全文获取类型
收费全文 | 17470篇 |
免费 | 1594篇 |
国内免费 | 501篇 |
专业分类
化学 | 4753篇 |
晶体学 | 15篇 |
力学 | 847篇 |
综合类 | 64篇 |
数学 | 6495篇 |
物理学 | 4682篇 |
无线电 | 2709篇 |
出版年
2024年 | 39篇 |
2023年 | 229篇 |
2022年 | 271篇 |
2021年 | 433篇 |
2020年 | 454篇 |
2019年 | 440篇 |
2018年 | 325篇 |
2017年 | 385篇 |
2016年 | 617篇 |
2015年 | 540篇 |
2014年 | 882篇 |
2013年 | 1268篇 |
2012年 | 793篇 |
2011年 | 874篇 |
2010年 | 731篇 |
2009年 | 1005篇 |
2008年 | 1168篇 |
2007年 | 1177篇 |
2006年 | 969篇 |
2005年 | 745篇 |
2004年 | 627篇 |
2003年 | 682篇 |
2002年 | 673篇 |
2001年 | 506篇 |
2000年 | 523篇 |
1999年 | 438篇 |
1998年 | 420篇 |
1997年 | 286篇 |
1996年 | 249篇 |
1995年 | 211篇 |
1994年 | 200篇 |
1993年 | 168篇 |
1992年 | 155篇 |
1991年 | 104篇 |
1990年 | 93篇 |
1989年 | 103篇 |
1988年 | 107篇 |
1987年 | 72篇 |
1986年 | 68篇 |
1985年 | 104篇 |
1984年 | 84篇 |
1983年 | 27篇 |
1982年 | 51篇 |
1981年 | 48篇 |
1980年 | 49篇 |
1979年 | 38篇 |
1978年 | 33篇 |
1977年 | 34篇 |
1976年 | 31篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
61.
M. Combescot 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,60(3):289-303
We reconsider the procedure
developed for atoms a few decades ago by Girardeau, in the light of
the composite-boson many-body theory we recently proposed. The
Girardeau's procedure makes use of a so called “unitary Fock-Tani
operator” which in an exact way transforms one composite bound
atom into one bosonic “ideal” atom. When used to transform the
Hamiltonian of interacting atoms, this operator generates an extremely
complex set of effective scatterings between ideal bosonic atoms and free
fermions which makes the transformed Hamiltonian impossible to write
explicitly, in this way forcing to some truncation. The scatterings
restricted to the ideal-atom subspace are shown to read rather simply in
terms of the two elementary scatterings of the composite-boson many-body
theory, namely, the energy-like direct interaction scatterings
— which describe fermion interactions without fermion exchange — and
the dimensionless Pauli scatterings — which describe fermion exchanges
without fermion interaction. We here show
that, due to a fundamental difference in the scalar products of
elementary and composite bosons, the Hamiltonian expectation
value for N ground state atoms
obtained by staying in the ideal-atom subspace and working
with boson operators only, differ from the exact ones even for N = 2 and
a mapping to the ideal-atom subspace performed, as advocated, from
the fully antisymmetrical atomic state, i.e., the state which obeys the
so-called “subsidiary condition”. This shows that, within this
Girardeau's procedure too, we cannot completely forget the underlying
fermionic components of the particles if we want to correctly describe
their interactions. 相似文献
62.
Poly(ethylcyanoacrylate) nanoparticles prepared by interfacial polymerisation on the basis of microemulsions were prepared in this study and both colloidal systems, nanoparticles and microemulsions, were analysed by visual observation and several microscopic techniques. Phase boundaries for the microemulsions of the two pseudoternary systems ethyloleate, polyoxyethylene 20 sorbitan mono-oleate/sorbitan monolaurate and water with and without butanol as a cosurfactant were determined by visual observation of the samples. Microemulsions containing liquid crystals were determined by polarisation light microscopy. Using freeze-fracture transmission electron microscopy and Cryo-field emission scanning electron microscopy the type of microemulsion (w/o droplet, bicontinuous, solution) was characterised. Nanoparticles prepared from the different types of microemulsion were additionally observed by conventional scanning electron microscopy. The size of the nanoparticles obtained from electron microscopy was in good agreement with particle sizing techniques (photon correlation spectroscopy) from earlier studies and no morphological differences could be observed in particles prepared from the different types of microemulsions. Cryo-field emission scanning electron microscopy proved to be a most valuable technique in the visualisation of the colloidal systems as samples could be observed close to their natural state. 相似文献
63.
