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951.
In the study, sludge from the aluminum profile factory and kaolin were used as the raw materials. Through adding ZrO2 mineralizer in different contents, Al2-xZrx+yTi1-yO5 and Al4.54Si1.46O9.73 solid solution multiphase material was prepared to effectively inhibit the decomposition of aluminum titanate solid solution and optimize high temperature property of the multiphase material. With XRD and SEM means, crystalline structure and microstructure of each sample were characterized, and properties of each sample were tested. According to experimental results, the optimal addition amount of ZrO2 mineralizer was determined to be 1.5%. Correspondingly, contents for aluminum titanate solid solution, mullite solid solution and α-Al2O3 were 70.3%, 26.8% and 2.9% respectively, bulk density was 3.20 g/cm3, degree of porosity was 5.57%, water absorption rate was 1.74%, and the once thermal shock rupture strength retention rate was 90.52%. 相似文献
952.
应用修正的BET热力学模型对Mg(NO3)2-NH4NO3-H2O三元体系和LiNO3-Mg(NO3)2-NH4NO3-H2O四元体系在273~320 K的相图进行预测,并找到一个相变温度较低的四元共晶点Mg(NO3)2.6H2O-LiNO3.3H2O-NH4NO3,其质量百分数组成为:25.5%的硝酸铵,28.4%的硝酸锂,13.8%的硝酸镁和32.3%的水,通过实验对共晶点组成材料的吸放热行为进行测定,发现其熔化温度为286.3 K,且DSC测试其相变热焓为192.7 J.g-1,表明该材料可用作潜在的低温相变储能材料。 相似文献
953.
Yufang Hu Zhaohui Zhang Huabin Zhang Lijuan Luo Minglei Zhang Xiao Yang Shouzhuo Yao 《中国化学》2012,30(2):377-385
A novel sensor for detection of trace gallium ion [Ga(III)] was created by stepwise modification of a gold electrode with β‐cyclodextrin (β‐CD)/multi‐walled carbon nanotubes (MWCNTs) and an ion imprinted polymer (IIP). The sensor surface morphology was characterized by scanning electron microscopy. The electrochemical performance of the imprinted sensor was investigated by cyclic voltammetry, differential pulse voltammetry and chronoamperometry. The sensor displayed excellent selectivity towards the target Ga(III) ion. Meanwhile, the introduced MWCNTs displayed noticeable catalytic activity, and β‐CD demonstrated significant enrichment capacity. A linear calibration curve was obtained covering the concentration range from 5.0×10?8 to 1.0×10?4 mol·L?1, with a detection limit of 7.6×10?9 mol·L?1. The proposed sensor was successfully applied to detect Ga(III) in real urine samples. 相似文献
954.
Several 2‐alkylquinolizinium‐1‐olates 9 , i.e., heterobetaines, were prepared from ketone 11 , the latter being readily available either from pyridine‐2‐carbaldehyde via a Grignard reaction, followed by oxidation with MnO2, or from 2‐picolinic acid (=pyridine‐2‐carboxylic acid) via the corresponding Weinreb amide and subsequent Grignard reaction. Mesoionic heterobetaines such as quinolizinium derivatives have the potential to undergo cycloaddition reactions with double and triple bonds, e.g., 1,3‐dipolar cycloadditions or Diels? Alder reactions. We here report on the scope and limitations of cycloaddition reactions of 2‐alkylquinolizinium‐1‐olates 9 with electron‐poor acetylene derivatives. As main products of the reaction, 5‐oxopyrrolo[2,1,5‐de]quinolizines (=‘[2.3.3]cyclazin‐5‐ones’) 19 were formed via a regioselective [2+3] cycloaddition, and cyclohexadienone derivatives, formed via a Diels? Alder reaction, were obtained as side products. The structures of 2‐benzylquinolizinium‐1‐olate ( 9a ) and two ‘[2.3.3]cyclazin‐5‐ones’ 19i and 19l were established by X‐ray crystallography. 相似文献
955.
Jia‐Qi Li Xu Quan Prof. Dr. Pher G. Andersson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(34):10609-10616
α,β‐Unsaturated esters have been employed as substrates in iridium‐catalyzed asymmetric hydrogenation. Full conversions and good to excellent enantioselectivities (up to 99 % ee) were obtained for a broad range of substrates with both aromatic‐ and aliphatic substituents on the prochiral carbon. The hydrogenated products are highly useful as building blocks in the synthesis of a variety of natural products and pharmaceuticals. 相似文献
956.
