Determination of polycyclic aromatic hydrocarbons from ambient air particulate matter using a cold fiber solid phase microextraction gas chromatography-mass spectrometry method

Polycyclic aromatic hydrocarbons (PAH) from ambient air particulate matter (PM) were analyzed by a new method that utilized direct immersion (DI) and cold fiber (CF) SPME-GC/MS. Experimental design was used to optimize the conditions of extraction by DI-CF-SPME with a 100μm polydimethylsiloxane (PDMS) fiber. The optimal conditions included a 5min equilibration at 70°C time in an ultrasonic bath with an extraction time of 60min. The optimized method was validated by the analysis of a NIST standard reference material (SRM), 1649b urban dust. The results obtained were in good agreement with certified values. PAH recoveries for reference materials were between 88 and 98%, with a relative standard deviation ranging from 5 to 17%. Detection limits (LOD) varied from 0.02 to 1.16ng and the quantification limits (LOQ) varied from 0.05 to 3.86ng. The optimized and validated method was applied to the determination of PAH from real particulate matter (PM10) and total suspended particulate (TPS) samples collected on quartz fiber filters with high volume samplers.     

低温等离子模型中的一个混合型方程的闭Dirichlet问题

描述理想的低温等离子体中电磁波传播的模型是一个椭圆双曲混合型方程.证明了该方程闭Dirichlet问题弱解的存在唯一性.该结果关于区域的几何结构要求较少.由于这里所讨论的方程的奇异性与Keldysh方程的奇异性有相似性质,而后者的奇异性比Tricomi方程更强,因此关于其正则性的研究是很有意义的.作者给出了一个内正则性结果.     

热矫直机与冷床交接辊道不同步故障的解决方案

本文主要介绍了某钢铁公司宽厚板生产线上,热矫直机输出辊道与冷床输入辊道之间因为以太网通讯存在滞后现象,导致两部分辊道存在速度不同步故障时,根据现场的实际情况提出的小投入,见大效的解决方案。     

Aerodynamics of indirect thrust measurement by the impulse method

The aerodynamic aspects of indirect thrust measurement by the impulse method have been studied both experimentally and numerically. The underlying basic aerodynamic principle is outlined, the phenomena in subsonic, supersonic and arc-heated jets are explored, and factors affecting the accuracy of the method are studied and discussed. Results show that the impulse method is reliable for indirect thrust measurement if certain basic requirements are met, and a simple guideline for its proper application is given.     

高传热性能封装中θ_(jc)测量的挑战

高功耗封装的传热设计需要精确地测量热由芯片结面传到IC封装外壳的热阻值,即θ_(jc)值,用以设计合适的外接散热器。对于热阻值较小的封装来说,由于难以精确获得封装外壳温度值,θ_(jc)的测量和确定具有相当的挑战性。本文研究了四种封装外壳温度的测量方法,包括光测量,弹簧接触,冷板中嵌入热电偶,和热电偶粘贴到封装外壳等方法。测试结果表明,不准确的封装外壳温度测量会导致较大的θ_(jc)的误差。我们开发了一种温度校正标准装置来比较各种测试方法的误差。结果表明,弹簧接触式和光测试方法在测试封装外壳温度时所需的修正较小。     

Rumford and the Reflection of Radiant Cold: Historical Reflections and Metaphysical Reflexes

In this paper I examine the debate regarding the positive reality of cold: whether it is merely an absence of heat, or a quality or entity in its own right. Marc-Auguste Pictet stimulated this debate by showing that radiation from a cold object apparently could be focused by concave mirrors to cool another object some distance away from it. Pictet and other believers in material theories of heat, most notably Pierre Prevost, sought to understand this phenomenon as a result of the radiation of caloric in a peculiar arrangement. By contrast, Count Rumford saw in Pictet's experiment a genuine action of “frigorific rays,” and performed striking new experiments to support his view. For Rumford heat and cold radiation consisted in sound-like undulations in the ether, a mechanism compatible with his own vibration theory of heat, and discordant with the caloric theory. Rumford's strong arguments were overruled only because of the general dominance of the caloric theory of heat. However, Rumford did push the caloric theory to develop in a direction that eventually led to its downfall. I revisit this debate without preconceived notions of the metaphysical nature of cold and heat.     

Free convection flow over a truncated cone embedded in a porous medium saturated with pure or saline water at low temperatures

Steady free convection boundary layer about a truncated cone embedded in a porous medium saturated with pure or saline water at low temperatures has been studied in this paper. The governing coupled partial differential equations are solved numerically using a very efficient finite-difference method. Several new parameters arise and the results are given for some specific values of these parameters. The obtained results for a Boussinesq fluid are compared with known results from the open literature and it is shown that the agreement between these results is very good.     

新型Pd-Ba冷阴极在前向波放大管中的应用

介绍了新型Pd-Ba冷阴极在前向波放大管的应用情况，分析了这种冷阴极的特性，对焊接及处理工艺进行了有益的探索。     

High temperature properties of by-product cold bonded pellets containing blast furnace flue dust

In this investigation, the fundamental reactions occurring during the heat treatment of cold bonded pellets (CBP) comprised of iron and steelmaking by-products have been studied. Blast furnace (BF) flue dust, which contains fractions of coal and coke particles, has been included in the CBP blend as a source of solid reductant. Thermal analysis was performed on CBP samples in inert atmosphere at a heating rate of 10 °C/min in order to observe their high temperature properties, specifically, the mechanisms of self-reduction within CBPs. Both endothermic and exothermic reactions were observed during heating. The gases generated during thermal analysis were analyzed using a quadropole mass spectrometer (QMS). Furthermore, CBP samples heated to several different temperatures and quenched in argon were analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Results from this investigation demonstrate that the decomposition of hydrates and carbonates in CBP samples contribute, as gaseous intermediates, to an earlier reduction of contained iron oxides. The gaseous intermediates are responsible for an initial gasification of carbon contained in blast furnace flue dust leading to low temperature iron oxide reduction. The step-wise reduction of iron oxides in CBPs at the given conditions begins at ∼500 °C and is nearly completed at 1200 °C. This work can help to provide a fundamental understanding of the reduction characteristics of iron and steelmaking by-product agglomerates.