天线若丹明染料分子内能量与电荷传递的研究

染料三重态在染料激光的应用中起着重要作用，尤其是三重态一Z重态（T－T）吸收常常会造成谐振腔损耗＊．为了减少由基态吸收而造成的话振腔损耗，带有紫外吸收天线分子的三发色团染料已在研究问，2，5·二苯基螨喳（PP0）在紫外区（如308删）有很强的吸收，PPO－rhod．系列染料（见图1）在紫外区的吸收就很强，由PPO到若丹明母体的单线态一单线态（S功能量传递使这类三发色团染料具有较大的荧光量子效率，较小的基态重复吸收耗能卜，司．然而，在610N640nm区域中这些天线若丹明染料的激光输出效率远远小于若丹明Rh630＊，其原因正是…     

Synthesis of oligo(p-phenylene vinylene)-porphyrin-oligo(p-phenylene vinylene) triads as antenna molecules for energy transfer

The oligo(p-phenylene vinylene)-porphyrin-oligo(p-phenylene vinylene) (P-OPVn, n=2, 4, where n is the number of phenyl rings) and the complex with Zn²⁺ based on P-OPVn were synthesized for investigating their photophysical properties via UV-vis, voltammetry, steady-state and time-resolved fluorescence spectra. In these molecules two OPV moieties as energy donors were linked to porphyrin center by virtue of Wittig reaction. The detailed studies of photophysical properties indicate that OPV group can act as an antenna unit for effective intramolecular energy transfer.     

Time-resolved fluorescence analysis of the mobile flavin cofactor in p -hydroxybenzoate hydroxylase

Conformational heterogeneity of the FAD cofactor in p-hydroxybenzoate hydroxylase (PHBH) was investigated with time-resolved polarized flavin fluorescence. For binary enzyme/substrate (analogue) complexes of wild-type PHBH and Tyr222 mutants, crystallographic studies have revealed two distinct flavin conformations; the ‘in’ conformation with the isoalloxazine ring located in the active site, and the ‘out’ conformation with the isoalloxazine ring disposed towards the protein surface. Fluorescence-lifetime analysis of these complexes revealed similar lifetime distributions for the ‘in’ and ‘out’ conformations. The reason for this is twofold. First, the active site of PHBH contains various potential fluorescence-quenching sites close to the flavin. Fluorescence analysis of uncomplexed PHBH Y222V and Y222A showed that Tyr222 is responsible for picosecond fluorescence quenching free enzyme. In addition, other potential quenching sites, including a tryptophan and two tyrosines involved in substrate binding, are located nearby. Since the shortest distance between these quenching sites and the isoalloxazine ring differs only little on average, these aromatic residues are likely to contribute to fluorescence quenching. Second, the effect of flavin conformation on the fluorescence lifetime distribution is blurred by binding of the aromatic substrates: saturation with aromatic substrates induces highly efficient fluorescence quenching. The flavin conformation is therefore only reflected in the small relative contributions of the longer lifetimes.     

The transitional isoelectric focusing process

The transitional isoelectric focusing (IEF) process (the course of pH gradient formation by carrier ampholytes (CAs) and the correlation of the focusing time with CA concentration) were investigated using a whole-column detection capillary isoelectric focusing (CIEF) system. The transitional double-peak phenomenon in IEF was explained as a result of migration of protons from the anodic end and hydroxyl ions from the cathodic end into the separation channel and the higher electric field at both acidic and basic sides of the separation channel. It was observed that focusing times increase logarithmically with CA concentration under a constant applied voltage. The correlation of focusing time with CA concentration was explained by the dependence of the charge-transfer rate on the amount of charged CAs within the separation channel during focusing.     

碲镉汞薄膜少子寿命测试研究

碲镉汞(HgCdTe)材料的少子寿命是影响碲镉汞红外探测器性能的重要参数.分别采用微波光电导衰减(Microwave Photoconductivity Decay,μ-PCD)法和微波探测光电导(Microwave Detected Photoconductivity,MDP)法对 HgCdTe 薄膜的少子寿命进行了...     

RBF网络用于性能退化的可靠性评估

针对无法用数学式准确描述退化量与环境因子间复杂非线性关系的问题,提出了一种基于RBF网络的退化轨迹建模方法.利用RBF网络能够逼近任意非线性函数的特性,进行退化轨迹的建模,并结合失效值预测产品寿命.将所有估计寿命作为完全失效数据进行可靠性评估,有效地解决了失效数据少的问题.通过对疲劳裂纹增长数据的RBF网络建模分析,证明RBF网络具有很好的函数逼近能力,寿命预测结果非常理想.经验证,在更少的退化数据下,RBF网络仍能够较好地模拟退化轨迹,寿命预测精度较高.     

Hg1-xCdx Te晶体生长及太赫兹性能研究

利用移动加热区方法(THM)生长了不同Cd组分的Hg1-xCdxTe晶体,通过傅立叶光谱仪和太赫兹时域光谱系统,研究了不同Cd组分Hg1-xCdxTe晶体在红外波段和太赫兹波段的透射光谱.当Cd组分小于0.279时,Hg1-xCdxTe材料在0.2～1.5 THz波段透过率接近0.在0.9 THz附近观察到Hg1-xC...     

基于激光-微波双辐射源少子寿命的测定装置

单晶硅材料中光生少数载流子寿命是太阳电池设计及生产过程中需要考虑的一个重要参数。基于微波光电导法的测量原理,从单晶硅材料中的电导率和少数载流子浓度的关系着手,提出了一种基于激光-微波双辐射源的硅材料非平衡少数载流子寿命测量系统,实现了对其寿命的初步测量。实验表明,该设计方案具有可行性。     

液体温度对空泡生长和溃灭过程的影响

采用光偏转测试系统研究了不同温度纯净水中激光空泡脉动过程,通过实验获得了激光空泡在靶表面膨胀和收缩全过程,确定了空泡的最大、最小泡半径、脉动周期和泡壁运动速度。实验采用0℃到70℃的纯净水,测量了空泡的泡半径和脉动周期等特征参量变化情况。实验结果表明,液体温度是影响空泡脉动的一个非常重要的因素,随着液体温度的增加空泡的最大泡半径和溃灭周期均呈增加趋势。给出了相应的理论解释。     

无接触法测量多晶硅材料的少子扩散长度

用微波光电导谱仪无接触、非破坏性地测量了多晶硅的微波光电导谱,推导了由光电导谱计算多晶硅样品的少子扩散长度和表面复合速度的计算方法,并由此算得了样品的少子扩散长度和表面复合速度。测试区域是一个直径为3mm的圆斑。这是一种简便而又准确的测试方法。这样的方法还适用于GaAs薄片材料少子扩散长度的测量和计算。