A new strategy was explored to generate pure gold cluster ions, Aun+/?, from gold films deposited on solid substrates via a matrix‐assisted laser ablation technique. The gold films deposited on SiO2‐particle‐assembled photonic crystals were demonstrated to be the most ideal compared with the films deposited on various glass slides. Dropped with a matrix of 2‐(4‐hydroxyphenylazo) benzoic acid and bombarded by nitrogen pulse laser (355 nm), they could release a series of Aun+ with n more than 110 or Aun? with n more than 60 according to the data obtained by inline time‐of‐flight mass spectrometry. The gold‐deposited photonic crystal substrates could be stored at room temperature for at least 6 months. The method is hence steady and convenient in use. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
957.
计算了气相反应C60+O3=C6O(C2v)+O2的热力学函数.得到了该反应Gibbs自由能的具体数值,结果表明在所研究的温度范围内Gibbs自由能为负值,从热力学角度来说,该反应可以自发进行,在计算该气相反应热力学函数的基础上,给出了气相C6O(C2v)的标准热力学函数 相似文献
958.
Solvothermal reaction of aromatic terphenyl-2,5,2',5'-tetracarboxylic acid (H 4 qptc) ligand and the transitional metal cation of Mn II in the presence of 3-(2-pyridyl)pyrazole (pp) affords one new coordination polymer, [Mn(qptc)0.5(pp)2]n·n(H2O) (1). The structure has been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR, TGA, and magnetism. The carboxyl groups of qptc 4-exhibit a μ1-η1 :η 0 coordination mode, and the qptc4- acts as a H-shaped ligand linking the Mn Ⅱ centers together to form a 2D polymeric [Mn(qptc) 0.5 ] n layer. The crystal of 1 crystallizes in orthorhombic, space group Pbca with a=9.3119(12), b=20.848(3), c=26.134(3) , V=5073.4(11) 3 , Z=8, C27H19MnN6O5 , Mr=562.42, Dc=1.473 g/cm3 , F(000)=2304 and μ(MoKα)=0.571 mm-1 . The final R=0.0468 and wR=0.1196 for 4429 observed reflections with I > 2σ(I) and R=0.0797 and wR=0.1383 for all data. 相似文献
959.
取水样25mL,加入无水硫酸钠3.0g,加入环己烷2.0mL,振荡萃取3min。移取萃取了邻苯二甲酸二(2-乙基己基)酯(DEHP)的上层有机相2.0μL注入HP-5毛细管柱(30m×0.32mm,0.25μm)色谱分离后进行质谱测定。DEHP的质量浓度在50.0μg.L-1以内与其峰面积呈线性关系,方法的检出限(3S/N)为0.052μg.L-1。分析了早、中、晚不同时间的天津市自来水,并用标准加入法做回收试验,测得回收率在97.0%~109.4%之间,测定值的相对标准偏差(n=6)均小于2.5%。 相似文献
960.
《Analytical letters》2012,45(10):1587-1596
Chemically synthesized nanostructures possess well-defined domains with an interconnected network, which helps the carriers to bypass the other material in the solar cell while moving to their respective electrodes. In this work, CuInS2 films constituting CuInS2 nanotubes and nanoparticles were fabricated using a hot-injection chemical technique, followed by sulfurization. Structural and microstructural investigations reveal Cu2S nanoparticle formation at an early stage of growth of nanotubes, serving as possible catalyst sites for the subsequent anisotropic growth of the heterostructured hexagons. The crossover takes place over a number of intermediate stages. This sharing of the heterostructure by the hexagonal Cu2S and chalcopyrite CuInS2 minimizes the lattice distortion. The Cu2S- CuInS2 interface in the heterostructure acts as the nucleation center for CuInS2 nanotubes. Optical absorption and Raman spectroscopy studies reveal better optical properties for CuInS2 nanoparticles as compared to CuInS2 nanotubes. Compared to all other nanostructures, nanowires or nanotubes tend to provide single-crystalline nanograins for direct characterization. These nanoparticles, especially the nanotubes, can be used to form an interconnected network structure of p- and n-type materials in bulk heterojunctions providing the key to improve solar cell efficiencies. 相似文献