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排序方式: 共有3516条查询结果,搜索用时 31 毫秒
211.
Taejoon Kang Ilsun Yoon Dr. Jangbae Kim Hyotcherl Ihee Prof. Bongsoo Kim Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(4):1351-1355
We report a new type of molecular sensor using a Au nanowire (NW)–Au nanoparticles (NPs) conjugated system. The Au NW–NPs structure is fabricated by the self‐assembly of biotinylated Au NPs on a biotinylated Au NW through avidin; this creates hot spots between NW and NPs that strongly enhance the Raman signal. The number of the Au NPs attached to the NW is reproducibly proportional to the concentration of the avidin, and is also proportional to the measured surface‐enhanced Raman scattering (SERS) signals. Since this well‐defined NW–NPs conjugated sensor is only a few micrometer long, we expect that development of multiplex nanobiosensor of a few tens micrometer size would become feasible by combining individually modified multiple Au NWs together on one substrate. 相似文献
212.
213.
Mohammed Es‐Souni Martha Es‐Souni Salah Habouti Nicole Pfeiffer Abdelilah Lahmar Matthias Dietze Claus‐Henning Solterbeck 《Advanced functional materials》2010,20(3):377-385
TiO2? Ag‐nanocomposites exhibit various desirable properties that make them suitable for a variety of applications, for example in photocatalysis and as bactericidal coatings. In this work, a new method for processing TiO2? Ag nanocomposites is presented. The nanocomposite films are fabricated from one precursor solution with high silver loading of up to 50%. The resulting films exhibit a microstructure consisting of TiO2? AgxO nanocomposites with a largely XRD‐amorphous TiO2 matrix containing brookite nanocrystals. This specific microstructure absorbs in the visible range so that photoreduction of Ag ions can be accomplished by using visible light. The thin films can be patterned using simple shadow masks. The illuminated areas show a high density of self‐organized nanoparticles (SNPs) and nanorods (SNRs), which are templated by the TiO2 porous network. The particle size can be tuned by varying the irradiation time. Most of the SNPs and SNRs form faceted crystals, which are mostly a combination of {111} and {110}. The application of these films as substrates for surface‐enhanced Raman scattering is shown. Enhancement factors as high as 4.6 × 106 could be obtained using rhodamine 6G dye molecules. More applications should involve photocatalytic water purification using visible light. 相似文献
214.
Katharina K. Strelau Thomas Schüler Dr. Robert Möller Dr. Wolfgang Fritzsche Dr. habil. Jürgen Popp Prof. Dr. 《Chemphyschem》2010,11(2):394-398
Surface‐enhanced Raman spectroscopy (SERS) is an emerging technology in the field of analytics. Due to the high sensitivity in connection with specific Raman molecular fingerprint information SERS can be used in a variety of analytical, bioanalytical, and biosensing applications. However, for the SERS effect substrates with metal nanostructures are needed. The broad application of this technology is greatly hampered by the lack of reliable and reproducible substrates. Usually the activity of a given substrate has to be determined by time‐consuming experiments such as calibration or ultramicroscopic studies. To use SERS as a standard analytical tool, cheap and reproducible substrates are required, preferably with a characterization technique that does not interfere with the subsequent measurements. Herein we introduce an innovative approach to produce low‐cost and large‐scale reproducible substrates for SERS applications, which allows easy and economical production of micropatterned SERS active surfaces on a large scale. This approach is based on an enzyme‐induced growth of silver nanostructures. The special structural feature of the enzymatically deposited silver nanoparticles prevents the breakdown of SERS activity even at high particle densities (particle density >60 %) that lead to a conductive layer. In contrast to other approaches, this substrate exhibits a relationship between electrical conductivity and the resulting SERS activity of a given spot. This enables the prediction of the SERS activity of the nanostructure ensemble and therewith the controllable and reproducible production of SERS substrates of enzymatic silver nanoparticles on a large scale, utilizing a simple measurement of the electrical conductivity. Furthermore, through a correlation between the conductivity and the SERS activity of the substrates it is possible to quantify SERS measurements with these substrates. 相似文献
215.
