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61.
在 IEEE 802.11b MAC层协议的研究基础上,提出了一种基于无线Ad Hoc网络的最佳中继选择策略,该策略综合考虑瞬时信道信息和节点剩余能量,能够有效防止信道条件好的节点的过度使用,并能保证系统高吞吐量。文中以饱和吞吐量和网络生存时间为性能指标,对新算法和以往协作MAC算法进行仿真和比较,结果表明新算法在网络吞吐量下降不明显的情况下,能大大增加网络生存时间。 相似文献
62.
以LTE-Advanced系统为研究背景,提出了一种基于动态频谱接入技术的载波聚合方案(DSA-CA)。该方案的主要思想是使支持载波聚合技术的eNB根据小区的平均负载自适应地调节聚合的载波数量,从而达到合理利用频谱的目的。通过对基于动态频谱接入技术的载波聚合方案在LTE-Advanced 系统中的性能进行仿真研究,结果表明:DSA-CA方案与传统载波聚合方案(CA)相比,可使系统性能在一定程度上得到提高,尤其当一个小区处于高负载、另一个小区处于低负载时,DSA-CA方案的优势更加明显,此时高负载小区系统吞吐量得到明显提高,低负载小区的频谱效率也显著上升。 相似文献
63.
随着国家互联网 战略部署和移动互联网广泛发展,为在现有商用TD-LTE网络快速部署LTE-Advance关键技术-载波聚合来提升无线网络带宽,本文依据现阶段主流厂商功能实现情况和相关的网络现状进行了实践性研究,主要从频率配置、分量载波转化和移动性管理三方面进行现网配置研究,并提出了相应的参数设置需求,为快速部署载波聚合网络提供了借鉴意义。 相似文献
64.
65.
Fen Jin Yan Lian Jishan Li Jing Zheng Yaping Hu Jinhua Liu Jin Huang Ronghua Yang 《Analytica chimica acta》2013
A highly sensitive and selective fluorescence aptamer biosensors for the determination of adenosine triphosphate (ATP) was developed. Binding of a target with splitting aptamers labeled with pyrene molecules form stable pyrene dimer in the γ-cyclodextrin (γ-CD) cavity, yielding a strong excimer emission. We have found that inclusion of pyrene dimer in γ-cyclodextrin cavity not only exhibits additive increases in quantum yield and emission lifetime of the excimer, but also facilitates target-induced fusion of the splitting aptamers to form the aptamer/target complex. As proof-of-principle, the approach was applied to fluorescence detection of adenosine triphosphate. With an anti-ATP aptamer, the approach exhibits excimer fluorescence response toward ATP with a maximum signal-to-background ratio of 32.1 and remarkably low detection limit of 80 nM ATP in buffer solution. Moreover, due to the additive fluorescence lifetime of excimer induced by γ-cyclodextrin, time-resolved measurements could be conveniently used to detect as low as 0.5 μM ATP in blood serum quantitatively. 相似文献
66.
设计合成出两种含有不同结构单元的新型豆甾醇衍生物凝胶因子(化合物1和2)。通过扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和紫外-可见光谱(UV-Vis)等技术手段对形成凝胶的结构和性能进行研究。结果表明,两种凝胶因子可分别在二甲基亚砜及甲醇溶剂中形成稳定的凝胶。其中化合物1还可在二甲基亚砜/水混合溶液体积比分别为9∶1、8∶2和7∶3中形成稳定的凝胶。当化合物1和2在DMSO溶剂中以质量浓度均为12 mg/mL形成凝胶时,二者的凝胶-溶胶相转变温度(Tgel)分别为51和46 ℃,表明随着凝胶因子中甾体结构单元的增加,其形成凝胶的热稳定性显著下降。在此基础上,以化合物1制备的凝胶为载体,通过紫外-可见光谱对罗丹明B、亚甲基蓝和阿霉素的包封与释放应用进行了研究。结果表明,制备的凝胶可以作为药物载体,并在240 min时在水中达到的最大释放值为84%。本文为豆甾醇衍生物凝胶的制备,及将其作为药物载体在药物输送领域的应用提供了有益的思路。 相似文献
67.
