TiN和Ti1-xSixNy薄膜的微观结构分析

使用x射线衍射(XRD)、x射线光电子谱(XPS)、高分辨透射电子显微镜(HRTEM)和原子力显微镜(AFM)多种观测手段分析了TiN薄膜和Ti1-xSixNy纳米复合薄膜的微观结构.实验分析证明Ti1-xSixNy薄膜是由直径为3-5nm的纳米晶TiN和非晶Si3N4相构成,并且Ti1-xSixNy薄膜的表面粗糙度小于相同条件下制备的TiN薄膜,在Ti1-xSixNy薄膜体系的自由能中引入界面能的概念,在此基础上分析了体系中TiN晶粒的取向问题.     

Studies on the Adsorption of Asymmetrical Triblock Copolymers by Scheutjens-Fleer Theory and Monte Carlo Simulation

The adsorption of asymmetrical triblock copolymers from a non-selective solvent on solid surface has been studied by using Scheutjens-Fleer mean-field theory and Monte Carlo simulation method on lattice model. The main aim of this paper is to provide detailed computer simulation data, taking A8-kB20Ak as a key example, to study the influence of the structure of copolymer on adsorption behavior and make a comparison between MC and SF results. The simulated results show that the size distribution of various configurations and density-profile are dependent on molecular structure and adsorption energy. The molecular structure will lead to diversity of adsorption behavior. This discrepancy between different structures would be enlarged for the surface coverage and adsorption amount with increasing of the adsorption energy. The surface coverage and the adsorption amount as well as the bound fraction will become larger as symmetry of the molecular structure becomes gradually worse. The adsorption layer becomes thicker with increasing of symmetry of the molecule when adsorption energy is smaller but it becomes thinner when adsorption energy is higher. It is shown that SF theory can reproduce the adsorption behavior of asymmetrical triblock copolymers. However, systematic discrepancy between the theory and simulation still exists.The approximations inherited in the mean-filed theory such as random mixing and the allowance of direct back folding may be responsible for those deviations.     

SMT的110个必知问题

新型表面贴装技术进步非常迅速，发展非常快，对于从事SMT行业的人士来说，掌握一些基础知识是非常有必要的。本文介绍一些表面贴装技术的一些基础知识。     

我国表面安装器件发展状况

概括介绍我国表面安装器件十年来的生产发展状况，提供至今生产线的引进分布、品种生产能力、原材料国产化、外形和引线框架标准、市场、国内表面安装技术设备研制动向，说明存在的问题和国外技术上的差距，从而就社会主义市场经济下，如何发展表面安装产业，提出一些建议以供参考。     

利用正交法优化人造水晶生长工艺

本文介绍了应用正交法优化人造水晶生长工艺的方法并在此基础上提出了生长工艺较为理想的设计；进一步明确了实际生产当中Ｑ值，生长速率，包裹体等各单项指标的优化方法，准确估计目前正使用的生长工艺距理想工艺的距离。从而有效地提高人造水晶生长工艺水平，在实际生产提供可靠的指导依据。本文给出利用正交法优化人造水晶生长工艺的较详细的操作和分析方法。     

SMT的关键——贴片技术

本文介绍了贴片机的近况与发展，较详细介绍了西铁城Ａ４３０贴片机及其维护，并就实际生产中遇到的问题谈谈自己的解决办法。     

分形技术在40Cr钢断裂中的应用

Ｍａｎｄｅｌｂｏｒｔ等指出，金属受冲击或拉伸载荷断裂以后所表成的断裂表面是粗糙的和不规则的，它的形状受金属的晶粒、夹杂物和沉淀相的大小及分布有关，同时也受试样的几何尺寸等因素的影响。然而，用不同的放大倍数观察断口的放射区，发现它具有自相似性。这种自相...     

冲击波对结晶MgO晶体结构,表面性质和催化剂性能的影响

用ＸＲＤ，ＥＳＲ和ＴＰＤ等技术研究冲击波处理的结晶ＭｇＯ后发现，ＭｇＯ的晶格发生畸变，微应力值ε１／２Ｄ显著增大，有大量缺陷产生并形成Ｆ心，晶体的平均晶粒减小，且表现出各向异性，从而引起了催化剂表面碱中心强度增大，数目变化，在对乙烷氧化脱氢反应中表现出较高的活性和对乙烯的选择性，初步讨论了可能的结构模型和催化机理。