电气工程及其自动化技术在供热建设中的难点分析

本文将探讨研究电气工程及其自动化技术在供热建设中的难点,分析解决问题的办法,希望能够促进供热系统的建设与发展,为研究学者们提供一定的借鉴意义。     

基于资源能力需求计划的区分服务MPLS流量工程

本文对近期区分服务MPLS流量工程相关框架进行了研究，在此基础上提出一个新的框架结构。增加了新的模块包括资源能力计划、能力需求调度排期和路由路径管理模块，并提出平行路径资源调度新算法，模拟分析显示可以有效实现流量工程更高程度规划管理，增强了网络规划流量工程方面的性能。     

Incremental analysis for MCDM with an application to group TOPSIS

The study aims to exploit incremental analysis or marginal analysis to overcome the drawbacks of ratio scales utilized in various multi-criteria or multi-attribute decision making (MCDM/MADM) techniques. In the proposed 11-step procedure, multiple criteria of alternatives are first reorganized as two categories – benefits and costs – and decision information will be manipulated separately. The performances of alternatives are then evaluated on their incremental benefit–cost ratio, and the rank can be obtained by applying the group TOPSIS (technique for order preference by similarity to ideal solution) model (Shih et al., 2007). Two representations of cost, i.e., a cost index and utility index, are proposed in the model to better-fit real-world situations. In addition, some considerations on costs and input–output relations are also discussed in order to understand the essentials of incremental analysis. In the final part, a case of robot selection demonstrates the suggested model to be both robust and efficient in a group decision-making environment.     

提高话务承载能力与载频收益的综合优化方案

基于对广西联通GSM网络现状的分析,通过专题优化项目的实践验证,总结出一套全面、系统的资源优化流程:通过综合运用各种操作性较强的非资本性优化手段,可有效地缓解网络拥塞,提高整网的话务承载能力与载频收益。     

Efficient activation of peroxymonosulfate by hollow cobalt hydroxide for degradation of ibuprofen and theoretical study

Hollow microsphere structure cobalt hydroxide (h-Co(OH)₂) was synthesized via an optimized solvothermal-hydrothermal process and applied to activate peroxymonosulfate (PMS) for degradation of a typical pharmaceutically active compound, ibuprofen (IBP). The material characterizations confirmed the presence of the microscale hollow spheres with thin nanosheets shell in h-Co(OH)₂, and the crystalline phase was assigned to α-Co(OH)₂. h-Co(OH)₂ could efficiently activate PMS for radicals production, and 98.6% of IBP was degraded at 10 min. The activation of PMS by h-Co(OH)₂ was a pH-independent process, and pH 7 was the optimum condition for the activation-degradation system. Scavenger quenching test indicated that the sulfate radical (SO₄^{? ?}) was the primary reactive oxygen species for IBP degradation, which contributed to 75.7%. Fukui index (f ^?) based on density functional theory (DFT) calculation predicted the active sites of IBP molecule for SO₄^{? ?} attack, and then IBP degradation pathway was proposed by means of intermediates identification and theoretical calculation. The developed hollow Co(OH)₂ used to efficiently activate PMS is promising and innovative alternative for organic contaminants removal from water and wastewater.     

Nd(OTf)3-catalyzed intramolecular-intermolecular cascade cyclization reaction: An access to phenanthro[9,10-b]furan derivatives

An intramolecular-intermolecular cascade cyclization reaction via multi metal-carbene intermediates has been developed. This reaction uses catalytic amount of Nd(OTf)₃, which actives both alkyne and aldehyde moieties. This protocol provides a novel strategy for the synthesis of phenanthro[9,10-b]furans.     

Encapsulated ultrafine and highly dispersed molybdenum dioxide nanoparticles in hollow mesoporous silica spheres as an efficient epoxidation catalyst for alkenes

A facile post-synthetic strategy was developed to functionalize the preformed hollow mesoporous silica spheres by encapsulating the molybdenum dioxide (MoO₂) nanoparticles inside the interior cavity. Hollow mesoporous silica spheres were prepared and employed as carriers, and the encapsulation of MoO₂ nanoparticles was achieved through a one-pot hydrothermal protocol. After characterization, the encapsulated MoO₂ nanoparticles were certified to be ultrafine and highly dispersed, which greatly promoted the catalytic activity. The as-prepared catalysts were utilized in epoxidation of alkenes and exhibited as a promising catalyst in this reaction. After reacting for 10 h, the optimal catalyst MoO₂@SiO₂-1 achieved a conversion above 95% and selectivity above 95%, respectively. Moreover, the catalysts also exhibited good reusability, conversion of 78% and selectivity of 89% (reaction time 4 h) were still obtained after recycling for 5 times. Meanwhile, the employed facial and efficient hydrothermal approach could be expanded to other molybdenum modified heterogeneous catalysts in various applications.