Joao Gari da Silva Fonseca Junior Takashi Oozeki Hideaki Ohtake Takumi Takashima Kazuhiko Ogimoto 《Progress in Photovoltaics: Research and Applications》2015,23(10):1203-1218
The development of methods to forecast photovoltaic (PV) power generation regionally is of utmost importance to support the spread of such power systems in current power grids. The objective of this study is to propose and to evaluate methods to forecast regional PV power 1 day ahead of time and to compare their performances. Four forecast methods were regarded, of which two are new ones proposed in this study. Together, they characterize a set of forecast methods that can be applied in different scenarios regarding availability of data and infrastructure to make the forecasts. The forecast methods were based on the use of support vector regression and weather prediction data. Evaluations were performed for 1 year of hourly forecasts using data of 273 PV systems installed in two adjacent regions in Japan, Kanto, and Chubu. The results show the importance of selecting the proper forecast method regarding the region characteristics. For Chubu, the region with a variety of weather conditions, the forecast methods based on single systems' forecasts and the one based on stratified sampling provided the best results. In this case, the best annual normalized root mean square error (RMSE) and mean absolute error (MAE) were 0.25 and 0.15 kWh/kWhavg, respectively. For Kanto, with homogeneous weather conditions, the four methods performed similarly. In this case, the lowest annual forecast errors were 0.33 kWh/kWhavg for the normalized RMSE and 0.202 kWh/kWhavg for the normalized MAE. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
64.
We revisit recent results on integrable cases for higher-dimensional generalizations of the 2D pentagram map: short-diagonal, dented, deep-dented, and corrugated versions, and define a universal class of pentagram maps, which are proved to possess projective duality. We show that in many cases the pentagram map cannot be included into integrable flows as a time-one map, and discuss how the corresponding notion of discrete integrability can be extended to include jumps between invariant tori. We also present a numerical evidence that certain generalizations of the integrable 2D pentagram map are non-integrable and present a conjecture for a necessary condition of their discrete integrability. 相似文献
65.
66.
Azobenzene‐Functionalized Metal–Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules 下载免费PDF全文
Dr. Jinhee Park Dr. Lin‐Bing Sun Ying‐Pin Chen Zachary Perry Prof. Dr. Hong‐Cai Zhou 《Angewandte Chemie (International ed. in English)》2014,53(23):5842-5846
Stimuli‐responsive metal–organic polyhedra (srMOPs) functionalized with azobenzene showed UV‐irradiation‐induced isomerization from the insoluble trans‐srMOP to the soluble cis‐srMOP, whereas irradiation with blue light reversed this process. Guest molecules were trapped and released upon cis‐to‐trans and trans‐to‐cis isomerization of the srMOPs, respectively. This study provides a new direction in the ever‐diversifying field of MOPs, while laying the groundwork for a new class of optically responsive materials. 相似文献
67.
