Y态TU1环的动态脆性碎裂特性

针对膨胀环的碎裂问题,以Mott碎裂理论和Grady能量平衡理论为基础,利用裂纹张开位移碎裂模型（crack opening displacement model,COD）描述脆性无氧铜环的碎裂特性,并推导了碎片尺寸和数目表达式。利用电磁膨胀环加载技术,完成了不同应变率的脆性无氧铜（TU1）环碎裂实验,实验结果与理论计算结果符合较好,可为脆性金属环膨胀碎裂特性描述提供参考。     

Moving line crack accompanied with damage zone subject to remote tensile loading

In the 1920s, a closed-form solution of the moving Griffith crack was first obtained by Yoffe. Based on Yoffe's solution, the Dugdale model for the moving crack case gives a good result. However, the Dugdale model fails when the crack speed is closed to the Rayleigh wave speed because of the discontinuity occurred in the crack opening displacement (COD). The problem is solved in this paper by introducing a restraining stress zone ahead of the crack tip and two velocity functions. The restraining stresses are linearly distributed and related to the velocity of the moving crack. An analytical solution of the problem is obtained by use of the superposition principle and a complex function method. The final result of the COD is continuous while the crack moves at a Rayleigh wave speed. The characteristics of the strain energy density (SED) and numerical results are discussed, and conclusions are given.     

UV-spektroskopische Untersuchungen an cis-und trans-Bis(phenyl)bis(phosphan)platin(II)-Verbindungen

A long-wavelength absorption band in the UV spectra of compounds of the typecis-and trans-bis(phenyl)bis(tri-n-butylphosphane) platinum(II) and cis-bis-(phenyl)bis(tris[4-(dimethylamino)phenyl]phosphane)platinum(II) is probably due to the influence of substituents in the phenyl rings in the form of a phenyl → platinum charge-transfer-transition.     

Influence of Vapor Phase Pretreatments of Epoxy Surfaces on the Nucleation of MOCVD Copper Thin Films

Vapor phase pretreatments of epoxy composite material reinforced with carbon fibers were carried out prior to the growth of Cu thin films by metal-organic chemical vapor deposition (MOCVD) using Cu (hfa)(COD) as copper precursor. These dry surface oxidation processes include H₂O/UV, O₂/UV and O₂/Plasma treatments. Oxygen plasma method is the most efficient to oxidize the surface and it has the greatest effect to improve the wettability of epoxy samples. As a consequence, the higher hydrophilicity of the plasma-modified epoxy surface induces a higher nucleation density in the Cu film. Furthermore, this treatment reduces drastically the induction period observed for the growth of the metal. Even though the O₂/UV pretreatment incorporates almost the same amount of oxygen in the epoxy surface than the plasma treatment, the functional groups are different, as revealed by XPS analyses, and the surface is less hydrophilic. Correlations between oxidation, wettability and nucleation density of the Cu films are discussed.     

COD阻力曲线的单试样三曲线分析法

在三曲线分析的基础上,提出了一种新的单试样测定 COD 阻力曲线的方法和步骤,编制了计算机应用程序。用三曲线法测定了 C—Mn 钢,Cr-Mo 钢和一种焊缝金属的 COD 阻力曲线,与标准的多试样法实验结果符合较好。该方法使用方便经济。有推广使用的价值。     

大功率单隧道结半导体激光器的研制简

针对大功率隧道结半导体激光器因光学灾变损伤(COD)而导致输出光功率无法进一步提高的问题,通过优化器件材料结构,提高了其COD阈值.采用标准的半导体激光器制作工艺,制作了发光区条宽为200 μm、腔长为900 μm的单隧道结半导体激光器.在脉冲宽度为200 ns、重复频率为5 kHz的室温下进行测试,器件峰值功率超过70 W,并且无明显COD现象发生.在20 A工作电流下,器件峰值波长为907 nm,光谱宽度为7 nm,斜率效率为1.88,接近相同工作电流下单有源层激光器的两倍.     

微波消化光度法测定化学需氧量

研究了微波化制样光度法测定ＣＯＤ的新方法,确定了微波消化的主要因素,要佳消化条件和测定条件,吸光度与ＣＯＤ值在０－１ｇ．Ｌ＾－１范围内呈良好的线性关系。对实际水样测定结果的准确度和精密度都能很好的满意测定要求。     

MBBR处理低C/N生活污水影响因素研究

摘要：采用移动床生物膜反应器(MBBR)处理低C/N生活污水,重点考察了填充率(PR)、水力停留时间(HRT)和溶解氧(DO)等对MBBR脱氮除磷及COD去除的影响.结果表明：在填充率为30%,控制HRT=6 h,DO=3.0±0.25 mg·L-1的条件下,经驯化的MBBR系统处理此类低C/N生活污水,COD、氨氮、TN及TP的平均去除率〖JP2〗分别为92.4%、85.8%、70.4%和40.1%,脱氮削碳效果较为理想,对于提高除磷需考虑联合其他工艺作进一步研究.     

矿山酸碱混合废水的氧化处理

针对某铜矿矿山酸性废水具有低pH值,含大量Fe3+、Fe2+以及Cu2+等金属离子和浮选废水中存在大量残留浮选药剂,废水COD较高等特点,分别研究了NaClO,O3和Fe2+/H2O2三种氧化剂对该混合废水中残留浮选药剂的降解处理效果.研究表明:利用H2O2氧化方法降低混合废水的COD是可行的,而NaClO和O3的氧化效果则较差;H2O2最佳的投加浓度为340mg/L时,COD的去除率可达91.6%.对H2O2氧化机理的研究表明,混合废水中的Fe2+与H2O2在低pH值下反应生成活性自由基是残留浮选药剂去除的关键.最后,应用动力学模型对Fenton氧化反应进行了模拟.