全文获取类型
收费全文 | 4714篇 |
免费 | 244篇 |
国内免费 | 411篇 |
专业分类
化学 | 3085篇 |
晶体学 | 71篇 |
力学 | 33篇 |
综合类 | 28篇 |
数学 | 605篇 |
物理学 | 860篇 |
无线电 | 687篇 |
出版年
2024年 | 5篇 |
2023年 | 34篇 |
2022年 | 112篇 |
2021年 | 104篇 |
2020年 | 76篇 |
2019年 | 182篇 |
2018年 | 237篇 |
2017年 | 83篇 |
2016年 | 113篇 |
2015年 | 89篇 |
2014年 | 142篇 |
2013年 | 268篇 |
2012年 | 188篇 |
2011年 | 263篇 |
2010年 | 264篇 |
2009年 | 365篇 |
2008年 | 325篇 |
2007年 | 305篇 |
2006年 | 287篇 |
2005年 | 260篇 |
2004年 | 234篇 |
2003年 | 182篇 |
2002年 | 234篇 |
2001年 | 132篇 |
2000年 | 101篇 |
1999年 | 73篇 |
1998年 | 82篇 |
1997年 | 59篇 |
1996年 | 73篇 |
1995年 | 66篇 |
1994年 | 80篇 |
1993年 | 63篇 |
1992年 | 49篇 |
1991年 | 28篇 |
1990年 | 26篇 |
1989年 | 20篇 |
1988年 | 21篇 |
1987年 | 16篇 |
1986年 | 15篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 13篇 |
1980年 | 10篇 |
1979年 | 16篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1975年 | 4篇 |
排序方式: 共有5369条查询结果,搜索用时 687 毫秒
981.
5,7-二羟基黄酮与牛血清白蛋白相互作用的研究 总被引:1,自引:0,他引:1
用荧光光谱(FS)和紫外光谱(UV)法研究了5,7-二羟基黄酮与牛血清白蛋白之间的相互作用.实验结果表明,5,7-二羟基黄酮与BSA形成基态复合物导致内源荧光淬灭,淬灭机理主要为静态淬灭.该反应的结合常数4.16×107 L/mol,结合位点数n=1.5;并用同步荧光技术考察了5,7-二羟基黄酮对BSA构象的影响. 相似文献
982.
The adiabatic Shinnar–Le Roux (SLR) algorithm for radiofrequency (RF) pulse design enables systematic control of pulse parameters such as bandwidth, RF energy distribution and duration. Some applications, such as diffusion-weighted imaging (DWI) at high magnetic fields, would benefit from RF pulses that can provide greater B1 insensitivity while adhering to echo time and specific absorption rate (SAR) limits. In this study, the adiabatic SLR algorithm was employed to generate 6-ms and 4-ms 180° semi-adiabatic RF pulses which were used to replace the refocusing pulses in a twice-refocused spin echo (TRSE) diffusion-weighted echo planar imaging (DW-EPI) sequence to create two versions of a twice-refocused adiabatic spin echo (TRASE) sequence. The two versions were designed for different trade-offs between adiabaticity and echo time. Since a pair of identical refocusing pulses is applied, the quadratic phase imposed by the first is unwound by the second, preserving the linear phase created by the excitation pulse. In vivo images of the human brain obtained at 7 Testa (7 T) demonstrate that both versions of the TRASE sequence developed in this study achieve more homogeneous signal in the diffusion-weighted images than the conventional TRSE sequence. Semi-adiabatic SLR pulses offer a more B1-insensitive solution for diffusion preparation at 7 T, while operating within SAR constraints. This method may be coupled with any EPI readout trajectory and parallel imaging scheme to provide more uniform coverage for diffusion tensor imaging at 7 T and 3 T. 相似文献
983.
984.