Jingbin Zeng Jinmei Chen Xinhong Song Yiru Wang Jaeho Ha Xi Chen Xiaoru Wang 《Journal of chromatography. A》2010,1217(11):1735-1741
In this paper, we proposed an approach using a multi-walled carbon nanotubes (MWCNTs)/Nafion composite coating as a working electrode for the electrochemically enhanced solid-phase microextraction (EE-SPME) of charged compounds. Suitable negative and positive potentials were applied to enhance the extraction of cationic (protonated amines) and anionic compounds (deprotonated carboxylic acids) in aqueous solutions, respectively. Compared to the direct SPME mode (DI-SPME) (without applying potential), the EE-SPME presented more effective and selective extraction of charged analytes primarily via electrophoresis and complementary charge interaction. The experimental parameters relating to extraction efficiency of the EE-SPME such as applied potentials, extraction time, ionic strength, sample pH were studied and optimized. The linear dynamic range of developed EE-SPME-GC for the selected amines spanned three orders of magnitude (0.005–1 μg mL−1) with R2 larger than 0.9933, and the limits of detection were in the range of 0.048–0.070 ng mL−1. All of these characteristics demonstrate that the proposed MWCNTs/Nafion EE-SPME is an efficient, flexible and versatile sampling and extraction tool which is ideally suited for use with chromatographic methods. 相似文献
216.
为了解决MEMS封装过程中易对微致动件造成损伤的问题,提出了一种低成本、与CMOS工艺兼容的晶圆级薄膜封装技术,用等离子体增强化学气相淀积(PECVD)法制备的低应力SiC作为封装和密封材料。此材料的杨氏模量为460 GPa,残余应力为65 MPa,可使MEMS器件悬浮时封装部位不变形。与GaAs,Si半导体材料相比,SiC具有较佳的物理稳定性,较高的杨氏模量等性能优势。将PECVD薄膜封装技术用于表面微结构和绝缘膜上Si(SOI)微结构部件(如射频开关、微加速度计等)封装中,不仅减小了封装尺寸,降低了芯片厚度,简化了封装工艺,而且封装芯片还与CMOS工艺兼容。较之晶圆键合封装方式,此晶圆级薄膜封装成本可降低5%左右。 相似文献
217.
相干光时域反射仪中受激布里渊散射的抑制 总被引:1,自引:1,他引:0
采用对分布反馈半导体激光器(DFB-LD)直接进行小信号电流调制的方法抑制相干光时域反射仪(COT-DR)中的受激布里渊散射(SBS),分析了DFB-LD受到小信号电流调制时的频谱特性以及SBS阈值和频谱宽度的关系,设计了实验电路和光路抑制光纤中SBS。理论分析和实验结果表明,在低频调制电流处,光源频谱宽度随调制频率增加而减小,随调制幅度增加而增加,而SBS随频谱宽度增加而减弱,直接用电流调制激光器可抑制COTDR中的SBS。 相似文献
218.
Luc THVENAZ 《中国光电子学前沿》2010,3(1)
Optical fiber sensors based on stimulated Brillouin scattering have now clearly demonstrated their excellent capability for long-range distributed strain and temperature measurements. The fiber is used as sensing element, and a value for temperature and/or strain can be obtained from any point along the fiber. After explaining the principle and presenting the standard implementation, the latest developments in this class of sensors will be introduced, such as the possibility to measure with a spatial resolution of 10 cm and below while preserving the full accuracy on the determination of temperature and strain. 相似文献
219.
LTE对BOSS系统影响的研究 总被引:1,自引:0,他引:1
LTE网络演进过程中,其独特的网络架构和业务特性,以及网络切换等方面,都会给BOSS系统带来影响。另外,包括2G、TD-SCDMA、WLAN和TD-LTE在内的不同网络,其各自具备不同的覆盖能力和业务场景,不但会长期共存,还会适时进行融合。四网融合可为用户提供更优质的网络接入服务,同时也为BOSS系统带来了挑战。 相似文献
220.