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81.
Tun Hai Xu Gang Lv Tong Hua Liu Ya Juan Xu Yun Shan Si Sheng Xu Xie Hong Feng Zhao Dong Han Dong Ming Xu 《中国化学快报》2008,19(7):817-820
A new tdterpenoid glycoside, 3-β-O-β-D-glucopyranosyl presenegenin 28-O-α-L-arabipyranosyl(1 → 3)-6-β- xylopyranosyl(1 → 4)-[β-D-apiofuranosyl(1 → 3)]-Ct-L-rhamnopyranosyl(1 → 2)-[α-L-rhamnopyranosyl(1 → 3)]-β-D-fucopyranosyl ester (1) was isolated from the Polygala tenuifolia Willd., together with two known saponins, including polygalasaponinXXIV (2) and polygalasaponinXXVIII (3). The structure of new compound was elucidated by spectroscopic methods. 相似文献
82.
Lian Chun Zou Tong Fei Zhu Shu Cai Gan Da Cheng Wang Yu Zhang Xu Ming Deng 《中国化学快报》2008,19(10):1224-1227
From the roots ofPicrorhiza scrophulariiflora, two new secoifidoid glycosides, named picrosecosides Ⅰ and Ⅱ (1, 2) have been isolated. Their structures were elucidated on the basis of chemical and spectropic evidences. 相似文献
83.
提升化学对学生的吸引力是促使学生选修化学、落实化学核心素养的前提。以校本选修课程“化学与考古”为例,从现代技术、物质性质、实验装备、反应原理、工艺、生物化学等多角度用化学知识解决考古与文保疑难,将抽象的化学知识落实到考古事例中探讨,主动创设情境帮助学生体验化学的魅力,为普高教学中化学知识的实用化提供新的视角。 相似文献
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AMI semi-empirical method was used to optimize the barbituric acid derivatives substituted with glucosyl B1-5 (series B), and the thiobarbituric acid derivatives substituted with glucosyl T1-5 (series T). Based on the optimized structures, INDO/CI method was adopted to calculate the electronic spectra. Meanwhile, the second-order nonlinear optical (NLO) coefficients βμ were calculated with the sum-over-state (SOS) formula. The results show that when the number of glucosyl units was increased, |βμ| values of the barbituric and thiobarbituric acid derivatives were both enhanced, especially for thiobarbituric acid derivatives. It indicates that non-conjugated substituted group could also improve NLO properties of materials when the number of repeated units was increased. Additionally, the absorption bands appearing in UV area are consistent with the proper change of the number of glucosyl units, and consequently it can be concluded that the high transparencies of all systems were scarcely varied. 相似文献
86.
聚合物粒子在生物化学与生物医学中的应用 总被引:21,自引:1,他引:21
就亚微米和单粒径两种新型的聚合物粒子在生物化学与生物医学如免疫分析、药物载体、真核细胞、原核细胞及生物大分子产品等的分离等领域中的最新应用进行了综述。 相似文献
87.
A new alkaloid, named 6-(2',3'-dihydroxy-4'-hydroxymethyl-tetrahydro-furan-1'-yl)cyclopentadiene[c]pyrrole-1,3-diol, was isolated from the seeds of Castanea mollissima Blume. The structure was elucidated based on spectroscopic evidence including 2D NMR techniques. 相似文献
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90.
Samples with 5.1%9.8% and 15.3% HbA1c were extracted from normal subjects and patients with slight and serious diabetes respectively.Extended x-ray absorption fine structure spectra of Fe K absorption were collected at the EXAFS experimental station of the Beijing Synchrotron Radiation Facility.The step-by-step fluorescent mode was employed with a count time of 10s per point.Several independent scans were averageed to eliminate the statistical nosie.Reference backscattering amplitudes and phaseshifts were calculated using the curve wave theory (FEFF code) of EXAFS.Apart from the nitrogen neighbors around the central iron atom,oxygen neighbours are also found.The Fe-Nbond length increases by about 0.02A for the sample with 15.3% HbAlc Compared with the others,but the Fe-Obond length is almost unchanged.With increasing of HbAlc concentration,the content of Hb increases and the content of HbO2 decreases.This demonstrates that the glycosylation of haemoglobin will decrease its ability to carry oxygen. 相似文献