本文利用X射线粉末衍射和位敏探测技术,研究了R2Fe4/3W2/3O7(R=Er、Yb、Dy)化合物经高温高压处理后的变化情况。在3.7 GPa,1 200 ℃条件下,六方相R2Fe4/3W2/3O7化合物按两种方式分解,而直接由R2O3,Fe2O3和WO3原料出发,经上述同样的高温高压条件合成所得的产物与六方相高温高压分解产物相同,均为R2WO6、RFeO3、WO3和Fe2O3的多相聚合物。同时给出了R2Fe4/3W2/3O7六方相高温高压下的稳定区范围。 相似文献
985.
The crystallographic and the magnetic structures of the composite compound Nd2Co7 at 300 K are investigated by a combined refinement of X-ray diffraction data and high-resolution neutron diffraction data. The compound crystallizes into a hexagonal Ce2Ni7-type structure and consists of alternately stacking MgZn2-type NdCo2 and CaCu5-type NdCo5 structural blocks along the c axis. A magnetic structure model with the moments of all atoms aligning along the c axis provides a satisfactory fitting to the neutron diffraction data and coincides with the easy magnetization direction revealed by the X-ray diffraction experiments on magnetically pre-aligned fine particles. The refinement results show that the derived atomic moments of the Co atoms vary in a range of 0.7 μB-1.1 μB and the atomic moment of Nd in the NdCo5 slab is close to the theoretical moment of a free trivalent Nd3+ ion, whereas the atomic moment of Nd in the NdCo2 slab is much smaller than the theoretical value for a free Nd3+ ion. The remarkable difference in the atomic moment of Nd atoms between different structural slabs at room temperature is explained in terms of the magnetic characteristics of the NdCo2 and NdCo5 compounds and the local chemical environments of the Nd atoms in different structural slabs of the Nd2Co7 compound. 相似文献
986.
Zubair Ahmad Tianyu Ma Shan TaoMi Yan 《Journal of magnetism and magnetic materials》2012,324(8):1534-1538
The Fe63B23Nd7Y3Nb3Cr1 nanocomposite magnets in the form of sheets have been prepared by copper mold casting technique. The phase evolution, crystal structure, microstructural and magnetic properties have been investigated in the as-cast and annealed states. The as-cast sheets show magnetically soft behaviors which become magnetically hard by thermal annealing. The optimal annealed microstructure was composed of nanosize soft magnetic α-Fe (19-29 nm) and hard magnetic Nd2Fe14B (45-55 nm) grains. The best hard magnetic properties such as intrinsic coercivity, jHc of 1119 kA/m, remanence, Br of 0.44 T, magnetic induction to saturation magnetization ratio, Mr/Ms=0.61 and maximum energy product, (BH)max of 55 kJ/m3 was obtained after annealing at 680 °C for 15 min. The annealing treatment above 680 °C results in non-ideal phase grains growth, which degrade the magnetic properties. 相似文献
987.
Paul Kirren Lucile Barka Saher Rahmani Nicolas Bondon Nicolas Donzel Philippe Trens Aurlie Bessire Laurence Raehm Clarence Charnay Jean-Olivier Durand 《Molecules (Basel, Switzerland)》2022,27(13)
(1) Background: Due to human activities, greenhouse gas (GHG) concentrations in the atmosphere are constantly rising, causing the greenhouse effect. Among GHGs, carbon dioxide (CO2) is responsible for about two-thirds of the total energy imbalance which is the origin of the increase in the Earth’s temperature. (2) Methods: In this field, we describe the development of periodic mesoporous organosilica nanoparticles (PMO NPs) used to capture and store CO2 present in the atmosphere. Several types of PMO NP (bis(triethoxysilyl)ethane (BTEE) as matrix, co-condensed with trialkoxysilylated aminopyridine (py) and trialkoxysilylated bipyridine (Etbipy and iPrbipy)) were synthesized by means of the sol-gel procedure, then characterized with different techniques (DLS, TEM, FTIR, BET). A systematic evaluation of CO2 adsorption was carried out at 298 K and 273 K, at low pressure. (3) Results: The best values of CO2 adsorption were obtained with 6% bipyridine: 1.045 mmol·g−1 at 298 K and 2.26 mmol·g−1 at 273 K. (4) Conclusions: The synthetized BTEE/aminopyridine or bipyridine PMO NPs showed significant results and could be promising for carbon capture and storage (CCS) application. 相似文献
988.
