毛细管区带电泳分离测定邻、对、间氯代苯酚

通过改变电泳条件,用毛细管区带电泳成功地分离了邻、对、间氯代苯酚,并检测到废水中样品的含量。研究了缓冲溶液种类、浓度、pH值、电泳电压以及内标物的选择,并得出了三种样品的标准曲线、线性范围以及加样回收率,为环境样品的监测提供了依据。     

π-Bindungsbeitrag in Boranen, 2. Mitt.:Ab initio- und Kraftfeld-Rechnungen von Vinyldifluorboran

Ab initio calculations on vinyldifluoroborane yield a -contribution of 23 kJ/mol (5.5 kcal/mol) mainly due to the C=C bond and not to the lone pairs of the fluorine atoms. The rotational barrier was also determined. The force field calculations favour the interpretation of the bond structure derived from the theab initio results.

     

Synthetische und NMR-spektroskopische Untersuchungen der Benzylaminaddition an N-Maleyl-aminosäurederivate

Summary During the addition of amines to maleylamino acids in general -amino derivatives are formed. In order to change the reactivity within the vinylogous maleyl system we introduced the -benzylester group into the starting compound N-(cis--carboxyacryloyl)-phenylalanine methylester1. The obtained benzylester2 is adding benzylamine in -position yielding N-benzyl--aspartyl(-benzyl)-phenylalanine methylester4. The addition reaction was investigated by¹H-NMR-spectroscopy. The structures of the compounds have been confirmed by elemental analysis, IR,¹H-NMR and¹³C-NMR spectroscopy.

     

Reaction of the dimethoxyaminyl radical with tertiary nitrosoalkanes as a method for the preparation of N-alkyl-N′-methoxydiazene N-oxides

The reaction of the dimethoxyaminyl radical with functionally substituted nitrosoalkanes (2) in a 2:1 ratio at 20°C gives the corresponding N-alkyl-N-methoxydiazene N-oxides (3) as a single isomer in preparative yields.N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117913 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2443–2445, October, 1992.     

An unusual new reaction of α-olefins with magnesiumn-alkyl derivatives catalyzed by Cp2ZrCl2

The reaction of organomagnesium compounds (OMC) containing alkyl radicals of normal structure with -olefins, resulting in the formation of alkenylorganomagnesium compounds and accompanied by hydride transfer was discovered and systematically investigated. A scheme providing for the formation of zirconacyclopentane complexes was proposed for the mechanism of the reaction.Institute of Organic Chemistry, Ural Branch, Russian Academy of Sciences, 450054 Ufa. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 5, pp. 1187–1196, May, 1992.     

正交试验法研制多烷基二氢化茚

双环苯型麝香化合物对香料工业具有重要意义。如粉檀麝香是合成麝香料。而1,1,2,3,3,5-六甲基-2.3-二氢化茚(HMI)则是制备粉檀麝香的母体化合物, 其经酰化后即可得到粉檀麝香。本文以对甲基异丙苯和2-甲基-丁烯-[2]为原料, 合成了HMI。     

Comparing the weak and strong gate‐coupling regimes for nanotube and graphene transistors

We present an experimental and theoretical comparison of the weak and strong gate‐coupling regimes that arise for carbon nanotube (CNT) and graphene field‐effect transistors (FETs) in back‐gated and liquid‐gated configuration, respectively. We find that whereas the back‐gate efficiency is suppressed for a liquid‐gated CNT FET, the back gate is still effective in case of a liquid‐gated graphene FET. We calculate the gate‐induced Fermi‐level shifts and induced charge densities. In both strong and weak coupling regimes, nonlinearities occur in the gate dependence of these parameters, which can significantly influence the electronic transport. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Doubly special relativity and translation invariance

We propose a new interpretation of doubly special relativity (DSR) based on the distinction between the momentum and the translation generators in its phase space realization. We also argue that the implementation of DSR theories does not necessarily require a deformation of the Lorentz symmetry, but only of the translation invariance.     

Coordinates, observables and symmetry in relativity

We investigate the interplay and connections between symmetry properties of equations, the interpretation of coordinates, the construction of observables, and the existence of physical relativity principles in spacetime theories. Using the refined notion of an event as a “point-coincidence” between scalar fields that completely characterise a spacetime model, we also propose a natural generalisation of the relational local observables that does not require the existence of four everywhere invertible scalar fields. The collection of all point-coincidences forms in generic situations a four-dimensional manifold, which is naturally identified with the physical spacetime.     

Branching spin chain dynamics

We study the dynamics of various branched spin chain systems. In such systems entanglement can be generated and distributed, providing an essential resource for teleportation or distributed quantum processing. We show in detail how simple operations can be employed at chosen times to change the subsequent dynamics of the branched spin chains, rendering the distributed entanglement more accessible.