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91.
O2(1Δ) Yield Measurement by Raman Spectroscopy With Elimination of Chlorine Fluorescence Interference 下载免费PDF全文
Rong-rong Cui Wen-bo Shi Lie-zheng Deng He-ping Yang Guo-he Sha Cun-hao Zhang 《化学物理学报(中文版)》2012,25(2):142-146
Deleterious chlorine fluorescence was found to occur at the same frequency as the Raman scattering of O2(1Δ) and O2(3∑), seriously affecting the O2(1Δ) yield measurement in the re-action of chlorine with basic hydrogen peroxide by use of the Raman spectroscopy technique. To solve this problem we have taken advantage of the fact that Raman radiation is always strongly polarized while fluorescence is essentially non-polarized in a gaseous medium. When chlorine utilization of a singlet oxygen generator is 88%, O2(1Δ) yield reaches (42.4±7.4)% with the effect of chlorine fluorescence completely eliminated. 相似文献
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93.
Gas Phase Structure of CF3NCl2 and Preparation of CF3NCl2F+MF6? (M = As, Sb) and CF2 = NCl2F+SbF6? The gas phase structure of CF3NCl2 is reported. The following skeletal parameters are derived (ra-values, error limits are 3σ values): N? C = 1.470(6) Å, N? Cl = 1.733(3) Å, ClNCl = 111.5(4)° and ClNC = 107.6(5)°. CF3NCl2F+MF6? is prepared by fluorination of CF3NCl2 with XeF+MF6?. The same educt CF3NCl2 reacts with XeF+SbF6? at ?40°C to CF2 = NClF+SbF6? under elimination of ClF. 相似文献
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95.
Low-fluence XeCl laser etching of copper foils in a chlorine environment has been studied. The etch rate is fluence-dependent in the range 0.05–1.0 J cm?2 and is governed by the growth characteristics of the chloride layer formed in the interpulse period. Projection etching with good pattern reproduction and resolution for high-aspect-ratio features is demonstrated. 相似文献
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97.
《Electroanalysis》2005,17(8):724-726
The cathodic reaction of chlorine residual (CR) combined with anodic pre‐electrolysis enables the quantification of CR as a gaseous chlorine. Potential‐step chronocoulometry was successfully applied to extend the CR detection range. 相似文献
98.
The chlorite ion is the principal by-product of the treatment of drinking water by chlorine dioxide. In function of the chlorite salt instability, standard solutions of this ion need standardization by iodometric titration, which is a reliable method although labor intensive and time consuming. An alternative method to standardization of aqueous chlorite solutions, based on its direct UV absorption measurement, was presented. Besides the maximum absorption (260 nm) generally used in other studies, the minimum (239 nm) and isosbestic (248 nm) wavelengths were proposed as supplementary points to chlorite quantification and their molar absorptivity coefficients were estimated (155.2 ± 0.6, 104.5 ± 1.0 and 69.0 ± 1.2 L cm−1 mol−1, respectively). The direct spectrophotometric determination of chlorite could be made selectively even in the presence of high concentration of major contaminants (chorine dioxide, chloride and chlorate), being a simple and rapid method, consuming very low volume of sample and generating low quantities of laboratory wastes. 相似文献
99.
Mayra Kerolly Sales Monteiro Mayara Maria Sales Monteiro André Miller de Melo Henrique Javier Llanos Cristina Saez Elisama Vieira Dos Santos Manuel Andrés Rodrigo 《Current Opinion in Electrochemistry》2021
Chlorine dioxide is one of the most interesting oxidants because it combines a strong capacity of oxidation with low formation of hazardous byproducts such as chlorinated organics during its application. Because of that, it is widely used in disinfection of drinking water and, currently, it is aimed to be used in the disinfection of surfaces or buildings. Although it is usually produced by the chemical interaction of chlorite with hypochlorite/chlorine or hydrochloric acid, one interesting alternative for its production is the combination in strongly acidic media of chlorate and hydrogen peroxide. Both compounds are known to be efficiently manufactured with electrochemical technology, opening the possibility of a complete electrochemical process to produce this important oxidant. This review summarizes the recent progress in the electrochemical production of the two raw materials, as well as the complete electrochemical production of chlorine dioxide, not only paying attention to the scientific literature but, most importantly, to recent patents, trying to see in which technology readiness level are each of the technologies and what are the elements of the value chain required for a complete implementation of the technology. 相似文献
100.
Zbigniew Kisiel Ewa Bia?kowska Jaworska Douglas T. Petkie Ivan R. Medvedev 《Journal of Molecular Spectroscopy》2009,254(2):78-86
The analysis of the recently recorded 78-378 GHz broadband spectrum of ClONO2 has been extended to cover rotational transitions in all 14 excited vibrational states up to 650 cm−1 above the ground state. We report new measurements and analysis of the 2ν9 and 3ν9 dyads, and first assignment and analysis for the 4ν9 and 5ν9 triads. The polyad fits encompass a total of over 20 000 newly measured transition frequencies and spectroscopic constants are reported for 10 vibrationally excited states in each of 35ClONO2 and 37ClONO2. All polyads were fitted with a new coupling scheme between the perturbing states combining c-axis Coriolis and Fermi interactions. The scheme is validated by multiple tests of the physical significance of the derived parameters and it results in improved deviations of fits and significant reduction in the number of adjustable parameters. 相似文献