Fourier transform IR spectrum and photoreactivity of the C3O2:HCl complex isolated in solid argon

IR spectroscopy was coupled with the matrix isolation technique to study the molecular complex formed between C₃O₂ and HCl and its photodissociation. The vibrational frequencies of the complex were compared with those of HCl and C₃O₂ monomers. For C₃O₂, a bent structure was characterized in the solid environment.

The vibrational frequencies were calculated in the 4000–400 cm⁻¹ range using an ab initio method at the MP2/6-31G** level for the most stable complex; these frequencies describe the hydrogen interaction with the central carbon atom of C₃O₂ (T complex). The measured shifts between the vibrational mode frequencies of the complex and monomers were in good agreement with the calculated values.

Broad-band UV irradiation ( > 230 nm) of the T complex leads preferentially to ketene chloride and carbon monoxide. Ketene chloride formation can be explained by the reaction between HCl and the carbene C₂O, which results from photo-dissociation at the C=CO bond of C₃O₂.     

On pre-exit joint occupation times for spectrally negative Lévy processes

We adopt a new approach to find Laplace transforms of joint occupation times over disjoint intervals for spectrally negative Lévy processes. The Laplace transforms are expressed in terms of scale functions.     

ON SOLVABILITY AND WAVEFORM RELAXATION METHODS FOR LINEAR VARIABLE-COEFFICIENT DIFFERENTIAL-ALGEBRAIC EQUATIONS

This paper is concerned with the solvability and waveform relaxation methods of linear variable-coefficient differential-algebraic equations （DAEs）. Most of the previous works have been focused on linear variable-coefficient DAEs with smooth coefficients and data, yet no results related to the convergence rate of the corresponding waveform relaxation methods has been obtained. In this paper, we develope the solvability theory for the linear variable-coefficient DAEs on Legesgue square-integrable function space in both traditional and least squares senses, and determine the convergence rate of the waveform relaxation methods for solving linear variable-coefficient DAEs.     

Weinstein–Sobolev Spaces of Exponential Type and Applications

In this paper, we introduce and study the Sobolev spaces of exponential type associated with the Weinstein operator, via some elements of harmonic analysis related to this operator. In particular, some properties, including completeness and imbedding theorem, are proved. Finally, using the theory of reproducing kernels, some applications are given for these spaces.     

A Graphical Goodness-of-Fit Test for Dependence Models in Higher Dimensions

This article introduces a graphical goodness-of-fit test for copulas in more than two dimensions. The test is based on pairs of variables and can thus be interpreted as a first-order approximation of the underlying dependence structure. The idea is to first transform pairs of data columns with the Rosenblatt transform to bivariate standard uniform distributions under the null hypothesis. This hypothesis can be graphically tested with a matrix of bivariate scatterplots, Q-Q plots, or other transformations. Furthermore, additional information can be encoded as background color, such as measures of association or (approximate) p-values of tests of independence. The proposed goodness-of-fit test is designed as a basic graphical tool for detecting deviations from a postulated, possibly high-dimensional, dependence model. Various examples are given and the methodology is applied to a financial dataset. An implementation is provided by the R package copula. Supplementary material for this article is available online, which provides the R package copula and reproduces all the graphical results of this article.     

Some Penrose transforms in complex differential geometry

In this article, we review a construction in the complex geometry often known as the Penrose transform. We then present two new applications of this transform. One concerns the construction of symmetries of the massless field equations from mathematical physics. The other concerns obstructions to the embedding of CR structures on the three-sphere. Dedicated to Professor Sheng GONG on the occasion of his 75th birthday