研制的陶瓷材料可在超低温度(1 030 ℃±15 ℃)下烧结,获得瓷料的相对介电常数高于2 100,介质损耗不高于1.5%,温度特性满足X7R特性要求标准.与传统的X7R特性材料比较,本材料烧结温度更低,同时材料中不添加Pb、Hg、Cd、Cr等有害元素,符合绿色环保要求及欧盟RoHS指令要求. 相似文献
989.
Zainab S. Abbas Ghassan M. Sulaiman Majid S. Jabir Salman A. A. Mohammed Riaz A. Khan Hamdoon A. Mohammed Amal Al-Subaiyel 《Molecules (Basel, Switzerland)》2022,27(14)
The purpose of this study was to evaluate the potential of a newly modified cyclodextrin derivative, water-soluble β-cyclodextrin–epichlorohydrin (β-CD), as an effective drug carrier to enhance the poor solubility and bioavailability of galangin (GAL), a poorly water-soluble model drug. In this regard, inclusion complexes of GAL/β-CDP were prepared. UV-VIS spectrophotometry, Fourier-transform infrared spectroscopy (FTIR), X-ray crystallography (XRD), zeta potential analysis, particle size analysis, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) were applied to characterize the synthesized GAL/β-CD. Michigan Cancer Foundation-7 (MCF-7; human breast cancer cells) and rat embryo fibroblast (REF; normal cells) were employed to examine the in vitro cytotoxic effects of GAL/β-CD using various parameters. The dye-based tests of MTT and crystal violet clearly exhibited that GAL/β-CD-treated cells had a reduced proliferation rate, an influence that was not found in the normal cell line. The cells’ death was found to follow apoptotic mechanisms, as revealed by the dye-based test of acridine orange/ethidium bromide (AO/EtBr), with the involvement of the mitochondria via caspase-3-mediated events, as manifested by the Rh 123 test. We also included a mouse model to examine possible in vivo toxic effects of GAL/β-CD. It appears that the inclusion complex does not have a significant influence on normal cells, as indicated by serum levels of kidney and liver enzymatic markers, as well as thymic and splenic mass indices. A similar conclusion was reached on the histological level, as manifested by the absence of pathological alterations in the liver, kidney, thymus, spleen, heart, and lung. 相似文献
990.
采用柠檬酸凝胶-燃烧法合成了CaLa1-xAl3O7:xEu3+(0.05≤x≤0.8)材料的前驱粉末,在低于700℃退火处理时,得到非晶态样品,而高于800℃退火处理后为纯相的CaLa1-xAl3O7:xEu3+粉末样品.通过激发光谱和发射光谱研究了Eu3+在CaLaAl3O7基质中的发光性能及Eu3+掺杂量,退火温度和柠檬酸与金属离子的配比等对发光强度的影响.结果显示,非晶态和晶态CaLa1-xAl3O7:xEu3+样品均可发光,非晶态样品的最强激发峰出现在7F0-5D2的465 nm处,而晶相样品的最强激发峰为7F0-5L6跃迁的394nm.非晶态粉末在465 nm激发下发射光谱由5D0-7F0的578 nm和5D0-7F1的587 nm及5D0-7F2的615nm组成.而晶态粉末在394 nm激发下的发射光谱与非晶态相比5D0-7F0跃迁消失了,同时5D0-7F1跃迁发生谱线劈裂,出现在587和596 nm两处.随着退火温度的升高,主峰615 nm强度增强了,但5D0-7F1跃迁峰的增强更加明显. 相似文献