To date, luminescent materials have been preferably used for non-contact optical thermometers. In this manner, novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ (BYEN:Mn4+) phosphors were designed for multi-type non-contact luminescent thermometers based on the dual-emission states and temperature-dependent lifetime (TDL) models. In the temperature range of 303–483 K, the sensing sensitivities based on the dual-emission states of (5D0→7F2, 2Eg→4A2g) and (5D0→7F1, 2Eg→4A2g) were estimated. Especially, the maximum absolute sensing sensitivity (Sa) was found to be about 0.1558 K-1 for the BYEN:0.007Mn4+ phosphor based on the 5D0→7F1 and 2Eg→4A2g positions. This phosphor also exhibited good relative sensing sensitivity (Sr) (0.0186 K-1) based on the 5D0→7F2 and 2Eg→4A2g states. Besides, the relative sensing sensitivities (SR) at 5D0→7F1 and 2Eg→4A2g transitions were estimated to be 0.0034 and 0.0194 K-1, respectively with the help of the TDL technique. In the light of these results, novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ phosphors are expected to be a potentially attractive candidate for applications in multi-type luminescent thermometers. Finally, a novel unique polydimethylsiloxane film exhibiting tricolor-luminescent emissions was introduced and further suggested for high-security anti-counterfeiting. 相似文献
68.
Nicola Y. Edwards David M. Schnable Ioana R. Gearba-Dolocan Jenna L. Strubhar 《Molecules (Basel, Switzerland)》2021,26(1)
Lanthanide complexes have been developed and are reported herein. These complexes were derived from a terpyridine-functionalized calix[4]arene ligand, chelated with Tb3+ and Eu3+. Synthesis of these complexes was achieved in two steps from a calix[4]arene derivative: (1) amide coupling of a calix[4]arene bearing carboxylic acid functionalities and (2) metallation with a lanthanide triflate salt. The ligand and its complexes were characterized by NMR (1H and 13C), fluorescence and UV-vis spectroscopy as well as MS. The photophysical properties of these complexes were studied; high molar absorptivity values, modest quantum yields and luminescence lifetimes on the ms timescale were obtained. Anion binding results in a change in the photophysical properties of the complexes. The anion sensing ability of the Tb(III) complex was evaluated via visual detection, UV-vis and fluorescence studies. The sensor was found to be responsive towards a variety of anions, and large binding constants were obtained for the coordination of anions to the sensor. 相似文献
69.
Sul Lee Sunho Jeong Dongjo Kim Bong Kyun Park Jooho Moon 《Superlattices and Microstructures》2007,42(1-6):361
We have fabricated a solution-processed ZnO thin-film transistor without vacuum deposition. ZnO nanoparticles were prepared by the polyol method from zinc acetate, polyvinyl pyrrolidone, and diethyleneglycol. The solution-processable semiconductor ink was prepared by dispersing the synthesized ZnO in a solvent. Inverted stagger type thin-film transistors were fabricated by spin casting the ZnO ink on the heavily doped Si wafer with 200 nm thick SiO2, followed by evaporation of Cr/Au source and drain electrodes. After the drying and heat treatment at 600 C, a relatively dense ZnO film was obtained. The film characteristics were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). In order to obtain the electrical properties of the solution-derived transistor, the on–off ratio, threshold voltage, and mobility were measured. 相似文献
70.
The difference in time-resolved fluorescence spectrum between the cortical sarcoma and the adjacent normal tissue was studied
in both experimental and theoretical ways. The Clinical data were obtained in vivo using a time-resolved fluorescence spectrometer employing a single fiber-optic probe for excitation and detection. Tissue
was modeled as s-180 sarcoma tumor surrounded with normal muscle and was mediated by the Palladium-porphyrin photosensitizer
(Pd-TCPP). The emitted fluorescence was considered as arising from the tumor tissue or the normal muscle, due to the presence
of the photosensitizer. A computational code which could simulating time-resolved fluorescence emission was presented and
applied to comparing fluorescence decay of photosensitizer in different stages of tumor growth. In this code the different
stages of the tumor was modeled through changing the time τ, the delay of the fluorescence photon emission and z
max, the thickness of the tumor. It was found in the in vivo experiment that the fluorescence from tumor tissue decayed more quickly than from the adjacent normal muscle. For the ten
rats in the first experiment day, the mean decay constant of tumor T
s and normal tissue T
n were 554 and 526 μs, respectively. And T
s increased with the tumor growth, from 554 μs in the first day to 634 μs in the eighth day while T
s kept steady. It was believed that the more adequate oxygen supplied by the normal tissue can more effectively quench the
fluorescence and in the normal tissue the photosensitizer lifetime is smaller. As a result the simulated time-resolved fluorescence
spectrum of normal tissue showed more quickly decay. And the thickness of the tumor can also delay the fluorescence decay.
Both the experimental and simulated results indicated that the germination of the tumor would increase the decay constant
of the time-resolved fluorescence spectrum. So decay constant of the tumor tissue spectrum should be larger than that of adjacent
normal tissue for the reason of hypoxia and overgrouth. This fact could be of use in the tumor diagnoses. 相似文献