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The unsaturable trap model, which attributes the increase of the electrical resistivity of fcc metals during electron irradiation in the temperature regime of Stage-II recovery to the trapping of Stage-IE interstitials at impurity atoms, is shown to be in serious disagreement with the experiments, contrary to opposite statements in the literature. As shown recently, the predictions of the unsaturable trap model are independent of the dimensionality of the diffusion of the Stage-IE interstitials. Previous attempts to rule out a one-dimensional migration of the Stage-IE interstitials (and hence the two-interstitial model) on the basis of the alleged agreement of the unsaturable trap model with Stage-II damage curves are thus meaningless. On the contrary, it is demonstrated that the two-interstitial model accounts for minute details of the measured Stage-II damage curves in a natural way. 相似文献
74.
A polymer crystal with a noncrystalline surface layer formed by chain loops of different lengths is considered. It is assumed that the length of each loop can be changed by longitudinal diffusion of the molecule through the crystal lattice. From the condition that the free energy of the system is minimum, the loop length distribution and the average loop length as function of temperature are calculated. In contrast to the results for loops of equal length, for the present model, a substantial thickness of the noncrystalline surface layer and a broad melting range is obtained also for the case of adjacent reentry. In order to get this result one has to take into account that even an “ideal fold” consists of at least four rigidly arranged CH2 groups in energetically unfavored conformation. 相似文献
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76.
This paper introduces a new algorithm for Boolean operations on rasterized geometric shapes that are represented with chain codes. The algorithm works in three steps. Firstly, the chain code symbols are transformed in the Hilbert space, where the overlaid chain code symbols are recognised. After that, a suitable starting cell is determined. Finally, the walk-about through the sequence of the initial chain code symbols is performed to obtain the sequence of chain code symbols representing the shape of the required Boolean operation. The algorithm is demonstrated on Freeman chain code in four directions. The time and space complexity of the proposed algorithm is linear, which was proven theoretically and confirmed by experiments. 相似文献
77.
Mohammad Khorrami Ahmad Shariati Amir Aghamohammadi Amir H. Fatollahi 《Physics letters. A》2012,376(5):687-691
It is shown that as far as the linear diffusion equation meets both time- and space-translational invariance, the time dependence of a moment of degree α is a polynomial of degree at most equal to α, while all connected moments are at most linear functions of time. As a special case, the variance is an at most linear function of time. 相似文献
78.
Mathematical deconvolution methods can separate co-eluting peaks in samples for which (chromatographic) separation fail. However, these methods often heavily rely on manual user-input and interpretation. This is not only time-consuming but also error-prone and automation is needed if such methods are to be applied in a routine manner. 相似文献
79.
采用高精度的量子化学从头计算多参考组态相互作用方法和相关一致基, 计算了LiBr分子基态的光谱常数和势能曲线. 为获得更准确的结果, 计算中还考虑了二阶Douglas-Kroll-Hess相对论修正对LiBr分子基态的平衡键长、谐振频率和离解能影响. 将计算得到的势能曲线拟合为Murrell-Sorbie解析势能函数形式, 并进一步计算得到LiBr分子基态的其它光谱常数,ωeχe, αe, Be, D0. 比较发现它们与实验值符合的非常好. 通过求解核运动径向Schrodinger方程, 找到了LiBr分子基态的全部振动态. 还计算了每一个振动态的振动能级、经典转折点和惯性转动常数, 这些结果与已有的实验值一致. 相似文献
80.
The present paper deals with the effect of europium (Eu3+) doping concentration (0.1–2.5 mol%) on photoluminescence (PL) and thermoluminescence (TL) of strontium yttrium oxide (SrY2O4) phosphor. The sample was prepared by the modified solid state reaction method, which is the most suitable method for large-scale production. The prepared phosphor sample was characterized by using X-ray Diffraction (XRD), field emission gun scanning electron microscopy, fourier transform infrared spectroscopy, high resolution transmission electron microscopy, photoluminescence, thermoluminescence and commission internationale de I׳Eclairage techniques. The PL emission was observed in the range of 410–630 nm for the SrY2O4 phosphor doped with Eu3+. Excitation spectrum was found at 254 and 325 nm, sharp peaks were found around 593, 615 and 625 nm with high intensity. From the XRD data, using Scherrer׳s formula, calculated average crystallite size of Eu3+ doped SrY2O4 phosphor is around 32 nm. Thermoluminescence study was carried out for the phosphor with UV and gamma irradiation. The TL response of SrY2O4:Eu3+ phosphor for two different radiations was compared and studied in detail. The present phosphor can act as a single host for white light emission in display devices. The detailed process and possible mechanisms for PL and TL are studied and discussed. For the variable concentration of Eu3+ on PL studies the PL intensity increases with increasing the concentration of dopant and the concentration quenching found after 2 mol% of Eu3+ the optimized concentration was 2 mol%, which is suitable for the display device application. In TL glow curve the optimized concentration was 1 mol% for the UV irradiated sample and 0.2 mol% of Eu3+ for the gamma irradiated sample and beta irradiated sample for 10 Gy dose. The kinetic parameters were calculated by the computerized glow curve deconvolution (CGCD) technique. 相似文献