PHOTOPHYSICAL STUDIES ON ORGANIC COMPOUNDS——TIME-RESOLVED TRANSIENT ABSORPTION SPECTRA STUDIES ON TRIPHENYLAMINE IN VARIOUS SOLVENTS

The transient absorption spectra of triphenylamine (TPA) in various solvents have beeninvestigated by the methods of nanosecond laser photolysis. The lifetimes of TPA were meas-ured. In hexane and ethanol, the transient absorptions of triplet state and triplet excimer ofTPA were observed. However, the transient absorptions of the TPA cation radical was alsoobserved in acetonitrile besides that of the triplet TPA monomer and excimer. According tothe experimental facts, the transient photophysical mechanism of TPA in various solvents hasbeen proposed.     

Prediction of the ageing of rubber using the chemiluminescence approach and isoconversional kinetics

A common scepticism towards the application of many product formulations results from the fact that their long-term stability is difficult to predict. In the present study we report on a new approach of kinetic analysis of the oxidation reactions of natural rubbers with and without stabiliser in an oxygen atmosphere at moderate temperatures using CL measurements carried out on a newly-developed instrumentation. The kinetic parameters of the oxidation process, calculated from the chemiluminescence’s signals by means of the differential isoconversional method of Friedman, were subsequently applied for the simulation of the rubber aging under different temperature profiles. The presented results are the first stage of research by using the chemiluminescence method to measure the oxidative aging of rubber and predicting the life time of rubber items.     

差示扫描量热法测定食用油脂的热氧化稳定性及氧化寿命

利用差示扫描量热法（DSC）测定了四种食用花生油的热氧化稳定性,用Ozawa法和Kissinger法计算了四种食用花生油热氧化反应的动力学参数,推算了不同温度下的氧化寿命。     

功能高分子材料载体在检测诊断中的应用

综述了作为生物活性分子载体用功能高分子材料（生物传感器、胶乳、磁性粒子、凝胶）的合成、特点及其在检测诊断中的应用。     

紫外光离子源-高场不对称波形离子迁移谱检测环境中挥发性有机物

本研究采用紫外光离子源-高场不对称波形离子迁移谱(UV-FAIMS)快速检测环境中挥发性有机物.选取苯和对二甲苯为研究对象,并分析了分离电压、流速等因素对其分离识别的影响.实验结果表明:当分离电压值为0～1200 V时,苯和对二甲苯信号强度逐渐降低,而特征补偿电压值却逐渐增加.实验选取分离电压值为900 V,当载气流速为0～240 L/h时,苯和对二甲苯的特征离子峰信号强度逐渐增加,当载气流速为0～120 L/h时,苯和对二甲苯团簇峰信号强度增加,当载气流速为120～240 L/h时,苯的团簇峰信号强度增加,而对二甲苯的团簇峰信号强度降低.此外,对样品浓度、信号强度与噪声的比值进行探讨,获得UV-FAIMS检测苯的检测限为0.011mg/m3.     

The lifetime of an artificial satellite moving in nonuniform rotating atmosphere and instantaneous circle orbit

The lifetime of an artificial satellite moving in the circular orbit under the action ofnonuniform rotating atmospheric drag is studied from an energy point of view in this paper.The angular velocity of atmospheric rotation decreases with height according tohydrodynamics.The atmospheric density decreases with height according to theexponential formula.The expression for the lifetime of a satellite in the instantaneouscircular orbit in the above-mentioned rotating atmospheric model is derived,and thenumerical estimation for the lifetime of a concrete satellite has been made.The result showsclearly that the satellite lifetime calculated by this paper is shorter than that calculated bythe uniform rotating atmospheric model.     

不同载荷下3Cr13不锈钢涂层磨损寿命研究

在T-11摩擦磨损试验机上研究了不同载荷下高速电弧喷涂3Cr13不锈钢涂层的磨损寿命.提出载荷-涂层磨损寿命耦合的关系函数方程.通过对涂层磨损形貌观察,分析了不同载荷对磨损失效机制的影响.结果表明:当载荷较低时,涂层磨损寿命分散程度大,磨损主要失效机制为点蚀和剥落;当载荷较高时,涂层磨损寿命分散程度小,分层是引发涂层磨损失效的关键机制.     

Comparison of in-situ measurement techniques of solder joint reliability under thermo-mechanical stresses

Thermo Mechanical Cycle Lifetime (TMCL) test is a widely used test methodology for evaluating the reliability of solder joints in the microelectronics industry. The commonly used measurement techniques to monitor solder joint failures during the TMCL test are either event detector or data logger. In this study, TMCL test has been carried out on the same devices in parallel with both measurement techniques. The pros and cons of both techniques are compared. It is observed that the solder joint reliability results on the investigated samples by both techniques are comparable. The event detector can catch short intermittent events, while the data logger is able to capture the details of the solder joint degradation process. In applications for which performance is dependent on the transmission of signals with a frequency of several hundred megahertz or more, the event detector technique shall be used. In such cases the data logger technique may overestimate product lifetime. On the other hand, for some applications where the performance is less susceptible to intermittent solder joint interconnect interruption but more to the increase of the solder joint resistance, the data logger shall be used. In such cases the event detector technique may underestimate product lifetime. In conclusion depending on the end application of the device, the most suitable technique can be selected.     

Carrier Frequency Offset estimation for interleaved OFDMA uplink based on subspace processing

This paper investigates Carrier Frequency Offset （CFO）, estimation in the uplink of the Orthogonal Frequency-Division Multiple Access （OFDMA） systems with the interleaved subcarrier assignment. CFOs between the transmitters and the uplink receiver will destroy orthogonality among different subcarriers, hence resulting in inter-carrier interference and multiuser interference. A two-stage frequency offset estimation algorithm based on subspace processing is proposed. The main advantage of the proposed method is that it can obtain the CFOs of all users simultaneously using only one OFDMA block. Compared with the previously known methods, it not only has a relatively low implementation complexity but is also suitable for random subchannel assignment.     

Estimation of carrier frequency offsets for MIMO systems with distributed transmit antennas

The problem of estimating the carrier frequency offsets in Multiple-Input Multiple-Output (MIMO) systems with distributed transmit antennas is addressed. It is supposed that the transmit antennas are distributed while the receive antennas are still centralized, and the general case where both the time delays and the frequency offsets are possibly different for each transmit antenna is considered. The channel is supposed to be frequency flat, and the macroscopic fading is also taken into consideration. A carrier frequency offset estimator based on Maximum Likelihood (ML) is proposed, which can separately estimate the frequency offset for each transmit antenna and exploit the spatial diversity. The Cramer-Rao Bound (CRB) for synchronous MIMO (i.e., the time delays for each transmit antenna are all equal) is also derived. Simulation results are given to illustrate the per- formance of the estimator and compare it with the CRB. It is shown that the estimator can provide satisfactory frequency offset estimates and its performance is close to the CRB for the Signal-to-Noise Ratio (SNR) below 20dB.