溶液中CO…CO+体系相互作用的理论研究

在B3LYP/6-311+G水平上利用SCRF方法中的Onsager model模型考察了CO…CO+体系在两种介质(水和苯)中可能存在的相互作用复合物,发现由于H2O与CO+之间存在较强的相互作用,在水中仅能存在一种稳定结构,而在苯溶液中存在三种稳定的复合物.通过消除基函数引起的叠加误差(BSSE)和零点振动能(ZPVE)的校正,精确求算出三种复合物在两种介质中的相互作用能,表明溶剂的性质对复合物的稳定性有着重要的影响.     

K＋－SrO－La_2O_3／ZnO催化剂上甲烷氧化偶联反应Ⅰ．催化活性和反应气中添加CO_2的影响

Ｋ＋┐ＳｒＯ┐Ｌａ２Ｏ３／ＺｎＯ催化剂上甲烷氧化偶联反应＊Ⅰ．催化活性和反应气中添加ＣＯ２的影响余林徐奕德＊＊郭燮贤（中国科学院大连化学物理研究所催化基础国家重点实验室，大连１１６０２３）关键词钾离子，氧化锶，氧化镧，氧化锌，金属氧化物催化剂，甲烷，...     

自聚焦透镜用于端泵浦DPL的耦合光学系统

本文用自聚焦透镜耦合ＬＤ输出，解决了需要短焦距、大数值孔径透镜的设计和制方面的困难。提出了计算自聚焦透镜耦合效率的简化模型。用自聚焦透镜和一对正交柱面透镜设计了一个耦合系统，并用该耦合系统端泵浦Ｎｄ：ＹＡＧ棒做了实验。     

Creation of entangled states of excitons in coupled quantum dots

We present two methods for the creation of two-particle entangled states of excitons in a coupled quantum dot system. The system contains two identical quantum dots that are coupled by an inter-dot hopping process. The manipulation of the system is succeeded by proper application of an external laser field.     

一种实现光源与光纤耦合的方法

本文介绍了一种用显微镜筒与透镜构成的光学系统来实现光源与光纤耦合的方法。该方法具有光路系统小巧方便、耐用、耦合效率高等优点。     

1.30μmDFB激光器组件的设计和制做及其工作原理

本文自行设计和制作了１．３０μｍＤＦＢ激光器组件的讨论了光隔离和光耦合原理。由于采用的激光器－光隔离器－光纤的一体化结构，大大增加了该组件的可用性。在实验中得到高达５５％的耦合效率。     

强流RFQ的稳定性设计研究

对强流RFQ耦合间隙的确定、二极模稳定杆的设计进行了详细的研究和讨论.利用现有的RFQ冷模,进行了本征模频率的测量、场分布的调试和测量、二极模稳定杆的试验.并通过与模拟结果的比较,验证了模拟程序在RFQ腔体设计中的可靠性.同时,对影响RFQ稳定性设计的物理进行了有益的探讨.     

In situ Synthesis of Oligonucleotides on Plasma Treated Polypropylene Microporous Membrane

Polypropylene microporous membranes were treated with plasma in a mixture of N2 and H2 (1:2 in volume). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and ultra-violet (UV) spectra demonstrated the success of grafting amino groups. The density of the polar amino groups on the membrane surface is about 0.59 μmol/cm^2. The as-treated membranes were successively applied to the in situ synthesis of oligonucleotides and an average coupling yield was more than 98%. The surface feature of the treated membrane is suggested to be responsible for its advantage over a glass slide.     

Alternating copolyfluorenevinyles with polynuclear aromatic moieties: Synthesis,photophysics, and electroluminescence

Three new copolymers, namely poly(fluorenevinylene‐alt‐naphthalenevinylene) ( N ), poly(fluorenevinylene‐alt‐anthracenevinylene) ( A ) and poly(fluorenevinylene‐alt‐pyrenevinylene) ( P ), were synthesized by Heck coupling of 9,9‐dihexyl‐2, 7‐divinylfluorene with a polynuclear aromatic dibromide. The 9,10‐disubstituted anthracene was obtained exclusively for A while N and P were obtained as a mixture of two isomers with predominant the 1,4‐disubstituted naphthalene and 1,8‐disubstituted pyrene, respectively. The polymers were soluble in common organic solvents and decomposed above 370 °C. Their glass transition temperature increased from 58 to 110 °C by increasing the number of the phenyl rings of the polynuclear aromatic moiety. Rather high‐efficiency blue and blue‐greenish photoluminescence (PL) of these copolymers in solution was largely decreased in their films, indicating the presence of concentration quenching in the solid state. The OLED using these polymers demonstrated green EL in the case of copolymers N and A , and red EL in the P derivative with η_EL = 0.26–0.31%. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4661–4670, 2007