LC/ESI-MS n and 1H HR-MAS NMR analytical methods as useful taxonomical tools within the genus Cystoseira C. Agardh (Fucales; Phaeophyceae)

Species of the genus Cystoseira are particularly hard to discriminate, due to the complexity of their morphology, which can be influenced by their phenological state and ecological parameters. Our study emphasized on the relevance of two kinds of analytical tools, (1) LC/ESI-MSⁿ and (2) ¹H HR-MAS NMR, also called in vivo NMR, to identify Cystoseira specimens at the specific level and discuss their taxonomy. For these analyses, samples were collected at several locations in Brittany (France), where Cystoseira baccata, C. foeniculacea, C. humilis, C. nodicaulis and C. tamariscifolia were previously reported. To validate our chemical procedure, the sequence of the ITS2 has been obtained for each species to investigate their phylogenetic relationships at a molecular level. Our study highlighted the consistency of the two physico-chemical methods, compared to “classical” molecular approach, in studying taxonomy within the genus Cystoseira. Especially, LC/ESI-MSⁿ and phylogenetic analyses converged into the discrimination of two taxonomical groups among the 5 species. The occurrence of some specific signals in the ¹H HR-MAS NMR spectra and/or some characteristic chemical compounds during LC/ESI-MSⁿ analysis could be regarded as discriminating factors. LC/ESI-MSⁿ and ¹H HR-MAS NMR turned out to be two relevant and innovative techniques to discriminate taxonomically this complex genus.     

Thermal analysis applied to the characterization of degradation in soil of polylactide: I. Calorimetric and viscoelastic analyses

An accelerated soil burial test has been performed on a commercial polylactide (PLA) for simulating non-controlled disposal. Degradation in soil promotes physical and chemical changes in polylactide properties, which can be characterized by Thermal Analysis techniques. Physical changes occurred in polylactide due to the degradation in soil were evaluated by correlating their calorimetric and viscoelastic properties. It is highly remarkable that each calorimetric scan offers specific and enlightening information. Degradation in soil affects the polylactide chains reorganization. A multimodal melting behavior is observed for buried PLA, degradation in soil also promotes the enlarging the lamellar thickness distribution of the population with bigger average size. Morphological changes due to degradation in soil lead to an increase in the free volume of the polylactide chains in the amorphous phase that highly affected the bulk properties. Thermal Analysis techniques provide reliable indicators of the degradation stage of polylactide induced by degradation in soil, as corroborated by molecular weight analysis.     

两种系统级单粒子效应容错方法性能仿真分析

基于VLSI的信息处理系统空间应用时容易遭受单粒子翻转效应(SEU:Single Event Upset)的影响.基于结构冗余的三模冗余(TMR:Three Module Redundancy)和基于信息冗余的错误检纠错(EDAC:Error Detection and Correction)是两种常见的系统级抗单粒子翻转的容错方法,被广泛应用于空间信息处理系统中.从可靠性改进、存储资源占用、硬件实现代价以及实现延时等四个方面,对两种方法进行了性能分析和仿真实验.性能分析和仿真实验结果表明,EDAC方法适合应用于基本数据宽度较大、存储资源受限、实时性要求不高的应用中,结构TMR方法适合应用于基本数据宽度较小、存储资源充足、实时性要求较高的应用中.     

临近空间中核爆源区电磁脉冲与等离子体流场耦合

对临近空间中核爆源区电磁脉冲与飞行器等离子体流场的耦合进行了分析计算。对源区辐射场采用平面波近和源区感应场直接计入等离子体电导率的影响,推导出新的差分迭代公式计算。计算结果可供临近空间飞行器电磁兼容性研究参考。     

基于投影和主成分分析的偏心检测

在生产实践中,管类工件的内部结构之中常常存在微小的偏心误差。偏心误差对工件的工作性能影响很大,因此,能否准确、快速地检测出偏心误差在生产实践中意义重大。本文介绍了一种基于投影数据和主成分分析的偏心检测方法。截取工件中任意两个截面,利用Radon变化求得它们在一定投影角度下的投影。分别计算投影的第一主成分,并以第一主成分之间的欧氏距离表征偏心误差。如果欧氏距离不等于零,则证明工件存在偏心误差。通过仿真实验证明该方法能检测出0.1%的微小偏心,并且抗噪性能较好。     

近期国外陶瓷-金属封接的技术进展

本文叙述了近期国外陶瓷-金属封接技术的进展,特别是有关Mo粉的有关特性,并对国外典型产品作了分析报告。     

国内第一条真空灭弧室自动检测线的建立

应用工业工程的方法,对灭弧室成品检验进行了作业流程分析,概述了灭弧室自动检测线的建立过程,描述了灭弧室成品检验进行工业自动化改造的应用效果,提高检测效率3倍以上,降低劳动强度80%。     

强非线性广义 Boussinesq 方程孤波解的波形分析及求解

上海理工大学理学院\quad 上海 200093该文建立了强非线性广义 Boussinesq 方程的耗散项、波速、渐进值与波形函数的导数之间的关系.利用适当变换和待定假设方法,作者求出了上述广义 Boussinesq 方程的扭状或钟状孤波解,还求出了以前文献中未曾提到过的余弦函数的周期波解.进一步给出了波速对波形影响的结论,即:``好'广义 Boussinesq 方程的行波当波速由小变大时,波形由钟状孤波变成余弦函数周期波解;``坏'广义 Boussinesq 方程的行波当波速由小变大时,波形由余弦函数周期波解变成钟状孤波.     

木薯淀粉改性絮凝剂的光谱研究

采用氧化还原引发体系引发木薯淀粉与丙烯酰胺接枝共聚制备出天然木薯淀粉改性絮凝剂,用紫外-可见吸收光谱(UV-Vis)、红外光谱(FTIR)和拉曼光谱(RS)详细对比研究了木薯淀粉、丙烯酰胺和接枝共聚物三者的光谱特征,并据此讨论了接枝共聚机理.     

概率神经网络及FAAS在植物药分类研究中的应用

用火焰原子吸收法（FAAS）测定了植物药中Fe、Mg、Mn、Cu、Zn和Ca元素的含量,采用主成分分析法对所测数据进行预处理,结合概率神经网络模型对中药功效类别进行识别预测研究,取得了较满意的结果。