Fourier transform IR spectrum and photoreactivity of the C3O2:HCl complex isolated in solid argon

IR spectroscopy was coupled with the matrix isolation technique to study the molecular complex formed between C₃O₂ and HCl and its photodissociation. The vibrational frequencies of the complex were compared with those of HCl and C₃O₂ monomers. For C₃O₂, a bent structure was characterized in the solid environment.

The vibrational frequencies were calculated in the 4000–400 cm⁻¹ range using an ab initio method at the MP2/6-31G** level for the most stable complex; these frequencies describe the hydrogen interaction with the central carbon atom of C₃O₂ (T complex). The measured shifts between the vibrational mode frequencies of the complex and monomers were in good agreement with the calculated values.

Broad-band UV irradiation ( > 230 nm) of the T complex leads preferentially to ketene chloride and carbon monoxide. Ketene chloride formation can be explained by the reaction between HCl and the carbene C₂O, which results from photo-dissociation at the C=CO bond of C₃O₂.     

The transient blended queue

This study aims to determine the transient behavior of the blended queue. Priority customers arrive over time and benefit from a threshold reservation policy, while non-priority ones can be contacted at any time. We show how to compute the Laplace transforms of the transient probabilities. Using the uniformization technique, we prove some monotonicty properties of the expected number of customers in the queue, explaining why the optimal transient reservation threshold should be lower than the stationary one.     

N叉树上的离散时间量子随机行走

通过离散时间量子随机行走的框架,我们研究了在N叉树上的离散时间量子随机行走,该框架不需要硬币空间,仅仅只需要选择一个除了酉性再无其它限制的演化算子,并且包含了使用再生结构的轨道枚举和z变换.作为结果,我们在封闭形式中计算了在根处的振幅的生成函数.     

Superexponential stability of KAM tori

We study the dynamics in the neighborhood of an invariant torus of a nearly integrable system. We provide an upper bound to the diffusion speed, which turns out to be of superexponentially small size exp[-exp(1/)], being the distance from the invariant torus. We also discuss the connection of this result with the existence of many invariant tori close to the considered one.     

Cramér theorem on symmetric spaces of noncompact type

We prove the Cramér theorem forK-invariant Gaussian measures on irreducible symmetric spacesX=G/K withG semisimple noncompact. To do this we use a kind of Abel transform ofK-invariant measures onX.This research is supported by KBN Grant.     

Characterization of measures by potentials

Let μ be a measure in a Banach spaceE, f be an even function onR. We consider the potentialg(a)=f _E f(‖x?a‖)dμ(x). The question is as follows: For whichf does the potentialg determine μ uniquely? In this article we give answers in the cases whereE=l _∞ ⁿ and wheref(t)=|t| ^p andE is a finite dimensional Banach space with symmetric analytic norm. Calculating the Fourier transform of the functionf(‖x‖ _∞) we give a new proof of the J. Misiewicz's result that the functionf(‖x‖ _∞) is positive definite only iff is a constant function.     

一种利用小波降噪的卫星导航信号并行捕获算法

针对全球定位系统（Global Positioning System,GPS）接收机传统捕获算法计算复杂度高、捕获灵敏度低等缺点,提出了一种可降噪的简化并行码相位捕获（Noise Reduction for Simplified Parallel Code Phase Acquisition,NR-SPCA）算法。该算法通过对信号降采样,利用小波变换对二次采样信号作降噪处理,提高了捕获灵敏度;利用GPS信号和C/A码互相关的稀疏性,并行计算降噪后的信号的相关值,提高了运算效率。仿真结果表明,在90%概率捕获成功的前提下,NR-SPCA算法比传统的PCA算法信噪比低1 dB,运算效率提升了100%。该算法还可应用于航天探测、自动驾驶等领域。     

基于余弦-指数混沌映射的分块图像加密算法

为平衡混沌映射中结构与性能的关系,保证加密系统安全性,提出一种基于余弦-指数混沌映射的分块图像加密算法。首先,通过非线性指数项对引入了Tent种子映射的余弦映射进行调制,构造新型余弦-指数混沌映射,并利用SHA-256函数产生与明文相关的密钥,生成随机性较强的混沌序列,实现一次一密;然后,基于拉丁方和位级转换,通过两轮拉丁方索引和比特位拼接,分别设计双重拉丁方和扩展比特位算法,并结合二维约瑟夫序列,对块间预置乱后的明文进行块内置乱,实现不同分块的差异化置乱;最后,基于Zig-Zag变换,采用环状仿Zig-Zag变换设计交叉Zig-Zag变换方法,将中间密文与混沌序列进行双向非线性扩散,实现同时改变像素位置与大小,完成图像加密。实验结果表明,该算法密钥空间大,能有效抵御差分分析和统计分析等典型攻击,具有较好的加密效果。     

一种基于Arnold置乱和DCT编码的无载体信息隐藏方法北大核心CSCD

近年来十分火热的搜索映射式无载体信息隐藏虽具有一定的鲁棒性,但其隐藏容量较低、传输负载大且算法复杂度高。针对以上问题,该文章提出一种基于Arnold置乱和离散余弦变换(discrete cosine transform,DCT)编码的无载体信息隐藏方法。该算法先对图片进行Arnold置乱,再对DCT后的低频系数进行编码,接着更换置乱参数来构建索引表。选择索引表中与秘密信息相同的编码值所对应的参数构建候选队列,最后筛选出鲁棒性强的参数作为密钥发送给接收方。实验结果表明,该方法与现有方法相比大大提高了嵌入容量,拥有更强的抗JPEG压缩性能。并且减少了传输负载,算法简捷,具有较强的应用价值。     

正交多载波降噪差分混沌键控通信系统

为解决多载波差分混沌移位键控(MC-DCSK)系统传输速率低和误码性能差的缺点,该文提出一种正交多载波降噪差分混沌移位键控(QMC-NR-DCSK)系统。在发送端,预定义载波用于发送参考信号,剩余M-1个不同中心频率的载波及其经正交调制技术后得到的频率相同但相位正交的载波都用于传输信息信号,此外,通过进一步引入Hilbert变换,将系统的频带利用率和传输速率提升为MC-DCSK系统的4倍。在接收端引入滑动平均滤波器的降噪操作降低了噪声的方差,从而改善了系统误码性能。推导了QMC-NR-DCSK系统在加性高斯白噪声(AWGN)信道和多径瑞利衰落(RFC)信道下的比特误码率公式并进行了仿真。仿真结果和理论分析表明：QMC-NR-DCSK系统能有效提升传输速率、带宽效率和误码性能,为该系统应用于多载波无线通信提供理论参考。