals. In order to generate LO signals, one may use a single-bit sigma-delta technique to encode sine waves. Today, direct generation of high-frequency sine wave using a clock with higher frequency, is possible. In this letter, we will analyze different LO signal generators and develop a practical way of computation to decide how to choose the best configuration under minimum degradation of signal-to-noise ratio (SNR) at the output.     

布里渊区内能带E(k)=E(-k)的对称性

说明了布里渊区内能带Ｅ（ｋ）＝Ｅ（－ｋ）的对称性是时间反演对称性的结果，而与晶体的空间对称性无关．并且证明了当晶体具有中心反演对称性时，布里渊区内能带是二重简并的．     

POM晶体倍频相位匹配角的设计及应用

计算了新型有机晶体ＰＯＭ的倍频匹配角，并将ＰＯＭ作为倍频器件用于超短光脉冲的测量中。     

集成半导体器件的工作稳定性与频响设计

本文用频响特性与试验研究相结合的方法,对三个微电子产品实例进行模拟,讨论了如何设计补偿元件,防止自激振荡,保证闭环稳定且满足各项性能指标要求的问题。     

ⅡB族同核准分子Hg2226.2nm漫射带研究

本文报导在高纯Ｈｇ蒸气石英放电管中首次观测到峰值位于２２６．２ｎｍ左右属于Ｈｇ２准分子ＧＯ＾＋ｕ→ＸＯ＾＋ｇ束缚→自由跃迁的漫射带辐射，实验测量了漫射带强度随放电电流、气体温度和密度的变化关系，获得漫射带最大信号输出的工作参量。     

Asymptotic behavior of energy band associated with a negative energy level

The mathematical foundation of the tight binding approximation is given. If ₀ is a negative energy level of a real potentialq, then there exists an energy band for a one-dimensional chain with period 2T of the same atoms which lies near ₀. We study this band whenT tends to infinity.On leave of absence from the Department of Physics, Leningrad State University, Leningrad, USSR.     

Conformations, Energy and Spectral Characteristics of 2,3-Trimethylene- and 2,3-Pentamethylene-3,4-dihydro-4-quinazolinones

Quantum-chemical calculations and IR spectroscopy were used to study the conformations as well as the energy and spectral characteristics of 2,3-trimethylene- and 2,3-pentamethylene-3,4-dihydro-4-quinazolinones. The shift of -electron density from the heterocyclic system to the carbonyl group and, thus, the proton affinity of the oxygen atom of this group increase with expansion of the bond angle at the nitrogen atom in going from a five-membered to seven-membered ring.     

Broadband and band-selective IMPRESS-gHMBC: compensation of refocusing inefficiency with synchronized inversion sweep

Compensation of refocusing inefficiency in a gHMBC experiment by replacing the rectangular pi pulse with a pair of adiabatic pulses with synchronized inversion sweep (CRISIS) significantly improves the performance of the gHMBC experiment. The CRISIS-gHMBC experiment retains the pure absorptive shapes in F1 and hence results in better lineshape and higher resolution than the current versions of magnitude mode gHMBC spectra. When used as a broadband experiment, CRISIS-gHMBC, owing to better refocusing efficiency of the adiabatic pulse pairs, gives improved performance across the 13C spectral width. Moreover, it is shown that CRISIS-gHMBC is a robust and improved alternative and when used along with the IMPRESS (Improved Resolution using Symmetrically Shifted pulses) technique further increases the sensitivity and resolution without additional experimental time. The IMPRESS-CRISIS combination is demonstrated for broadband gHMBC and band-selective gHMBC experiments. The ICbs-gHMBC [IMPRESS-CRISIS-band-selective gHMBC] experiment is an attractive and better alternative to individual band-selective gHMBC.