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61.
I. Esteban-Díez 《Analytica chimica acta》2006,555(1):84-95
Orthogonal WAVElet correction (OWAVEC) is a pre-processing method aimed at simultaneously accomplishing two essential needs in multivariate calibration, signal correction and data compression, by combining the application of an orthogonal signal correction algorithm to remove information unrelated to a certain response with the great potential that wavelet analysis has shown for signal processing. In the previous version of the OWAVEC method, once the wavelet coefficients matrix had been computed from NIR spectra and deflated from irrelevant information in the orthogonalization step, effective data compression was achieved by selecting those largest correlation/variance wavelet coefficients serving as the basis for the development of a reliable regression model. This paper presents an evolution of the OWAVEC method, maintaining the first two stages in its application procedure (wavelet signal decomposition and direct orthogonalization) intact but incorporating genetic algorithms as a wavelet coefficients selection method to perform data compression and to improve the quality of the regression models developed later. Several specific applications dealing with diverse NIR regression problems are analyzed to evaluate the actual performance of the new OWAVEC method. Results provided by OWAVEC are also compared with those obtained with original data and with other orthogonal signal correction methods. 相似文献
62.
Hong Tao Gao Dong Mei Dai Tong Hua Li 《中国化学快报》2007,18(4):495-498
Non-negative matrix factorization(NMF)is a technique for dimensionality reduction by placing non-negativity constraints onthe matrix.Based on the PARAFAC model,NMF was extended for three-dimension data decomposition.The three-dimension non-negative matrix factorization(NMF3)algorithm,which was concise and easy to implement,was given in this paper.The NMF3algorithm implementation was based on elements but not on vectors.It could decompose a data array directly without unfolding,which was not similar to that the traditional algorithms do.It has been applied to the simulated data array decomposition andobtained reasonable results.It showed that NMF3 could be introduced for curve resolution in chemometrics. 相似文献
63.
Formylation is one of the newly discovered post-translational modifications in lysine residue which is responsible for different kinds of diseases. In this work, a novel predictor, named predForm-Site, has been developed to predict formylation sites with higher accuracy. We have integrated multiple sequence features for developing a more informative representation of formylation sites. Moreover, decision function of the underlying classifier have been optimized on skewed formylation dataset during prediction model training for prediction quality improvement. On the dataset used by LFPred and Formator predictor, predForm-Site achieved 99.5% sensitivity, 99.8% specificity and 99.8% overall accuracy with AUC of 0.999 in the jackknife test. In the independent test, it has also achieved more than 97% sensitivity and 99% specificity. Similarly, in benchmarking with recent method CKSAAP_FormSite, the proposed predictor significantly outperformed in all the measures, particularly sensitivity by around 20%, specificity by nearly 30% and overall accuracy by more than 22%. These experimental results show that the proposed predForm-Site can be used as a complementary tool for the fast exploration of formylation sites. For convenience of the scientific community, predForm-Site has been deployed as an online tool, accessible at http://103.99.176.239:8080/predForm-Site. 相似文献
64.
65.
M. F. Gonnord I. Ignatiadis A. Jaulmes C. Vidal-Madjar 《Journal of separation science》1987,10(7):392-397
The performances of some numerical methods to improve the signal to noise ratio are compared and applied to enhance noisy signals obtained in gas chromatography with capillary columns and a flame Ionization detector. Several methods have been considered: cutoffs In the Fourier transform of the recorded signal; real time numerical filtering; theoretical model curve fitting; and the correlation of a chromatogram recorded from a pseudorandomly injected sample with the pseudorandom injection function. Numerical real time filtering is shown to be the most convenient method when the main periodic component of the noise has been determined by Fourier analysis. 相似文献
66.
Deep neural networks represent a compelling technique to tackle complex real-world problems, but are over-parameterized and often suffer from over- or under-confident estimates. Deep ensembles have shown better parameter estimations and often provide reliable uncertainty estimates that contribute to the robustness of the results. In this work, we propose a new metric to identify samples that are hard to classify. Our metric is defined as coincidence score for deep ensembles which measures the agreement of its individual models. The main hypothesis we rely on is that deep learning algorithms learn the low-loss samples better compared to large-loss samples. In order to compensate for this, we use controlled over-sampling on the identified ”hard” samples using proper data augmentation schemes to enable the models to learn those samples better. We validate the proposed metric using two public food datasets on different backbone architectures and show the improvements compared to the conventional deep neural network training using different performance metrics. 相似文献
67.
Existing point cloud classification researches are usually conducted on datasets with complete structure and clear semantics. However, in real point cloud scenes, the occlusion and truncation may destroy the completeness of objects affecting the classification performance. To solve this problem, we propose an incomplete point cloud classification network (IPC-Net) with data augmentation and similarity measurement. The proposed network learns the feature representation of incomplete point clouds and the semantic differences compared to the complete ones for classification. Specifically, IPC-Net adopts a random erasing-based data augmentation to deal with incomplete point clouds. IPC-Net also introduces an auxiliary loss function weighted by attention scores to measure the similarity between the incomplete and the complete point clouds. Extensive experiments verify that IPC-Net has the ability to classify incomplete point clouds and significantly improves the robustness of point cloud classification under different completeness. 相似文献
68.
69.
传统的多目标跟踪数据关联算法需要提前知晓目标运动模型和杂波密度等先验信息,然而这些先验信息在跟踪之前无法及时准确地获取。针对这个问题,提出一种基于Transformer网络的多目标跟踪数据关联算法。首先,考虑到传感器会存在漏检的情况,引入虚拟量测来重新建立数据关联模型。在此基础上,提出基于Transformer网络的数据关联方法来解决多目标与多量测的匹配问题。同时,设计了一种掩蔽交叉熵损失与重叠度损失相结合的损失函数(MCD)用于优化网络参数。仿真和实测数据结果表明:在不同检测概率条件下,所提算法性能均优于经典的数据关联算法和基于双向长短时记忆网络的算法。 相似文献
70.
《Digital Communications & Networks》2022,8(5):636-643
With the development of the Internet of Things (IoT), the massive data sharing between IoT devices improves the Quality of Service (QoS) and user experience in various IoT applications. However, data sharing may cause serious privacy leakages to data providers. To address this problem, in this study, data sharing is realized through model sharing, based on which a secure data sharing mechanism, called BP2P-FL, is proposed using peer-to-peer federated learning with the privacy protection of data providers. In addition, by introducing the blockchain to the data sharing, every training process is recorded to ensure that data providers offer high-quality data. For further privacy protection, the differential privacy technology is used to disturb the global data sharing model. The experimental results show that BP2P-FL has high accuracy and feasibility in the data sharing of various IoT applications. 相似文献