全文获取类型
收费全文 | 69895篇 |
免费 | 5641篇 |
国内免费 | 8836篇 |
专业分类
化学 | 41456篇 |
晶体学 | 2920篇 |
力学 | 2785篇 |
综合类 | 434篇 |
数学 | 14419篇 |
物理学 | 13994篇 |
无线电 | 8364篇 |
出版年
2024年 | 145篇 |
2023年 | 618篇 |
2022年 | 1199篇 |
2021年 | 1304篇 |
2020年 | 1616篇 |
2019年 | 1722篇 |
2018年 | 1564篇 |
2017年 | 1762篇 |
2016年 | 2255篇 |
2015年 | 2270篇 |
2014年 | 3085篇 |
2013年 | 4573篇 |
2012年 | 4598篇 |
2011年 | 4369篇 |
2010年 | 3935篇 |
2009年 | 4622篇 |
2008年 | 4790篇 |
2007年 | 4890篇 |
2006年 | 4342篇 |
2005年 | 3729篇 |
2004年 | 3612篇 |
2003年 | 3072篇 |
2002年 | 3136篇 |
2001年 | 2032篇 |
2000年 | 1991篇 |
1999年 | 1642篇 |
1998年 | 1456篇 |
1997年 | 1193篇 |
1996年 | 1289篇 |
1995年 | 1104篇 |
1994年 | 1065篇 |
1993年 | 832篇 |
1992年 | 783篇 |
1991年 | 480篇 |
1990年 | 387篇 |
1989年 | 323篇 |
1988年 | 281篇 |
1987年 | 226篇 |
1986年 | 218篇 |
1985年 | 297篇 |
1984年 | 200篇 |
1983年 | 157篇 |
1982年 | 170篇 |
1981年 | 178篇 |
1980年 | 137篇 |
1979年 | 104篇 |
1978年 | 106篇 |
1977年 | 125篇 |
1976年 | 97篇 |
1974年 | 79篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
61.
Z. X. Li L. Q. Lin W. M. Zhang T. Wu J. L. Pu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1291-1298
A series of new polyimides were prepared via the polycondensation of (3‐amino‐2,4,6‐trimethylphenyl)‐(3′‐aminophenyl)methanone and aromatic dianhydrides, that is, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride, and 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride. The structures of the polyimides were characterized by Fourier transform infrared and NMR measurements. The properties were evaluated by solubility tests, ultraviolet–visible analysis, differential scanning calorimetry, and thermogravimetric analysis. The two different meta‐position‐located amino groups with respect to the carbonyl bridge in the diamine monomer provided it with an unsymmetrical structure. This led to a restriction on the close packing of the resulting polymer chains and reduced interchain interactions, which contributed to the solubility increase. All the polyimides except that derived from BPDA had good solubility in strong aprotic solvents, such as N‐methyl‐2‐pyrrolidinone, N,N′‐dimethylacetamide, N,N‐dimethylformamide, and dimethyl sulfone, and in common organic solvents, such as cyclohexanone and chloroform. In addition, these polyimides exhibited high glass‐transition values and excellent thermal properties, with an initial thermal decomposition temperature above 470 °C and glass‐transition temperatures in the range of 280–320 °C. The polyimide films also exhibited good transparency in the visible‐light region, with transmittance higher than 80% at 450 nm and a cutoff wavelength lower than 370 nm. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1291–1298, 2006 相似文献
62.
Huseyin Zengin Gulay Zengin Dennis W. Smith 《Journal of polymer science. Part A, Polymer chemistry》2006,44(24):6988-6996
This study focuses on the preparation, characterization, and optical properties of new bis(3,4‐diphenylethynylphenyl)phenylamine. This is the first nitrogen‐containing bis‐ortho‐diynylarene (BODA) monomer having a nitrogen atom as the spacer group. BODA monomers are usually prepared from common bisphenols, thereby providing great synthetic versatility and the opportunity to develop a wide array of novel polyarylene thermosets by varying the aromatic spacer group. The new bis(3,4‐bisphenylethynylphenyl)phenylamine was synthesized in five steps. This compound emits an intense blue color (λ = 438 nm) upon irradiation by UV light and may be suitable for use as an emitting layer in electroluminescent devices. Bis‐(3,4‐bisphenylethynylphenyl)phenylamine and its polymer have photoluminescence quantum yields 34 and 38%, respectively, and long excited‐state lifetimes of 3.2 and 3.6 ns, respectively. The structure of the monomer and its polymer were characterized using spectroscopic techniques including Ultraviolet–visible Spectrophotometer, Photoluminescence Spectrophotometer, Fourier Transform infrared spectroscopy, and Gel Permeation Chromatography. The polymerizations were studied by Differential Scanning Calorimeter. The amount of weight loss and the thermostability of the nitrogen‐containing polymer were determined from thermogravimetric analysis. The electrical conductivity of neat HCl‐doped BODA‐derived polymer film was measured according to the standard four‐point probe technique. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6988–6996, 2006 相似文献
63.
