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101.
Eduardo Rissi Roberto Rivelino Sylvio Canuto 《International journal of quantum chemistry》2003,91(4):575-585
Density functional theory (DFT), using the most common functionals, and ab initio quantum chemistry methods are used to calculate the rotational constants and dipole moments of the astrophysically important molecules HCN, CH3CN, CH3CNH+, HCCCN, and HCCNC. As far as millimeter‐wave spectroscopy is of interest the DFT methods performed well with most functionals, giving results within ±1% of experiments for rotational constants and ±3% for dipole moments. Analyzing the results obtained with all theoretical models, it may be concluded that the Becke's three‐parameter exchange functional and the gradient‐corrected functional of Lee, Yang, and Paar (B3LYP) and Becke's three‐parameter functional with Perdew–Wang correlational functional [B3PW91/6‐31G(d, p)] give the best performances. A detailed analysis of the electron correlation effects shows that HCCCN is more stable than is HCCNC, by 1.16 eV, with important contribution arising from triple excitations. This result is also compared with those obtained with DFT methods. Despite occasional difficulties, DFT with the currently available functionals are of great utility in quickly assessing spectroscopic parameters of astrophysical interest. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2003 相似文献
102.
A fictitious domain approach to the numerical solution of PDEs in stochastic domains 总被引:1,自引:0,他引:1
We present an efficient method for the numerical realization of elliptic PDEs in domains depending on random variables. Domains
are bounded, and have finite fluctuations. The key feature is the combination of a fictitious domain approach and a polynomial
chaos expansion. The PDE is solved in a larger, fixed domain (the fictitious domain), with the original boundary condition
enforced via a Lagrange multiplier acting on a random manifold inside the new domain. A (generalized) Wiener expansion is
invoked to convert such a stochastic problem into a deterministic one, depending on an extra set of real variables (the stochastic
variables). Discretization is accomplished by standard mixed finite elements in the physical variables and a Galerkin projection
method with numerical integration (which coincides with a collocation scheme) in the stochastic variables. A stability and
convergence analysis of the method, as well as numerical results, are provided. The convergence is “spectral” in the polynomial
chaos order, in any subdomain which does not contain the random boundaries. 相似文献
103.
For a general K3 surface S of genus g, with 2 ≤ g ≤ 10, we prove that the intermediate Jacobians of the family of prime Fano threefolds of genus g containing S as a hyperplane section, form generically an algebraic completely integrable Hamiltonian system.
The first author is partially supported by grant MI1503/2005 of the Bulgarian Foundation for Scientific Research. 相似文献
104.
In this paper we investigate the electrostatic problem of determining conductivity profiles from the knowledge of boundary
currents and voltages. We obtain an improved estimate for the voltage potential of a two-dimensional conductor having finitely
many circular inclusions and piecewise constant conductivity profile. We derive an asymptotic expansion for the voltage potential
in terms of the reference voltage potential and the location, size, and conductivity of the inhomogeneities. This representation
is used to formulate the nonlinear least squares problem for estimating the location and size of the inhomogeneities. Required
boundary data for the voltage potential are generated numerically by solving a system of integral equations. Computational
experiments are presented to demonstrate the effectiveness of our identification procedure. 相似文献
105.
C. Foias A. E. Frazho I. Gohberg M. A. Kaashoek 《Integral Equations and Operator Theory》1997,29(4):455-490
The family of all solutions of the three chains completion problem with a prescribed tolerance is described explicitly. It is shown that this family can be parameterized by a natural set of contractive upper triangular operators. As an application all solutions to a suboptimal nonstationary Nehari problem are described. 相似文献
106.
R. M. Dudley 《Probability Theory and Related Fields》1994,100(2):175-189
Summary In a separable metric space, if two Borel probability measures (laws) are nearby in a suitable metric, then there exist random variables with those laws which are nearby in probability. Specifically, by a well-known theorem of Strassen, the Prohorov distance between two laws is the infimum of Ky Fan distances of random variables with those laws. The present paper considers possible extensions of Strassen's theorem to two random elements one of which may be (compact) set-valued and/or non-measurable. There are positive results in finite-dimensional spaces, but with factors depending on the dimension. Examples show that such factors cannot entirely be avoided, so that the extension of Strassen's theorem to the present situation fails in infinite dimensions.This research was partially supported by a Guggenheim Fellowship, by National Science Foundation grant DMS 8505550 at MSRI-Berkeley, and other NSF grants 相似文献
107.
Let E\subset \Bbb R
s
be compact and let d
n
E
denote the dimension of the space of polynomials of degree at most n in s variables restricted to E . We introduce the notion of an asymptotic interpolation measure (AIM). Such a measure, if it exists , describes the asymptotic behavior of any scheme τ
n
={ \bf x
k,n
}
k=1
dnE
, n=1,2,\ldots , of nodes for multivariate polynomial interpolation for which the norms of the corresponding interpolation operators do
not grow geometrically large with n . We demonstrate the existence of AIMs for the finite union of compact subsets of certain algebraic curves in R
2
. It turns out that the theory of logarithmic potentials with external fields plays a useful role in the investigation. Furthermore,
for the sets mentioned above, we give a computationally simple construction for ``good' interpolation schemes.
November 9, 2000. Date revised: August 4, 2001. Date accepted: September 14, 2001. 相似文献
108.
Y. Nakamura Ichiro Tanaka N. Takeuchi S. Koshiba H. Sakaki 《Journal of Electronic Materials》1998,27(11):1240-1243
We studied morphology of GaAs surfaces and the transport properties of two-dimensional electron gas (2DEG) on vicinal (111)B
planes. Multi-atomic steps (MASs) are found on the vicinal (111)B facet grown by molecular beam epitaxy, which will affect
electron transport on the facet. We also studied how the morphology of GaAs epilayers on vicinal (111)B substrates depends
on growth conditions, especially on the As4 flux. The uniformity of MASs on the substrates have been improved and smooth surfaces were obtained when the GaAs was grown
with high As4 flux, providing step periodicity of 20 nm. The channel resistance of the 2DEG perpendicular to the MASs is reduced drastically
with this smooth morphology. These findings are valuable not only for fabricating quantum devices on the (111)B facets but
also those on the vicinal (111)B substrates. 相似文献
109.
阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点,具体分析深紫外无机非线性光学晶体硼铍酸锶(SBBO)以氟硼铍酸钾(KBBF)为主要参考晶体的分子设计方法,随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论SBBO作为新型深紫外无机晶体的主要优点,即它既具有更短的紫外吸收边(接近155nm)和较大的非线性光学系数(d22(SBBO)=06×d22(BBO)=138pm/V),同时晶体无明显层状习性,并肯有良好的化学稳定性和机械性能 相似文献
110.
Olaf Steinbach 《Numerische Mathematik》2002,90(4):775-786
Summary. In this paper we investigate a stability estimate needed in hybrid finite and boundary element methods, especially in hybrid
coupled domain decomposition methods including mortar finite elements. This stability estimate is equivalent to the stability
of a generalized projection in certain Sobolev spaces. Using piecewise linear trial spaces and appropriate piecewise constant test spaces,
the stability of the generalized projection is proved assuming some mesh conditions locally.
Received April 11, 2000 / Revised version received February 15, 2001 / Published online July 25, 2001 相似文献