基于多核DSP的以太网通信接口设计

针对8核DSP TMS320C6678与外部设备进行数据通信的需求,以片上集成千兆以太网交换子系统为核心,选取芯片88E1111作为PHY设备,设计了千兆以太网通信接口的硬件电路。在嵌入式操作系统SYS/BIOS和网络开发环境NDK上,完成了以太网底层驱动和TCP/IP协议的程序设计。通过DSP与上位机进行以太网通信测试,证明了以太网接口电路硬件及软件的正确性和实用性。     

基于FH-AC系统Portal认证的实现与开发

随着当今移动互联网的快速发展,Wi Fi设备成为人们生活当中不可缺少的组成部分,而传统的无线网络在接入稳定性和安全性方面有待进一步提高。为了解决上述问题,设计了基于FH-AC系统的Portal认证系统。该系统通过对原有Portal协议进行改进并且采用Socket/HTTP通信和CHAP认证技术等一系列技术来提升系统性能,使整个系统在使用过程中能够更快更稳定地接入当前无线网络,其系统安全性也得到进一步的提升。     

A Novel Chemo‐selective Epoxidation across Acrylate Ester: Synthesis of New Water‐Soluble Forskolin Analogues

While removing the TBDMS group from OH protection, a novel epoxidation reaction occurred across acrylate ester attached to a forskolin fragment. Besides spectroscopic data, the epoxide formation was confirmed by ring opening with a secondary amine. This unique epoxidation reaction, to our knowledge, is not known in the literature. This reaction led us to discover a simple deblocking protocol. The epoxide and the desired Michael substrates were used to introduce imidazole into forskolin.     

Application of oxetane ring opening toward stereoselective synthesis of zincophorin fragment

A stereoselective synthesis of the C1–C11 fragment of zincophorin was achieved by using an intramolecular oxetane ring opening reaction as the key step. The oxetane moiety was synthesized by employing a desymmetrization protocol developed at our group and a non-Evans syn aldol as the key steps toward the synthesis.     

Stereoselective total synthesis of penaresidin A starting from d-galactal

A stereoselective total synthesis of penaresidin A has been accomplished involving Sharpless asymmetric epoxidation, regioselective ring-opening of epoxide, azetidine formation via S_N2 reaction, Jung’s protocol, and Julia–Kocienski olefination. This approach has successfully demonstrated the synthetic utility of d-galactal in the construction of azetidine core of the natural product.     

One-pot synthesis of dihydropyrimidines via eco-friendly phosphorus derivatives catalysis

A straightforward, cost effective and eco-friendly protocol for the Biginelli reaction relying on the use of readily available hypophosphorous acid is presented. The methodology developed displays improvements compared to existing methods, is high-yielding, robust and was applied to a panel of dihydropyrimidines and thio-derivatives with various substituents. Related urea derivatives such as guanidines, benzimidazoles and benzothiazoles also reacted efficiently to afford more complex scaffolds. Thus, this rapid and convenient catalysis allows access to a wide diversity of structures including original biologically relevant heterocycles.     

Avoiding Pitfalls in Comparison of Activity and Selectivity of Solid Catalysts for Electrochemical HMF Oxidation

Electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) offers a renewable approach to produce the value-added platform chemical 2,5-furandicarboxylic acid (FDCA). The key for the economic viability of this approach is to develop active and selective electrocatalysts. Nevertheless, a reliable catalyst evaluation protocol is still missing, leading to elusive conclusions on criteria for a high-performing catalyst. Herein, we demonstrate that besides the catalyst identity, secondary parameters such as materials of conductive substrates for the working electrode, concentration of the supporting electrolyte, and electrolyzer configurations have profound impact on the catalyst performance and thus need to be optimized before assessing the true activity of a catalyst. Moreover, we highlight the importance of those secondary parameters in suppressing side reactions, which has long been overlooked. The protocol is validated by evaluating the performance of free-standing Cu-foam, and CuCoO modified with NaPO₂H₂ and Ni, which were immobilized on boron-doped diamond (BDD) electrodes. Recommended practices and figure of merits in carefully evaluating the catalyst performance are proposed.     

基于TMS320C5402的IP语音通信系统的设计

介绍了基于DSP技术的IP语音通信系统的设计。详细论述了系统结构以及音频接口模块、网络接口模块的设计方法。针对软件结构,给出了G.729语音编码以及UDP传输协议的选择与在TMS320C5402上的实现。     

基于固定电话网的中文短信息终端开发

研究了基于固定电话网（PSTN）的采用中文信息终端服务接口通信协议（CTSI）的短消息终（CPE）的软硬件开发。介绍了短信编辑接收系统与信息终端之间数据交换的协议,并以电子订货系统中发送订单为例,描述了信息终端与CTSI服务器之间链路建立、信息交互的整个过程。