Takahiro Gunji Ryosuke Shimano Koji Arimitsu Yoshimoto Abe 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2542-2550
Tetraethoxysilane (TEOS) and polyethoxysiloxanes (PEOSs; prepared by the acid‐catalyzed hydrolytic polycondensation of TEOS) were subjected to the sol–gel process in the presence of cetyltrimethylammonium bromide (CTAB), respectively. The PEOSs with Mw 700–26,000, as prepared by sol–gel coating of TEOS and PEOS under various conditions, were used. Uniform and crack‐free thin films of thickness 276–613 nm were prepared by spin‐coating of a PEOS solution containing CTAB. When the coating films were sintered at 400 °C, the combustion of ethoxy groups and CTAB took place to provide porous silica thin films. The structure of the thin films was found to be dependent on the molecular weight of PEOS and the molar ratio of CTAB/Si: lamellar or hexagonal phase was observed for Mw less than 15,000 and for CTAB/Si molar ratios greater than 0.10. Honeycomb structures were observed for Mw less than 5000 and for CTAB/Si molar ratios of 0.15. The honeycomb structure was also observed by atomic force microscopy and transmission electron microscope. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2542–2550, 2006 相似文献
64.
Toshiyuki Oyama Akira Kitamura Eiichi Sato Masao Tomoi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2694-2706
The factors affecting pattern‐forming properties in reaction development patterning were examined with polyarylates with various bisphenol moieties. The developability of the photosensitive polyarylates was dependent on the properties of the subtituent (R) in the bisphenol moieties. The development time decreased in the following order: R?C(CH3)2 > fluorenyl unit ? phenolphthalein unit > C(CF3)2 > SO2. This order agreed with that of the reactivity between the polyarylates and ethanolamine, and these orders can be explained by pKa of the bisphenol used to prepare the polyarylates. The development with NH2? R′? OH resulted in successful positive‐tone pattern formation. However, pattern formation with the developers containing NH2? R′? OCH3 was unsuccessful. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2694–2706, 2006 相似文献
65.
Yunchun Zhou Jianxin Geng Gao Li Enle Zhou Liang Chen Wanjin Zhang 《Journal of Polymer Science.Polymer Physics》2006,44(4):764-769
A series of crystals of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 Å, b = 8.82 Å, c = 23.20 Å, and β = 95.03°, as determined using electron diffraction tilting method combined with wide‐angle X‐ray diffraction experiment. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 764–769, 2006 相似文献
66.
Some bounds on the entries and on the norm of the inverse of triangular matrices with nonnegative and monotone entries are found. All the results are obtained by exploiting the properties of the fundamental matrix of the recurrence relation which generates the sequence of the entries of the inverse matrix. One of the results generalizes a theorem contained in a recent article of one of the authors about Toeplitz matrices. 相似文献
67.
An element σ of An, the Alternating group of degree n, is extendible in Sn, the Symmetric group of degree n, if there exists a subgroup H of Sn but not An whose intersection with An is the cyclic group generated by σ. A simple number-theoretic criterion, in terms of the cycle-decomposition, for an element of An to be extendible in Sn is given here. 相似文献
68.
69.
William A. Lampe 《Periodica Mathematica Hungarica》1996,32(1-2):65-75
We survey results concerning the representations of lattices as lattices of congruences and as lattices of equational theories. Recent results and open problems will be mentioned.To László Fuchs on the occasion of his 70th birthday 相似文献
70.
With a view to applications to self-regulating dynamical processes in biology, we determine the geometric structure of what we call isotangent curves, i.e. curves parametrized by the slopes of their points. They come up naturally as bifurcation curves of rational unfoldings of X
k, and we classify them according to degree and number of cusps. They, as well as their isotangent involute curves, turn up in simulations of these processes. 相似文献