全文获取类型
收费全文 | 25770篇 |
免费 | 1660篇 |
国内免费 | 3657篇 |
专业分类
化学 | 19310篇 |
晶体学 | 1057篇 |
力学 | 218篇 |
综合类 | 192篇 |
数学 | 3686篇 |
物理学 | 4079篇 |
无线电 | 2545篇 |
出版年
2024年 | 15篇 |
2023年 | 198篇 |
2022年 | 613篇 |
2021年 | 773篇 |
2020年 | 579篇 |
2019年 | 592篇 |
2018年 | 451篇 |
2017年 | 627篇 |
2016年 | 653篇 |
2015年 | 634篇 |
2014年 | 906篇 |
2013年 | 1858篇 |
2012年 | 1406篇 |
2011年 | 1634篇 |
2010年 | 1608篇 |
2009年 | 1854篇 |
2008年 | 1776篇 |
2007年 | 1793篇 |
2006年 | 1725篇 |
2005年 | 1463篇 |
2004年 | 1418篇 |
2003年 | 1219篇 |
2002年 | 1041篇 |
2001年 | 790篇 |
2000年 | 747篇 |
1999年 | 569篇 |
1998年 | 558篇 |
1997年 | 468篇 |
1996年 | 403篇 |
1995年 | 398篇 |
1994年 | 349篇 |
1993年 | 323篇 |
1992年 | 305篇 |
1991年 | 225篇 |
1990年 | 136篇 |
1989年 | 160篇 |
1988年 | 142篇 |
1987年 | 93篇 |
1986年 | 62篇 |
1985年 | 73篇 |
1984年 | 95篇 |
1983年 | 26篇 |
1982年 | 49篇 |
1981年 | 66篇 |
1980年 | 54篇 |
1979年 | 44篇 |
1978年 | 28篇 |
1977年 | 23篇 |
1976年 | 14篇 |
1975年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
L. J. Yamí n S. E. Blanco J. M. Luco F. H. Ferretti 《Journal of Molecular Structure》1997,390(1-3):209-215
The isomerization mechanism of 2′(OH)chalcone (1) in flavanone (2) was studied. The calculations were performed with the semiempirical method AM1, using totally optimized molecular geometries. A 6-step mechanism including several equilibrium states was proposed. It was concluded that: (a) At the conformational equilibrium of 1 there could be 43.9% of s-cis conformer; (b) The acid dissociation of 1 trans-s-trans is considerable; (c) The EE, ΔHf and net charges show that the rotation of ring A of 1 and the formation of ring C of 2 occurs without greater impairments; (d) Although the keto structure is the most stable one, the enolate of 2 is present in the reaction medium; (e) The conversion of enol of 2 in the keto form would be the limiting step of the analyzed isomerization rate. 相似文献
132.
J. W. Huang J. M. Ryan K. L. Bray T. F. Kuech 《Journal of Electronic Materials》1995,24(11):1539-1546
The defect engineering in metalorganic vapor phase epitaxy InxGa1-xAs and InP by controlled oxygen doping using diethyl aluminum ethoxide (DEALO) was developed in this study. DEALO doping has
led to the incorporation of Al and O, and the compensation of shallow Si donors in InxGa1−xAs: Si with 0 ≤ x ≤ 0.25. With the same DEALO mole fraction during growth, the incorporation of Al and O was found to be independent
of x, but the compensation of Si donors decreases with increasing In content. Deep level transient spectroscopy analysis on
a series of InxGa1-xAs: Si. samples with 0 ≤ x ≤ 0.18 revealed that oxygen incorporation led to a set of deep levels, similar to those found in
DEALO doped GaAs. As the In composition was increased, one or more of these deep levels became resonant with the conduction
band and led to a high electron concentration in oxygen doped In0.53Ga0.47As. Low temperature photoluminescence emission measurements at 12K on the same set of samples revealed the quenching of the
near-band edge peak, and the appearance of new oxygen-induced emission features. DEALO doping in InP has also led to the incorporation
of Al and O, and the compensation of Si donors due to oxygen-induced multiple deep levels. 相似文献
133.
聚醚醚酮链结构与反应的模型化合物的量子化学研究 总被引:1,自引:1,他引:0
利用AM1方法对聚醚醚酮模型化合物全优化,结果为:芳环平均相互扭转角为33.0度,桥键角117.0-118.0度,其分子结构拓扑图形表明:所有苯环(核)为平面构型,但其内角扭曲;其氢原子对苯环构型无实质性贡献,在更长链的计算中,冻结苯核与氢原子也得出满意结果,根据Mulliken键序与电荷讨论了醚交换与磺化反应。 相似文献
134.
B. M. Dzhagarov N. N. Kruk N. V. Konovalova A. A. Solodunov I. I. Stepuro 《Journal of Applied Spectroscopy》1995,62(2):285-289
Presented at the XV IUPAC Symposium on Photochemistry, Prague, July 17–22, 1994. 相似文献
135.
New Spiro Compounds from Cyclophosphazenes and Cyclodi[phosphadiazanes] Chlorocyclophosphazenes (Cl2P = N)3 and (Cl2p = N)4 react with dihydrazidophosphoric acid derivatives in THF in the presence of triethylamine to give the spirocyclic compounds Cl4N3P3(NHN(CH3))2P(S)OC6H5, Cl6N4P4(NHNH)2P(S)OC6H5. Constitutions have been confirmed by MS, NMR, IR and elemental analysis. 相似文献
136.
Hans C. Fogedby 《Journal of statistical physics》1992,69(1-2):411-425
We elaborate in some detail on a new phase space approach to complexity, due to Y.-C. Zhang. We show in particular that the connection between maximal complexity and power law noise or correlations can be derived from a simple variational principle. For a 1D signal we find 1/f noise, in accordance with Zhang. 相似文献
137.
Shayesteh S. Farjami B. Soltani M. A. Solimany 《International Journal of Infrared and Millimeter Waves》2002,23(12):1691-1697
We present and discuss infrared magnetoplasma reflectivity and surface polariton modes in Ga1–xNxAs. It assumed that the sample is characterized by a magnetoplasma dielectric tensor. Surface polariton dispersion for two component magnetoplasma was calculated from reflectivity spectra data. We detect transverse optic phonon of GaN sublattice in 470 cm-1. The origin of sharp feature in p-polarization reflectivity about 300 cm–1 as well as LO phonon frequency of GaAs sublattice is due to Brewster mode. An interesting feature of surface modes in Voigt geometry is nonreciprocalicity, which means that the frequency changes when the direction of propagation is reversed. Also, the infrared magnetoplasma reflectivity of GaNAs should be providing determination of the electrons and heavy holes effective mass and carrier's concentration. 相似文献
138.
139.
J. M. Pico C. P. Menaut J. Fernández J. L. Legido M. I. Paz Andrade 《Journal of solution chemistry》1991,20(1):115-124
Excess molar enthalpies hE at 25 and 35° C and atmospheric pressure, are reported for the binary mixtures formed by a 2-butanone and 2-pentanone with 1-chlorobutane, 1-chloropentane, 1-chlorohexane, or 1-chlorooctane. The hE values for all the mixtures are positive, increasing as the 1-chloroalkane length increases and as the ketone length decreases. Excess molar enthalpies depend slightly on the temperature. The experimental values together with those from the literature were used to calculate the interaction parameters for the Dang-Tassios version of the UNIFAC model.Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990. 相似文献
140.