Systematic Tuning and Switching of Neutral and Ionic Phases in a Donor–Acceptor Chain Compound by Doping with Less‐Active Donors and by Pressure Application 下载免费PDF全文
Keita Nakabayashi Prof. Dr. Hitoshi Miyasaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(17):5121-5131
The temperature‐induced stepwise neutral–ionic (N–I) phase transition in the covalently bonded donor–acceptor chain compound [Ru2(2,3,5,6‐F4PhCO2)4DMDCNQI] ? 2(p‐xylene) (2,3,5,6‐F4PhCO2?=2,3,5,6‐tetrafluorobenzoate; DMDCNQI=2,5‐dimethyl‐N,N′‐dicyanoquinodiimine) was systematically tuned over a wide temperature range using two techniques: 1) A chemical technique based on doping with a less‐active donor unit [Ru2II,II(F5PhCO2)4] (F5PhCO2?=pentafluorobenzoate), thereby providing an isostructural doped series [{Ru2II,II(2,3,5,6‐F4PhCO2)4}1?x{Ru2II,II(F5PhCO2)4}xDMDCNQI] ? 2(p‐xylene), with x=0.06, 0.10, 0.21, and 0.24; and 2) a physical technique, which was the application of hydrostatic pressure to the doped compounds. The stepwise N–I transition observed in the original compound was systematically varied in terms of the viewpoints of both transition temperature and transition features (stepwise or monotonic) dependent on the amount of dopants x. Application of pressure efficiently tuned the N–I transitions, with the oxidation phases being dramatically modified by applying only weak pressure up to 4 kbar. Even in cases that led to N–I transitions in small domains of the chains at ambient pressure, the application of pressure caused an expansion of the domains that enabled N–I transitions, finally leading to a complete change in the oxidation state of the chains, from neutral to ionic, accompanied by a change from a paramagnetic state to a ferrimagnetically ordered state. 相似文献
68.
Perturbation of Spin Crossover Behavior by Covalent Post‐Synthetic Modification of a Porous Metal–Organic Framework 下载免费PDF全文
John E. Clements Dr. Jason R. Price Dr. Suzanne M. Neville Prof. Cameron J. Kepert 《Angewandte Chemie (International ed. in English)》2014,53(38):10164-10168
Covalent post‐synthetic modification is a versatile method for gaining high‐level synthetic control over functionality within porous metal–organic frameworks and for generating new materials not accessible through one‐step framework syntheses. Here we apply this topotactic synthetic approach to a porous spin crossover framework and show through detailed comparison of the structures and properties of the as‐synthesised and covalently modified phases that the modification reaction proceeds quantitatively by a thermally activated single‐crystal‐to‐single‐crystal transformation to yield a material with lowered spin‐switching temperature, decreased lattice cooperativity, and altered color. Structure–function relationships to emerge from this comparison show that the approach provides a new route for tuning spin crossover through control over both outer‐sphere and steric interactions. 相似文献
69.
Pd Uptake and H2S Sensing by an Amphoteric Metal–Organic Framework with a Soft Core and Rigid Side Arms 下载免费PDF全文
Jieshun Cui Yan‐Lung Wong Dr. Matthias Zeller Dr. Allen D. Hunter Dr. Zhengtao Xu 《Angewandte Chemie (International ed. in English)》2014,53(52):14438-14442
Molecular components of opposite character are often incorporated within a single system, with a rigid core and flexible side arms being a common design choice. Herein, molecule L has been designed and prepared featuring the reverse design, with rigid side arms (arylalkynyl) serving to calibrate the mobility of the flexible polyether links in the core. Crystallization of this molecule with PbII ions led to a dynamic metal–organic framework (MOF) system that not only exhibits dramatic, reversible single‐crystal‐to‐single‐crystal transformations, but combines distinct donor and acceptor characteristics, allowing for substantial uptake of PdCl2 and colorimetric sensing of H2S in water. 相似文献
70.
Thomas S. Parel Lefteris Danos Liping Fang Tomas Markvart 《Progress in Photovoltaics: Research and Applications》2015,23(10):1357-1366
Fluorescent solar concentrators (FSC) can concentrate light onto solar cells by trapping fluorescence through total internal reflection. In an ideal FSC, the major obstacle to efficient photon transport is the re‐absorption of the fluorescence emitted. In order to decompose the contribution of different photon flux streams within a FSC, the angular dependent re‐absorption probability is introduced and modeled in this paper. This is used to analyze the performance of different FSC configurations and is also compared with experimental results. To illustrate the application of the modeling, the collection efficiency of ideal devices has also been calculated from the re‐absorption probability and is shown to be useful for estimating non‐ideal losses such as those due to scattering or reflection from mirrors. The results also indicate that among the FSCs studied, the performance of those surrounded by four edge solar cells is close to ideal. The rapid optimization of FSCs has also been presented as another practical application of the models presented in this paper. © 2014 The Authors. Progress in Photovoltaics: Research and Applications published by John Wiley & Sons, Ltd. 相似文献