全文获取类型
收费全文 | 3857篇 |
免费 | 145篇 |
国内免费 | 366篇 |
专业分类
化学 | 1147篇 |
晶体学 | 14篇 |
力学 | 328篇 |
综合类 | 6篇 |
数学 | 439篇 |
物理学 | 1404篇 |
无线电 | 1030篇 |
出版年
2024年 | 10篇 |
2023年 | 148篇 |
2022年 | 113篇 |
2021年 | 112篇 |
2020年 | 137篇 |
2019年 | 93篇 |
2018年 | 113篇 |
2017年 | 161篇 |
2016年 | 130篇 |
2015年 | 145篇 |
2014年 | 229篇 |
2013年 | 270篇 |
2012年 | 188篇 |
2011年 | 287篇 |
2010年 | 223篇 |
2009年 | 260篇 |
2008年 | 271篇 |
2007年 | 223篇 |
2006年 | 209篇 |
2005年 | 133篇 |
2004年 | 123篇 |
2003年 | 123篇 |
2002年 | 94篇 |
2001年 | 75篇 |
2000年 | 54篇 |
1999年 | 49篇 |
1998年 | 56篇 |
1997年 | 44篇 |
1996年 | 28篇 |
1995年 | 31篇 |
1994年 | 28篇 |
1993年 | 22篇 |
1992年 | 27篇 |
1991年 | 28篇 |
1990年 | 17篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 12篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1975年 | 2篇 |
1973年 | 6篇 |
1970年 | 1篇 |
排序方式: 共有4368条查询结果,搜索用时 15 毫秒
91.
Tonggang Jiu Yongjun Li Haiyang Gan Yuliang Li Huibiao Liu Shu Wang Weidong Zhou Chunru Wang Xiaofang Li Xiaofeng Liu Daoben Zhu 《Tetrahedron》2007,63(1):232-240
The oligo(p-phenylene vinylene)-porphyrin-oligo(p-phenylene vinylene) (P-OPVn, n=2, 4, where n is the number of phenyl rings) and the complex with Zn2+ based on P-OPVn were synthesized for investigating their photophysical properties via UV-vis, voltammetry, steady-state and time-resolved fluorescence spectra. In these molecules two OPV moieties as energy donors were linked to porphyrin center by virtue of Wittig reaction. The detailed studies of photophysical properties indicate that OPV group can act as an antenna unit for effective intramolecular energy transfer. 相似文献
92.
用真空蒸发沉积的方法制备了纳米稀土(La、Nd、Sm)粒子 BaO介质薄膜.研究表明薄膜的光电发射光谱响应阈值受纳米稀土粒子形状和大小的影响,球形纳米稀土(Sm)粒子 BaO介质薄膜的光谱响应阈值波长为720 nm,条状纳米稀土(La和Nd)粒子 BaO介质薄膜阈值波长分别为650 nm和660 nm.研究得到纳米稀土粒子 介质薄膜等效界面位垒高度在1.7~2.0 eV之间.由于纳米稀土粒子与BaO介质各自逸出功不同,当构成薄膜后使得纳米粒子周围的空间电荷分布发生变化,纳米粒子周围的能带发生弯曲. 相似文献
93.
根据化合物形成过程中价电子能量变化与生成焓之间的关系, 推导出烷烃的生成焓和电离能之间的关系. 以21个烷烃化合物为模型将实验测定的电离能与标准生成焓进行直接关联, 证实了模型方程的适用性, 所得回归方程的相关系数达到0.9999, 估算值与实验值之间的标准偏差仅为0.03 eV. 同时还利用实验测定的标准生成焓对一系列烷烃的电离能作了预测. 相似文献
94.
Interlayer energy transfer between 2,3-naphthol-10-hexadecylaza-15-crown-5(NC16) and N-[1-(9-methoxyanthryl)] decylaza-15-crown-5(A10C) within multilayer Langmuir-Blodgett films has been studied by steady-state fluorescence spectra. The donor and acceptor could be separated precisely by inserting stearic acid (SA) spacers. The efficiency of the energy transfer increases with the decrease in the donor-acceptor distance by a quadratic manner, suggesting the donor excitations are delocalized in the layer. 相似文献
95.
Based on building emerging engineering education of "energy chemistry", we investigated the state key petro-chemical enterprises according to the industrial development and the demand of professional talents. The research report summarizes, analyzes and discusses the current priority development fields of industry, the talent training status, curriculum structure and education program of the chemistry and chemical engineering in universities. The ideas on emerging engineering education of "energy chemistry" have been proposed, and it will be beneficial to building a novel education program for talents training, which integrates the principle of chemistry, energy conversion and information science, etc. 相似文献
96.
