Modeling of cascaded high isolation bidirectional amplification in long-distance fiber-optic time and frequency synchronization system

We propose a physical model of estimating noise and asymmetry brought by high isolation Bi-directional erbiumdoped fiber amplifiers(Bi-EDFAs), no spontaneous lasing even with high gain, in longdistance fiber-optic time and frequency(T/F) synchronization system. It is found that the Rayleigh scattering noise can be suppressed due to the high isolation design, but the amplified spontaneous emission(ASE) noise generated by the high isolation Bi-EDFA and the bidirectional asymmetry of the transmission link caused by the high isolation Bi-EDFA will deteriorate the stability of the system.The calculated results show that under the influence of ASE noise, the frequency instability of a 1200 km system composed of 15 high isolation Bi-EDFAs is 1.773 × 10-13/1 s. And the instability caused by asymmetry is 2.6064 × 10-16/30000–35000 s if the total asymmetric length of the bidirectional link length is 30 m. The intensity noises originating from the laser and detector, the transfer delay fluctuations caused by the variation in ambient temperature and the jitter in laser output wavelength are also studied. The experiment composed of three high isolation Bi-EDFAs is done to confirm the theoretical analysis. In summary, the paper shows that the short-term instability of the T/F synchronization system composed of high isolation Bi-EDFAs is limited by the accumulation of ASE noise of amplifiers and the laser frequency drift, while the long-term instability is limited by the periodic variation in ambient temperature and the asymmetry of the amplifiers.The research results are useful for pointing out the direction to improve the stability of the fiber-optic T/F synchronization system.     

Multivariate optimization and comparison between conventional extraction (CE) and ultrasonic-assisted extraction (UAE) of carotenoid extraction from cashew apple

Carotenoids are an essential component of cashew and can be used in pharmaceuticals, cosmetics, natural pigment, food additives, among other applications. The present work focuses on optimizing and comparing conventional and ultrasound-assisted extraction methods. Every optimization step took place with a 1:1 (w:w) mixture of yellow and red cashew apples lyophilized and ground in a cryogenic mill. A Simplex-centroid design was applied for both methods, and the solvents acetone, methanol, ethanol, and petroleum ether were evaluated. After choosing the extractor solvent, a central composite design was applied to optimize the sample mass (59–201 mg) and extraction time (6–34 min). The optimum conditions for the extractor solvent were 38% acetone, 30% ethanol, and 32% petroleum ether for CE and a mixture of 44% acetone and 56% methanol for UAE. The best experimental conditions for UAE were a sonication time of 19 min and a sample mass of 153 mg, while the CE was 23 min and 136 mg. Comparing red and yellow cashews, red cashews showed a higher carotenoid content in both methodologies. The UAE methodology was ca. 21% faster, presented a more straightforward composition of extracting solution, showed an average yield of superior carotenoid content in all samples compared to CE. Therefore, UAE has demonstrated a simple, efficient, fast, low-cost adjustment methodology and a reliable alternative for other applications involving these bioactive compounds in the studied or similar matrix.     

正态线性模型中误差方差的二次型估计的容许性

设Ｙ遵从Ｎ（Ｘβ，σ２Ｉｎ），秩（Ｘ）＜ｎ，在平方损失下，本交给出σ２的二次型估计在整个估计类中可容许的充要条件．     

基于小波的汇率波动序列长记忆性研究

提出了基于小波方差的时间序列长记忆性分析方法，用该方法对汇率波动序列进行了分析，得到了长记忆参数的精确值。引入了关联尺度函数，对各汇率波动序列长记忆效应的大小程度进行了验证。结果表明各汇率波动序列存在长记忆效应，并且长记忆参数d值越大，汇率波动序列所受历史信息的影响就越强。     

Misclassification rates,critical values and size of the design in measurement systems capability studies

Measurement systems capability analysis aims to test if the variability of a measurement system is small relative to the variability of a monitored process. At present some open questions are related both to the interpretation of the critical values of the indices typically used by practitioners to assess the capability of a gauge and to the choice of the size of the experimental design to test the repeatability and the reproducibility of the measurement process. In this paper, starting from the misclassification rates of a measurement system, we present a solution to these issues. Copyright © 2009 John Wiley & Sons, Ltd.     

三能级J－C模型中压缩的进一步研究

本文从共振情形下三能级Ｊａｙｎｅｓ－Ｃｕｍｍｉｎｇ。模型的薛定谔方程的一般解出发，讨论了三种典型初始条件下产生压缩态的可能性，用最徒下降法研究了初始相干态强度很大时的情形，并将结果与二能级Ｊａｍｅｓ－Ｃｕｍｍｉｎｇｓ模型作了比较。     

ESR spectroscopy as a tool for identifying joining fragments of antique marbles: the example of a pulpit by Donatello and Michelozzo

ESR spectroscopy is one of the physicochemical techniques used to characterize archaeological white marbles and obtain information about their quarries of provenance. This is done by measuring selected spectral features of the Mn(2+) impurity ubiquitously present in marbles and developing a statistical classification rule from the variable vectors measured for a significant number of samples of known provenance (the quarry database). Now we show that the overall variability exhibited by the same spectroscopic features decreases rapidly with the linear dimensions of the sampled block and can be used to distinguish fragments belonging to the same piece of stone from those simply originating from the same quarry. Application of the method to the seven marble panels of the Donatello pulpit in Prato (Tuscany) shows that they have all been cut from the same single block and their different degradation must be ascribed to differential weathering and to the different conservation treatments undergone in the past. The limits and possible drawbacks of the method are also discussed.     

Upper- and lower-bound Hylleraas–CI calculations for the nonrelativistic Po states of the 4He isotope

Extensive Hylleraas–CI calculations for the lowest P^o states of ⁴He were performed. The dependence of the variational energy values E_κ on the mass parameter κ given by κ=m/m is discussed. Furthermore, lower bounds to E_κ were calculated using variance minimization. © 1998 John Wiley & Sons, Inc. Int J Quant Chem 66 : 25–30, 1998     

变分量子Monte Carlo的一个新算法

提出变分量子MonteCarlo(VMC)计算的新算法-极小化方差(MV)方法.它从局域能的内部结构出发,直接削减其波动以达到将VMC的方差减到极小的目的.给出了局域能的分析表达式,导出VMC的极小方差原理,并建立方差极小化的计算步骤.     

Limit of detection estimator for second-order bilinear calibration

A new approach is developed for estimating the limit of detection in second-order bilinear calibration with the generalized rank annihilation method (GRAM). The proposed estimator is based on recently derived expressions for prediction variance and bias. It follows the latest IUPAC recommendations in the sense that it concisely accounts for the probabilities of committing both types I and II errors, i.e. false positive and false negative declarations, respectively. The estimator has been extensively validated with simulated data, yielding promising results.