无线智能仓储管理系统的设计与实现

利用RFID技术与ZigBee技术融合组网的方式实现了智能仓储管理系统的设计。重点阐述了由CC2530作为ZigBee无线通信的射频芯片和核心控制器,CLRC632作为RFID射频芯片组成网络中各节点的硬件结构,同时给出了系统软件设计主流程图。经测试表明,该系统能够实现门禁、考勤、物品定位、安防等高效、实时地智能化仓储管理。     

Cleavage of acetylenic substituents from camphor-derivatives by copper(I) chloride

Copper(I) chloride was found to be a highly efficient reagent to promote the cleavage of acetylenic substituents from the camphor skeleton of compounds 1 containing two C-C triple bonds as well as from the compounds 6 and 7 containing one. This is a formal reversal of the formation of these compounds by the reaction of acetylides with keto and imino groups in compound 18. The substituent R at the triple bond modifies the reactivity and regioselectivity. As intermediates in the process we identified complexes of the types [Cu(L)_depr] (where (L)_depr denotes a deprotonated camphor-derived ligand (L)) and [CuCl(L)]. Quantum mechanical calculations support and rationalize the experimental results.     

B离子掺杂TiO2催化剂(TiO2－xBx)光催化活性的研究

采用溶胶-凝胶法制备出纳米TiO₂和TiO_2－xB_x催化剂. 光催化实验证明, TiO_2－xB_x催化剂的紫外、可见光催化活性均高于TiO₂. XRD, XPS和Raman结果表明, B离子是以取代式掺杂占据了TiO₂的O^2－的晶格位置. UV-Vis和PL谱的结果表明, B离子的2p轨道与O的2p轨道形成混合价带, 产生可见光响应, B离子的掺入有效地阻止了光生载流子的复合, 促进了其分离, 是TiO_2－xB_x催化剂紫外、可见光催化活性提高的主要原因.     

基于zigbee技术的电力无线传感温度监测系统的硬件设计与实现

阐述了基于zigbee协议的电力无线传感温度监测系统的硬件设计与实现,将ZigBee 技术与传感器技术结合,应用于电力温度数据采集监测系统中。将终端节点采集到的温度信息,以无线通信方式传送到网关,并通过串口将数据上传到 PC机,从而实现电力温度采集监测功能。     

基于CC3200的智能家居安防系统设计

设计了一款以德州仪器公司的首款单芯片无线微控制器SinpleLink WiFi CC3200为核心,与人体红外感应系统相结合的智能家居安防系统.设计结合Yeelink云和APP,利用CC3200片上WiFi系统传输安防信息,与手机、PC等建立通信,实现红外报警和实时监控.该系统设计基于CC3200的优越性能,使系统成本低、功耗低并有良好的可扩展性,因此具有一定的研究意义.     

云环境下景区游客流量监控与推荐系统设计

设计了云环境下景区游客流量监控与推荐系统,包括CC3200流量监控与景点推荐两部分,流量监控由RFID电子门票统计游客数量,数据经Wi-Fi上行本地AP节点,由AP节点汇聚至云推荐服务器;当前游客流量、时间富裕度、游客满意度,经服务器解析计算得景点综合推荐指数,主动为游客推荐旅游景点,规划最佳游览路线。经测试,系统工作稳定、数据准确,适用于各类景区游客流量监控与推荐服务。     

Optical Spectra of Oligofurans: A Theoretical Approach to the Transition Energies,Reorganization Energies,and the Vibronic Activity

There is experimental evidence of high vibronic activity that accompanies the allowed transition between the ground state and the lowest electronic singlet excited state of oligofurans that contain two, three, and four furan rings. The absorption and emission spectra of the three lowest oligofurans measured at liquid nitrogen temperature show distinct fine structures that are reproduced using the projection-based model of vibronic coupling (with Dushinsky rotation included) parameterized utilizing either Density Functional Theory (DFT, with several different exchange-correlation functionals) or ab initio (CC2) quantum chemistry calculations. Using as a reference the experimental data concerning the electronic absorption and fluorescence for the eight lowest oligofurans, we first analyzed the performance of the exchange-correlation functionals for the electronic transition energies and the reorganization energies. Subsequently, we used the best functionals alongside with the CC2 method to explore how the reorganization energies are distributed among the totally symmetric vibrations, identify the normal modes that dominate in the fine structures present in the absorption and emission bands, and trace their evolution with the increasing number of rings in the oligofuran series. Confrontation of the simulated spectra with the experiment allows for the verification of the performance of the selected DFT functionals and the CC2 method.     

O + NH反应在3A’’和1A’’势能面上的量子含时波包动力学研究

对于O + NH反应,在3A’’和1A’’ 势能面（Guadagnini R, Schatz G C, Walch S P. Global potential energy surface for the lowest 1A’, 3A’’, and 1A’’ states of HNO [J]. J. Chem. Phys., 1995,10:774）上,我们运用coupled state or centrifugal sudden (CS)近似和close coupling or Coriolis coupled (CC)方法进行了量子动力学计算。通过比较两种方法得到的总的反应几率,我们发现对于两个势能面上的标题反应,CS近似是失效的。我们还讨论了用CS和CC方法得到的速率常数,并进行了结果比较。     

一种ZigBee电力无线抄表数据收发终端设计

为了解决ZigBee无线抄表系统数据采集发送集成度不高、设备繁琐等问题,通过对ZigBee无线标准协议的研究和对当前无线抄表系统实现过程的分析,设计出一种基于ZigBee的电表数据收发终端。该终端主要是将MCU系统和RFCC2430无线射频芯片相结合,包括数据接收、无线数据发送和电源三个硬件电路部分,完成对电表数据的接收和无线发送,重点阐述该终端节点的硬件结构设计和软件设计流程。通过对其在无线抄表系统中检测,接收发送数据稳定可靠。实践表明,该终端可作为一个通用模块应用到其他无线收发系统中,具有很强的实用性和可移植性的特点。     

区间规划问题的最优性条件

区间规划是带有区间参数的规划问题,是一种更易于求解实际问题的柔性规划。它是确定性优化问题的延伸,有区间线性规划和区间非线性规划两种形式。本文讨论了目标函数是区间函数的区间非线性问题。给出了区间规划问题最优性必要条件的较简单证明方法,并利用LU最优解的概念,在一类广义凸函数－(p,r)－ρ－(η,θ)－不变凸函数定义下讨论了最优性充分条件。