- Download : Download high-res image (233KB)
- Download : Download full-size image
97.
Catherine D. Clark Morton Z. Hoffman D. Paul Rillema Quinto G. Mulazzani 《Journal of photochemistry and photobiology. A, Chemistry》1997,110(3):285-290
The photophysics of three complexes of the form Ru(bpy)3−(pypm)2+ (where bpy2,2′-bipyridine, pypm 2-(2′-pyridyl)pyrimidine and P=1, 2 or 3) was examined in H2O, propylene carbonate, CH3CN and 4:1 (v/v) C2H5OH---CH3OH; comparison was made with the well-known photophysical behavior of Ru(bpy)32+. The lifetimes of the luminescent metal-to-ligand charge transfer (MLCT) excited states were determined as a function of temperature (between −103 and 90 °C, depending on the solvent), from which were extracted the rate constants for radiative and non-radiative decay and ΔE, the energy gap between the MLCT and metal-centered (MC) excited states. The results indicate that *Ru(bpy)2(pypm)2+ decays via a higher lying MLCT state, whereas *Ru(pypm)32+ and *Ru(pypm)2(bpy)2+ decay predominantly via the MC state. 相似文献
98.
《Arabian Journal of Chemistry》2020,13(9):7115-7131
The impregnation of magnetite (Mt) nanoparticle (NPs) onto Musa acuminata peel (MApe), to form a novel magnetic combo (MApe-Mt) for the adsorption of anionic bromophenol blue (BPB) was studied. The SEM, EDX, BET, XRD, FTIR and TGA were used to characterize the adsorbents. The FTIR showed that the OH and CO groups were the major sites for BPB uptake onto the adsorbent materials. The average Mt crystalline size on MApe-Mt was 21.13 nm. SEM analysis revealed that Mt NPs were agglomerated on the surface of the MApe biosorbent, with an average Mt diameter of 25.97 nm. After Mt impregnation, a decrease in BET surface area (14.89 to 3.80 m2/g) and an increase in pore diameter (2.25–3.11 nm), pore volume (0.0052–0.01418 cm3/g) and pH point of zero charge (6.4–7.2) was obtained. The presence of Pb(II) ions in solution significantly decreased the uptake of BPB onto both MApe (66.1–43.8%) and MApe-Mt (80.3–59.1%), compared to other competing ions (Zn(II), Cd(II), Ni(II)) in the solution. Isotherm modeling showed that the Freundlich model best fitted the adsorption data (R2 > 0.994 and SSE < 0.0013). In addition, maximum monolayer uptake was enhanced from 6.04 to 8.12 mg/g after Mt impregnation. Kinetics were well described by the pseudo-first order and liquid film diffusion models. Thermodynamics revealed a physical, endothermic adsorption of BPB onto the adsorbents, with ΔHo values of 15.87–16.49 kJ/mol, corroborated by high desorption (over 90%) of BPB from the loaded materials. The viability of the prepared adsorbents was also revealed in its reusability for BPB uptake. 相似文献
99.
用巯基乙酸做稳定剂制备了水溶性CdSe纳米颗粒, 用十六烷基三甲基溴化铵(HTAB)、发光性(4-甲氧基均二苯乙烯基)二甲基乙基溴化铵 (MODAB)及末端含有双键的(4-甲基丙烯酰氧基均二苯乙烯基)二甲基乙基溴化铵(MSDAB)对该CdSe纳米颗粒进行了混合组装.通过改变三种有机分子的比例可以调控所得组装体的溶解性、聚合性及其发光性质.实验结果表明,当HTAB:MODAB:MSDAB=1:5.98~5.90:0.02~0.10(摩尔比)时,所得组装体具有较好的聚合性、溶解性和荧光性质. 相似文献
100.
基于能量量化的小波域数字音频水印算法 总被引:1,自引:0,他引:1
利用混沌动力学系统中logistic映射先对水印图像进行置乱预处理以增强其鲁棒性,在小波域中将原始音频信号按比例分段,求得每段的能量然后将其按步长delta以及要嵌入的水印的值进行量化,然后用量化后的能量与量化前的能量之比乘以该段每一个值即完成一位水印的嵌入。反复执行以上步骤,完成全部水印的嵌入。若低频部分分组数大于水印序列个数则重复嵌入。采用StirMark for Audio攻击后的实验结果表明该方案对StirMark for Audio的部分攻击具有一定的鲁棒性。 相似文献