全文获取类型
收费全文 | 11321篇 |
免费 | 1860篇 |
国内免费 | 1592篇 |
专业分类
化学 | 1316篇 |
晶体学 | 56篇 |
力学 | 355篇 |
综合类 | 86篇 |
数学 | 347篇 |
物理学 | 3503篇 |
无线电 | 9110篇 |
出版年
2024年 | 148篇 |
2023年 | 418篇 |
2022年 | 576篇 |
2021年 | 522篇 |
2020年 | 394篇 |
2019年 | 473篇 |
2018年 | 279篇 |
2017年 | 370篇 |
2016年 | 399篇 |
2015年 | 452篇 |
2014年 | 898篇 |
2013年 | 670篇 |
2012年 | 825篇 |
2011年 | 806篇 |
2010年 | 780篇 |
2009年 | 825篇 |
2008年 | 875篇 |
2007年 | 642篇 |
2006年 | 713篇 |
2005年 | 631篇 |
2004年 | 432篇 |
2003年 | 382篇 |
2002年 | 310篇 |
2001年 | 248篇 |
2000年 | 212篇 |
1999年 | 201篇 |
1998年 | 174篇 |
1997年 | 163篇 |
1996年 | 184篇 |
1995年 | 144篇 |
1994年 | 101篇 |
1993年 | 75篇 |
1992年 | 111篇 |
1991年 | 102篇 |
1990年 | 71篇 |
1989年 | 91篇 |
1988年 | 29篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 10篇 |
1980年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
881.
882.
高温超导体是一个强关联体系,它向传统的能带论和强关联模型研究提出了严重的挑战,第一性原理的电子结构的计算研究,试图给出反常的色散关系和费米面几何特性,以及大U修正下的影响等。模型哈密顿的研究,企图概括高温超导的主要物理特征,它主要采用两类方法;一类是严格对角化方法,另一类是量子蒙特卡罗方法,对于高温超导电性机制模型,也作了介绍。 相似文献
883.
讨论一类特殊情形的非方系统的Morgan问题,得到了问题有解的充分必要条件,给出了这一类系统判断其Morgan问题是否有解的算法. 相似文献
884.
885.
渡导CO2激光器具有紧凑、高增益、可调谐等优点,因此引起了人们极大的注意。它将在激光通讯、激光雷达、高分辨率光谱学等方面得到广泛的应用。 相似文献
886.
The implementation of clean energy techniques, including clean hydrogen generation, use of solar-driven photovoltaic hybrid systems, photochemical heat generation as well as thermoelectric conversion, is crucial for the sustainable development of our society. Among these promising techniques, electrocatalysis has received significant attention for its ability to facilitate clean energy conversion because it promotes a higher rate of reaction and efficiency for the associated chemical transformations. Noble-metal-based electrocatalysts typically show high activity for electrochemical conversion processes. However, their scarcity and high cost limit their applications in electrocatalytic devices. To overcome this limitation, binary catalysts prepared by alloying with transition metals can be used. However, optimization of the activity of the binary catalysts is considerably limited because of the presence of the miscibility gap in the phase diagram of binary alloys. The activity of binary electrocatalysts can be attributed to the adsorption energy of molecules and intermediates on the surface. High-entropy alloys (HEAs), which consist of diverse elements in a single NP, typically exhibit better physical and/or chemical properties than their single-element counterparts, because of their tunable composition and inherent surface complexity. Further, HEAs can improve the performance of binary electrocatalysts because they exhibit a near-continuous distribution of adsorption energy. Recently, HEAs have gained considerable attention for their application in electrocatalytic reactions. This review summarizes recent research advances in HEA nanostructures and their application in the field of electrocatalysis. First, we introduce the concept, structure, and four core effects of HEAs. We believe that this part will provide the basic information about HEAs. Next, we discuss the reported top-down and bottom-up synthesis strategies, emphasizing on the carbothermal shock method, nanodroplet-mediated electrodeposition, fast moving bed pyrolysis, polyol process, and dealloying. Other methods such as combinatorial co-sputtering, ultrashort-pulsed laser ablation, ultrasonication-assisted wet chemistry, and scanning-probe block copolymer lithography are also highlighted. Among these methods, wet chemistry has been reported to be effective for the formation of nano-scale HEAs because it facilitates the concurrent reduction of all metal precursors to form solid-solution alloys. Next, we present the theoretical investigation of HEA nanocatalysts, including their thermodynamics, kinetic stability, and adsorption energy tuning for optimizing their catalytic activity and selectivity. To elucidate the structure–property relationship in HEAs, we summarize the research progress related to electrocatalytic reactions promoted by HEA nanocatalysts, including the oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, methanol oxidation reaction, and CO2 reduction reaction. Finally, we discuss the challenges and various strategies toward the development of HEAs. 相似文献
887.
888.
889.
890.
报道了在兰州重离子加速器国家实验室电子回旋共振离子源原子物理实验平台上,用高电荷态40Arq+(1≤q≤12)离子作用于半导体Si固体表面时的电子发射产额实验测量.实验中,通过改变炮弹离子的电荷态和引出电压选取其不同的势能和动能,系统地研究了入射离子势能沉积和与其在固体中的电子能损对表面电子发射产额的贡献.结果表明,作为引起表面电子发射的两个主要因素,单离子的电子发射产额与炮弹离子在固体表面的势能沉积和电子能损都有近似的正比关系. 相似文献