关于耦合谐振滤波器中耦合极性的几点讨论

对改变带有交叉耦合的耦合谐振滤波器中的耦合系数的极性而不改变滤波器的性能 ,本文给出了一个充分条件及其两个推论。这为滤波器的设计和实现带来了一定的灵活性。结合这一充分条件 ,本文还详细解释了滤波器中的耦合极性的相对性问题。最后给出了在确定耦合系数矩阵后实现滤波器时设计耦合结构的一种通用方法。     

Efficient Imine Formation by Oxidative Coupling at Low Temperature Catalyzed by High-Surface-Area Mesoporous CeO2 with Exceptional Redox Property

High-surface-area mesoporous CeO₂ (hsmCeO₂) was prepared by a facile organic-template-induced homogeneous precipitation process and showed excellent catalytic activity in imine synthesis in the absence of base from primary alcohols and amines in air atmosphere at low temperature. For comparison, ordinary CeO₂ and hsmCeO₂ after different thermal treatments were also investigated. XRD, N₂ physisorption, UV-Raman, H₂ temperature-programmed reduction, O₂ temperature-programmed desorption, EPR spectroscopy, and X-ray photoelectron spectroscopy were used to unravel the structural and redox properties. The hsmCeO₂ calcined at 400 °C shows the highest specific surface area (158 m² g⁻¹), the highest fraction of surface coordinatively unsaturated Ce³⁺ ions (18.2 %), and the highest concentration of reactive oxygen vacancies (2.4×10¹⁵ spins g⁻¹). In the model reaction of oxidative coupling of benzyl alcohol and aniline, such an exceptional redox property of the hsmCeO₂ catalyst can boost benzylideneaniline formation (2.75 and 5.55 mmol h⁻¹ based on >99 % yield at 60 and 80 °C, respectively) in air with no base additives. It can also work effectively at a temperature of 30 °C and in gram-scale synthesis. These are among the best results for all benchmark ceria catalysts in the literature. Moreover, the hsmCeO₂ catalyst shows a wide scope towards primary alcohols and amines with good to excellent yield of imines. The influence of reaction parameters, the reusability of the catalyst, and the reaction mechanism were investigated.     

Electron transport of a quantum wire with spatially periodic spin–orbit coupling

Electron transport properties of an ideal one-dimensional (1D) quantum wire are studied including spatially periodic Rashba spin–orbit coupling (SOC) and Dresselhaus SOC. By comparing with the previous work [S.J. Gong, Z.Q. Yang, J. Phys. Condens. Matter 19 (2007) 446209], two transmission gaps appear in the transmission probability of electrons and their widths are also broadened dramatically. Moreover, it is found that their widths are sensitive not only to the strength of SOCs but also to the length ratio of SOCs segment and non-SOCs segment. In addition, a ‘circle-type’ transmission behavior has been found by tuning the strength of SOCs continuously. Our results may extend the previous work and provide an more effective method to manipulate the current in nanoelectric devices.     

槽区加载介质矩形格栅慢波结构的色散与增益

建立了槽区内加载介质的格栅慢波结构模型.通过Borgnis函数法和场匹配法得到冷态和热态色散方程.并推导了耦合阻抗的表达式.在稀疏电子注的假设下,求得增益近似解的表达式.通过数值方法,求解并分析了加载介质对色散关系、基波耦合阻抗、基波相速和基波增益的影响.并指出分别在槽内加载介质和格栅对侧加载介质对高频特性的不同影响趋势.     

耦合时滞光电反馈系统的同步研究

同步是实 现保密通信的基础,现有的基于时滞光电反馈混沌系统的同步研究主要集中在实现方面。本 文利用Lyapunov函数法,从理论研究耦合时滞光电反馈混沌系统的同步问题,包括单向耦合 和双向耦合两种形式。结果表明,耦合时滞光电反馈混沌系统能够实现鲁棒同步。对理论结 果进行了数值实验分析,结果与理论分析相一致。     

计算传输线平均耦合截面积的一种高效全波方法

在功率平衡法的网络化公式应用中,精确预知腔内装载物的耦合截面积是关键,这通常依赖于混响室的实验测定.文中使用平面波角谱概念和蒙特卡罗方法来数值模拟混响室中的电磁环境,在此基础上,首次应用基于互易定理的快速全波分析方法提取了理想混响室内靠近理想导电地平面的多导体传输线的平均耦合截面积,验证了方法的正确性,并计算了单根裸线传输线、带包层传输线、双绞传输线、传输线附近有导体挡板以及多导体传输线端口的平均耦合截面积.该方法具有计算精度高、仿真速度快、适用范围广的特点.     

平坦地面条件下装备间天线电磁耦合度分析

分析了地表面反射系数以及地面土壤介质的介电特性,研究了车体结构对天线辐射特性的影响,仿真得到了车体模型、地面介质、距离等因素对天线间耦合度的影响,建立了平坦地面条件下,通信车的收发天线间电磁耦合度的精确的仿真模型.经与实测数据对比分析,仿真结果与实测数据变化规律一致,最大误差16.54 dB,均方差4.21 dB.     

Highly selective synthesis of novel (E)-styrylsilatranes via ruthenium-catalyzed trans-silylation

Protocols for the synthesis of cage-substituted 1-vinylsilatranes have been developed and updated. The 1-vinylsilatranes with organic substituents attached to silatrane cage were functionalized in ruthenium-catalyzed trans-silylation with olefins, leading to novel styrylsilatranes in high yields.     

New and Practical Synthesis of Montelukast Sodium,an Antiasthmatic Drug

Abstract

A new and practical synthesis of montelukast sodium, an antiasthmatic drug, is described. The key steps are the synthesis of nitrile derivative 4 by chiral reduction of keto ester 9 using (?)-DIP-Cl, synthesis of vinylquinoline framework 16 by Wittig reaction, and Heck coupling of nitrile 4 with vinylquinoline 16. The method is operationally simple and suitable for the industrial production of the drug substance.

Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.     

Efficient and Convenient Method for the Synthesis of N‐Arylhydrazones using a Palladium‐Catalyzed Bond‐Forming Reaction

A highly effective, convenient, and reproducible industrial process for palladium‐catalyzed carbon–nitrogen cross coupling has been developed and applied on a large scale. Thus various functionalized N‐arylhydrazones have been easily prepared and well characterized by conventional spectroscopic methods.